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Exploratory variational pseudopotential density functional calculations are performed for the electronic properties of many-electron systems in the 3D cartesian coordinate grid (CCG). The atom-centered localized gaussian basis set,…

Chemical Physics · Physics 2015-05-18 Amlan K Roy

The $N$-particle wavefunction has too many dimensions for a direct time propagation of a many-body system according to the time-dependent Schr\"odinger equation (TDSE). On the other hand, time-dependent density functional theory (TDDFT)…

Computational Physics · Physics 2017-11-21 M. Brics , J. Rapp , D. Bauer

This chapter presents the development of a density functional theory (DFT)-based method for accurate, reliable treatment of various resonances in atoms. Many of these are known to be notorious for their strong correlation, proximity to more…

Chemical Physics · Physics 2019-04-19 Amlan K. Roy

We present a new method to describe the kinetics of driven lattice gases with particle-particle interactions beyond hard-core exclusions. The method is based on the time-dependent density functional theory for lattice systems and allows one…

Statistical Mechanics · Physics 2015-05-20 Marcel Dierl , Philipp Maass , Mario Einax

Multi-configurational wave functions are known to describe electronic structure across a Born-Oppenheimer surface qualitatively correct. However, for quantitative reaction energies, dynamical correlation originating from the many…

Chemical Physics · Physics 2020-04-16 Christopher J. Stein , Markus Reiher

Accurately and efficiently describing strongly correlated electronic systems is a central challenge in quantum computational chemistry, with classical and quantum computers. The localized active space self-consistent field method (LASSCF)…

A practical electronic structure method in which a two-body functional is the fundamental variable is constructed. The basic formalism of our method is equivalent to Hartree-Fock density matrix functional theory [M. Levy in {\it Density…

Other Condensed Matter · Physics 2008-04-23 Balazs Hetenyi , Andreas W. Hauser

The accurate prediction of singlet and triplet excitation energies is of significant fundamental interest and is critical for many applications. An area of intense research, most calculations of singlet and triplet energies use…

Computational Physics · Physics 2017-05-22 Tonatiuh Rangel , Samia M. Hamed , Fabien Bruneval , Jeffrey B. Neaton

The self consistent version of the density functional theory is presented, which allows to calculate the ground state and dynamic properties of finite multi-electron systems. An exact functional equation for the effective interaction, from…

Materials Science · Physics 2017-08-23 M. Ya. Amusia , A. Z. Msezane , V. R. Shaginyan

A numerical scheme for solving the time-evolution of wave functions under the time dependent Kohn-Sham equation has been developed. Since the effective Hamiltonian depends on the wave functions, the wave functions and the effective…

Computational Physics · Physics 2009-11-07 Naoki Watanabe , Masaru Tsukada

To address the impact of electron correlations in the linear and non-linear response regimes of interacting many-electron systems exposed to time-dependent external fields, we study one-dimensional (1D) systems where the interacting problem…

Other Condensed Matter · Physics 2011-08-17 N. Helbig , J. I. Fuks , I. V. Tokatly , H. Appel , E. K. U. Gross , A. Rubio

Time-dependent density-functional theory (TDDFT) is widely used to describe electronic excitations in complex finite systems with large numbers of atoms, such as biomolecules and nanocrystals. The first part of this paper will give a simple…

Materials Science · Physics 2008-08-15 C. A. Ullrich , V. Turkowski

We present a new velocity-gauge real-time, time-dependent density functional tight-binding (VG-rtTDDFTB) implementation in the open-source DFTB+ software package (https://dftbplus.org) for probing electronic excitations in large, condensed…

Mesoscale and Nanoscale Physics · Physics 2024-05-24 Qiang Xu , Mauro Del Ben , Mahmut Sait Okyay , Min Choi , Khaled Z. Ibrahim , Bryan M. Wong

Three variants of mean field methods for atomic and nuclear reactions are compared with respect to both conception and applicability: The time--dependent Hartree--Fock method solves the equation of motion for a Hermitian density operator as…

Nuclear Theory · Physics 2009-10-31 J. Uhlig , J. C. Lemm , A. Weiguny

First principle theoretical modeling of out-of-equilibrium processes observed in attosecond pump-probe transient absorption spectroscopy (TAS) triggering pure electron dynamics remains a challenging task, specially for heavy elements and/or…

Chemical Physics · Physics 2023-02-14 Torsha Moitra , Lukas Konecny , Marius Kadek , Angel Rubio , Michal Repisky

The time-dependent equation-of-motion coupled cluster (TD-EOM-CC) and time-dependent coupled cluster (TDCC) methods are compared by simulating Rabi oscillations for different numbers of non-interacting atoms in a classical electromagnetic…

Chemical Physics · Physics 2023-10-02 Andreas S. Skeidsvoll , Henrik Koch

The Finite-Difference Time-Domain (FDTD) method is a well-known technique for the analysis of quantum devices. It solves a discretized Schrodinger equation in an explicitly iterative process. However, the method requires the spatial grid…

Quantum Physics · Physics 2012-12-05 Frederick Ira Moxley , Weizhong Dai

The time-dependent energy density functional with pairing allows to describe a large variety of phenomena from small to large amplitude collective motion. Here, we briefly summarize the recent progresses made in the field using the TD-BCS…

Nuclear Theory · Physics 2015-10-01 Denis Lacroix , Yusuke Tanimura , Guillaume Scamps

A discontinuous Galerkin time-domain (DGTD) method based on dynamically adaptive Cartesian meshes (ACM) is developed for a full-wave analysis of electromagnetic fields in dispersive media. Hierarchical Cartesian grids offer simplicity close…

Computational Physics · Physics 2017-06-28 Su Yan , Chao-Ping Lin , Robert R. Arslanbekov , Vladimir I. Kolobov , Jian-Ming Jin

An alternative method of developing the theory of non-equilibrium two dimensional holographic superconductor is to start from the definition of a time dependent $AdS_3$ background. As originally proposed, many of these formulae were cast in…

High Energy Physics - Theory · Physics 2016-10-19 N. S. Mazhari , D. Momeni , R. Myrzakulov , H. Gholizade , M. Raza