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Related papers: Time-dependent restricted-active-space self-consis…

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We consider the calculations of photoionization spectra and core resonances of open-shell systems using range-separated time-dependent density-functional theory. Specifically, we use the time-dependent range-separated hybrid (TDRSH) scheme,…

Chemical Physics · Physics 2023-01-11 Julien Toulouse , Karno Schwinn , Felipe Zapata , Antoine Levitt , Eric Cancès , Eleonora Luppi

Various ways to analyze the dynamical response of clusters and molecules to electromagnetic perturbations exist. Particularly rich information can be obtained from measuring the properties of electrons emitted in the course of the…

Atomic and Molecular Clusters · Physics 2015-06-11 P. Wopperer , P. M. Dinh , P. -G. Reinhard , E. Suraud

Electronic response properties of high-energy density (HED) systems influence planetary structure, drive evolution of fusion targets, and underpin diagnostics in laboratory astrophysics. Real-time time-dependent density functional theory…

Plasma Physics · Physics 2025-11-19 Alina Kononov , Minh Nguyen , Andrew D. Baczewski

If one-electron observables of a many-electron system are of interest, a many-electron dynamics can be represented exactly by a one-electron dynamics with effective potentials. The formalism for this reduction is provided by the Exact…

Chemical Physics · Physics 2021-01-04 Jakub Kocák , Axel Schild

The real-time electronic dynamics on material surfaces is critically important to a variety of applications. However, their simulations have remained challenging for conventional methods such as the time-dependent density-functional theory…

Chemical Physics · Physics 2015-06-16 Rulin Wang , Dong Hou , Xiao Zheng

The localized active space self consistent field (LASSCF) method factorizes a complete active space (CAS) wave function into an antisymmetrized product of localized active space wave function fragments. Correlation between fragments is then…

Chemical Physics · Physics 2024-03-26 Valay Agarawal , Daniel King , Matthew R. Hermes , Laura Gagliardi

The time-dependent Schr\"odinger equation (TDSE) in real space is fundamental to understanding the dynamics of many-electron quantum systems, with applications ranging from quantum chemistry to condensed matter physics and materials…

Quantum Physics · Physics 2026-03-31 Enze Hou , Yuzhi Liu , Linxuan Zhang , Difa Ye , Lei Wang , Han Wang

Use of density-functional theory in a $\Delta$self-consistent field framework result in both the ground- and two lowest electronicly excited states of the NaCl and LiCl. The accuracy of this method is confirmed using a multi-configuration…

Chemical Physics · Physics 2007-05-23 A. Hellman , M. Slabanja

We present a theoretical framework which describes multiply-charged atomic ions, their stability within super-intense laser fields,also lay corrections to the systems due to relativistic effects. Dimensional scaling calculations with…

Quantum Physics · Physics 2015-05-30 Ross D. Hoehn , Jiaxiang Wang , Sabre Kais

Density functional theory (DFT) is a widespread and effective tool in electronic structure calculations for ground-state electron systems. Its success has prompted exploration into the use of DFT for non-collective excited states. The delta…

Chemical Physics · Physics 2025-08-12 Ethan Pollack , Rohan Maniar , John P. Perdew

We report benchmark results for one-dimensional (1D) atomic and molecular systems interacting via the Coulomb operator $|x|^{-1}$. Using various wavefunction-type approaches, such as Hartree-Fock theory, second- and third-order…

Chemical Physics · Physics 2015-06-19 Pierre-François Loos , Caleb J. Ball , Peter M. W. Gill

Accurately resolving many-body satellite features in molecular core-level spectra requires theoretical approaches that capture electron correlation both efficiently and systematically. The recently developed time-dependent double…

Quantum Physics · Physics 2026-05-12 Vibin Abraham , Priyabrata Senapati , Himadri Pathak , Bo Peng

In this paper, we present a new space-time Petrov-Galerkin-like method. This method utilizes a mixed formulation of Tensor Train (TT) and Quantized Tensor Train (QTT), designed for the spectral element discretization (Q1-SEM) of the…

The density-constrained time-dependent Hartree-Fock (DC-TDHF) theory is a fully microscopic approach for calculating heavy-ion interaction potentials and fusion cross sections below and above the fusion barrier. We discuss recent…

Nuclear Theory · Physics 2014-02-07 A. S. Umar , V. E. Oberacker , R. Keser , J. A. Maruh , P. -G. Reinhard

A time-dependent equation of motion coupled cluster singles and doubles (TD-EOM-CCSD) method is implemented, which uses a reduced basis calculated with the asymmetric band Lanczos algorithm. The approach is used to study weak-field…

We study dissipation and relaxation processes within the time-dependent Hartree-Fock approach using the Wigner distribution function. On the technical side we present a geometrically unrestricted framework which allows us to calculate the…

Nuclear Theory · Physics 2012-08-30 N. Loebl , A. S. Umar , J. A. Maruhn , P. -G. Reinhard , P. D. Stevenson , V. E. Oberacker

We systematically extend Bogoliubov theory beyond the mean field approximation of the Bose-Hubbard model in the superfluid phase. Our approach is based on the time dependent variational principle applied to the family of all Gaussian states…

Quantum Gases · Physics 2019-10-02 Tommaso Guaita , Lucas Hackl , Tao Shi , Claudius Hubig , Eugene Demler , J. Ignacio Cirac

The computation of excited states within the Complete Active Space Self-Consistent Field (CASSCF) framework remains a significant challenge in quantum chemistry, both theoretically and algorithmically. In this work, we extend the K\"ahler…

Chemical Physics · Physics 2026-04-16 Laura Grazioli , Yukuan Hu , Tommaso Nottoli , Filippo Lipparini , Eric Cancès

These lecture notes are addressed to PhD student and/or researchers who want a general overview of microscopic approaches based on mean-field and applied to nuclear dynamics. Our goal is to provide a good description of low energy heavy-ion…

Nuclear Theory · Physics 2009-04-20 Cédric Simenel , Benoît Avez , Denis Lacroix

We present a theoretical study of the formation of self-trapped excitons (STEs) and the associated broadband emission in metal-halide perovskites Cs$_4$SnBr$_6$ and Cs$_2$AgInCl$_6$, using time-dependent density functional theory (TDDFT)…

Materials Science · Physics 2024-04-10 Yu Jin , Mariami Rusishvili , Marco Govoni , Giulia Galli