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In this thesis, I propose a practical way to stabilize half passivated graphene (graphone). I show that the dipole moments induced by a hexagonal-boron nitride (h-BN) substrate on graphene stabilize the hydrogen atoms on one sublattice of…

Mesoscale and Nanoscale Physics · Physics 2016-12-21 Shayan Hemmatiyan

We study the electronic structure and magnetic properties of h-BN triangular clusters embedded in graphene supercells. We find that, depending on the sizes of the clusters and the graphene separation region between them, spin polarization…

Mesoscale and Nanoscale Physics · Physics 2012-12-05 Marcos G. Menezes , Rodrigo B. Capaz

Hexagonal boron nitride encapsulation is the method of choice for protecting graphene from environmental doping and impurity scattering. It was previously demonstrated that metal-organic vapor phase epitaxy (MOVPE) grows epitaxially…

We present an experimental study of spin transport in single layer graphene using atomic sheets of hexagonal boron nitride (h-BN) as a tunnel barrier for spin injection. While h-BN is expected to be favorable for spin injection, previous…

Mesoscale and Nanoscale Physics · Physics 2017-03-31 Simranjeet Singh , Jyoti Katoch , Jinsong Xu , Cheng Tan , Tiancong Zhu , Walid Amamou , James Hone , Roland Kawakami

The current research in graphene spintronics strives for achieving a long spin lifetime, and efficient spin injection and detection in graphene. In this article, we review how hexagonal boron nitride (hBN) has evolved as a crucial…

Mesoscale and Nanoscale Physics · Physics 2018-06-26 Mallikarjuna Gurram , Siddhartha Omar , Bart J. van Wees

We study fully hexagonal boron nitride (hBN)-encapsulated graphene spin valve devices at room temperature. The device consists of a graphene channel encapsulated between two crystalline hBN flakes; thick-hBN flake as a bottom gate…

Mesoscale and Nanoscale Physics · Physics 2016-04-01 M. Gurram , S. Omar , S. Zihlmann , P. Makk , C. Schönenberger , B. J. van Wees

We investigate theoretically the electronic structure of graphene and boron nitride (BN) lateral heterostructures, which were fabricated in recent experiments. The first-principles density functional calculation demonstrates that a huge…

Mesoscale and Nanoscale Physics · Physics 2016-07-04 Dong Zhang , Maosheng Miao , Fuhua Yang , Haiqing Lin , Kai Chang

We demonstrate that freeing a single-atom thick layer of hexagonal boron nitride (hbn) from tight chemical bonding to a Ni(111) thin film grown on a W(110) substrate can be achieved by intercalation of Au atoms into the interface. This…

Hexagonal boron nitride (h-BN) is a natural hyperbolic material, for which the dielectric constants are the same in the basal plane (epsilon^t = epsilon^x = epsilon^y) but have opposite signs (epsilon^t*epsilon^z < 0) from that in the…

The van der Waals heterostructures of two-dimensional (2D) atomic crystals constitute a new paradigm in nanoscience. Hybrid devices of graphene with insulating 2D hexagonal boron nitride (h-BN) have emerged as promising nanoelectronic…

Mesoscale and Nanoscale Physics · Physics 2014-06-24 M. Venkata Kamalakar , André Dankert , Johan Bergsten , Tommy Ive , Saroj P. Dash

To grow precisely aligned graphene on h-BN without metal catalyst is extremely important, which allows for intriguing physical properties and devices of graphene/h-BN hetero-structure to be studied in a controllable manner. In this report,…

We present a transfer-free preparation method for graphene on hexagonal boron nitride (h-BN) crystals by chemical vapor deposition of graphene via a catalytic proximity effect, i.e. activated by a Cu catalyst close-by . We demonstrate the…

Electrons in graphene are theoretically expected to retain spin states much longer than most materials, making graphene a promising platform for spintronics and quantum information technologies. Here, we use first-principles density-matrix…

Materials Science · Physics 2022-03-17 Adela Habib , Junqing Xu , Yuan Ping , Ravishankar Sundararaman

Hexagonal boron nitride (BN), one of the very few layered insulators, plays a crucial role in 2D materials research. In particular, BN grown with a high pressure technique has proven to be an excellent substrate material for graphene and…

Mesoscale and Nanoscale Physics · Physics 2020-06-19 J. Sonntag , J. Li , A. Plaud , A. Loiseau , J. Barjon , J. H. Edgar , C. Stampfer

Transferring graphene flakes onto hexagonal boron nitride (h-BN) has been the most popular approach for the fabrication of graphne/h-BN heterostructures so far. The orientation between graphene and h-BN lattices, however, are not…

Materials Science · Physics 2019-12-05 Hadi Arjmandi-Tash

Graphene - a single atomic layer of graphite - is a recently-found two-dimensional form of carbon, which exhibits high crystal quality and ballistic electron transport at room temperature. Soft magnetic NiFe electrodes have been used to…

Mesoscale and Nanoscale Physics · Physics 2019-08-19 E. W. Hill , A. K. Geim , K. Novoselov , F. Schedin , P. Blake

Monolayer-thick hexagonal boron nitride (h-BN) is grown on graphene on SiC(0001), by exposure of the graphene to borazine, (BH)3(NH)3, at 1100 C. The h-BN films form ~2-micrometer size grains with a preferred orientation of 30 degrees…

Mesoscale and Nanoscale Physics · Physics 2018-08-15 Patrick C. Mende , Jun Li , Randall M. Feenstra

Graphene devices on standard SiO2 substrates are highly disordered, exhibiting characteristics far inferior to the expected intrinsic properties of graphene[1-12]. While suspending graphene above the substrate yields substantial improvement…

Mesoscale and Nanoscale Physics · Physics 2010-10-19 C. R. Dean , A. F. Young , I. Meric , C. Lee , L. Wang , S. Sorgenfrei , K. Watanabe , T. Taniguchi , P. Kim , K. L. Shepard , J. Hone

Carbon (C) doped hexagonal boron nitride (hBN) has been experimentally reported to be ferromagnetic at room temperature. Substitution by C in hBN has been also reported to form islands of graphene. In this work we derive a mechanistic…

Mesoscale and Nanoscale Physics · Physics 2019-03-13 Rita Maji , Joydeep Bhattacharjee

Encapsulating graphene in hexagonal Boron Nitride has several advantages: the highest mobilities reported to date are achieved in this way, and precise nanostructuring of graphene becomes feasible through the protective hBN layers.…

Mesoscale and Nanoscale Physics · Physics 2021-01-04 Yongping Du , Ning Xu , Xianqing Lin , Antti-Pekka Jauho
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