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The 7.6(5) eV nuclear magnetic-dipole transition in a single 229Th3+ ion may provide the foundation for an optical clock of superb accuracy. A virtual clock transition composed of stretched states within the 5F5/2 electronic ground level of…

Atomic Physics · Physics 2015-05-30 C. J. Campbell , A. G. Radnaev , A. Kuzmich , V. A. Dzuba , V. V. Flambaum , A. Derevianko

Highly charged ions (HCIs) combine compact electronic structure with strong relativistic effects, offering both robustness against external perturbations and enhanced sensitivity to variations of the fine-structure constant. Recent advances…

Atomic Physics · Physics 2026-02-17 S. G. Porsev , M. S. Safronova

Precision comparisons of different atomic frequency standards over a period of a few years can be used for a sensitive search for temporal variations of fundamental constants. We present recent frequency measurements of the 688 THz…

Atomic Physics · Physics 2008-11-25 E. Peik , B. Lipphardt , H. Schnatz , Chr. Tamm , S. Weyers , R. Wynands

We study electronic transitions in highly-charged Cf ions that are within the frequency range of optical lasers and have very high sensitivity to potential variations in the fine-structure constant, alpha. The transitions are in the optical…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

With the development of microwave atomic clocks, the Zeeman shifts for the spectral lines of black-body radiation need to be investigated carefully. In this Letter, the frequency shifts of hyperfine splittings of atomic ground states due to…

Atomic Physics · Physics 2020-02-12 Jize Han , Yani Zuo , Jianwei Zhang , Lijun Wang

Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental "constants" in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , J. A. King , M. G. Kozlov , M. T. Murphy , J. K. Webb

Molecules and atomic highly charged ions provide powerful low-energy probes of the fundamental laws of physics: Polar molecules possess internal fields suitable to enhance fundamental symmetry violation by several orders of magnitudes,…

Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental ``constants'' in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…

Accurate values of electric dipole (E1) amplitudes along with their uncertainties for a number of transitions among low-lying states of Mg$^+$, Ca$^+$, Sr$^+$, and Ba$^+$ are listed by carrying out calculations using a relativistic…

Atomic Physics · Physics 2020-12-30 Mandeep Kaur , Danish Furekh Dar , B. K. Sahoo , Bindiya Arora

Transition frequencies of atoms and ions are among the most accurately accessible quantities in nature, playing important roles in pushing the frontiers of science by testing fundamental laws of physics, in addition to a wide range of…

Recent advances in high-precision spectroscopy of highly charged ions necessitate an understanding of energy shifts of ionic levels caused by external electric and magnetic fields. Beyond the well-known Stark and linear Zeeman shifts,…

Atomic Physics · Physics 2024-11-11 Jan Gilles , Stephan Fritzsche , Lukas J. Spieß , Piet O. Schmidt , Andrey Surzhykov

We report a single-ion optical atomic clock with fractional frequency uncertainty of $5.5\times10^{-19}$ and fractional frequency stability of $3.5 \times10^{-16}/\sqrt{\tau/\mathrm{s}}$, based on quantum logic spectroscopy of a single…

We use the relativistic Hartree-Fock method, many-body perturbation theory and configuration-interaction method to calculate the dependence of atomic transition frequencies on the fine structure constant, alpha. The results of these…

Atomic Physics · Physics 2008-11-26 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , M. V. Marchenko

We describe a broadly applicable experimental proposal to search for the violation of local Lorentz invariance (LLI) with atomic systems. The new scheme uses dynamic decoupling and can be implemented in current atomic clocks experiments,…

Atomic clocks have been transformational in science and technology, leading to innovations such as global positioning, advanced communications, and tests of fundamental constant variation. Next-generation optical atomic clocks can extend…

The possibility of using neutral and double ionized erbium for atomic clocks of high precision is investigated. In both cases the narrow electric quadrupole clock transition between the ground and first exited state of the same…

Atomic Physics · Physics 2015-06-16 A. Kozlov , V. A. Dzuba , V. V. Flambaum

We investigate the feasibility of precision frequency metrology with large ion crystals. For clock candidates with a negative differential static polarisability, we show that micromotion effects should not impede the performance of the…

Quantum Physics · Physics 2016-10-25 Kyle Arnold , Elnur Haciyev , Eduardo Paez , Chern Hui Lee , John Bollinger , M. D. Barrett

In this work, the $4D_{3/2}|3,\pm2\rangle \rightarrow 4D_{5/2}|3,\pm2\rangle$ transition in the Nb$^{4+}$ ion is identified as a promising candidate for a terahertz (THz) atomic clock, with the transition frequency occurring at 56.0224 THz.…

Atomic Physics · Physics 2025-04-23 Jyoti , A. Chakraborty , Zhiyang Wang , Jia Zhang , Jingbiao Chen , Bindiya Arora , B. K. Sahoo

Optical transitions of highly charged ions can be very sensitive to hypothetical beyond-the-Standard-Model phenomena. Those near the $5s-4f$ level crossing, where the $5s$ and $4f$ are degenerate are especially promising. We present…

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