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We review a number of highly charged ions which have optical transitions suitable for building extremely accurate atomic clocks. This includes ions from Hf$^{12+}$ to U$^{34+}$, which have the $4f^{12}$ configuration of valence electrons,…

Atomic Physics · Physics 2015-06-23 V. A. Dzuba , V. V. Flambaum

We examine energy level-crossings of fine-structure (FS) levels in the heavier highly charged ions (HCIs) with $d^6$ and $d^8$ configurations. From the analysis, we find that some of these HCIs are tailor-made for atomic clocks with quality…

Atomic Physics · Physics 2023-07-28 Yan-mei Yu , B. K. Sahoo

Recent developments in frequency metrology and optical clocks have been based on electronic transitions in atoms and singly charged ions as references. These systems have enabled relative frequency uncertainties at a level of a few parts in…

Atomic Physics · Physics 2018-12-06 M. G. Kozlov , M. S. Safronova , J. R. Crespo López-Urrutia , P. O. Schmidt

We identify two metastable excited states in Sm$ ^{10+} $ highly charged ion as candidates for high accuracy optical clocks. Several atomic properties relevant to optical clock development are calculated using relativistic many-body…

High Energy Physics - Phenomenology · Physics 2024-09-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

We carried out detailed high-precision study of Ag-like Nd$^{13+}$, Sm$^{15+}$ and In-like Ce$^{9+}$, Pr$^{10+}$, Nd$^{11+}$, Sm$^{13+}$, Eu$^{14+}$ highly-charged ions. These ions were identified to be of particular interest to the…

Atomic Physics · Physics 2015-06-22 M. S. Safronova , V. A. Dzuba , V. V. Flambaum , U. I. Safronova , S. G. Porsev , M. G. Kozlov

We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , V. A. Dzuba , V. V. Flambaum

Attempts are made to unify gravity with the other three fundamental forces of nature. As suggested by higher dimensional models, this unification may require space and time variation of some dimensionless fundamental constants. In this…

Atomic Physics · Physics 2023-02-15 Yan-Mei Yu , B. K. Sahoo , Bing-Bing Suo

Highly charged ions of heavy actinides from uranium to einsteinium are studied theoretically to find optical transitions sensitive to the variation of the fine structure constant. A number of promising transitions have been found in ions…

Atomic Physics · Physics 2024-05-21 V. A. Dzuba , V. V. Flambaum

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

We identify laser-accessible transitions in group 16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground $^{3}P_{J}$ fine structure manifold…

Atomic Physics · Physics 2022-10-06 Saleh O. Allehabi , S. M. Brewer , V. A. Dzuba , V. V. Flambaum , K. Beloy

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

An active optical clock based on highly charged Nd$^{9+}$ ion is proposed for the first time. The clock can offer ultra-narrow linewidth at the $\upmu$Hz-level which is more than two-order of magnitude below the currently recorded laser…

Atomic Physics · Physics 2021-07-23 Yan-mei Yu , Duo Pan , Shaolong Chen , Hua Guan , Kelin Gao , Jingbiao Chen

We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available.…

Atomic Physics · Physics 2022-09-20 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Highly charged ions (HCIs) are insensitive to external perturbations and are attractive for the development of ultrastable clocks. However, only a few HCI candidates are known to provide optical clock transitions. In this Letter, we show…

Atomic Physics · Physics 2025-01-07 Chunhai Lyu , Christoph H. Keitel , Zoltán Harman

We perform detailed calculations of the electronic structure of the Os$^{16+}$ ion and demonstrate that it has several metastable states which can be used for very accurate optical clocks. The clocks are highly sensitive to manifestations…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

We study atomic systems that are in the frequency range of optical atomic clocks and have enhanced sensitivity to potential time-variation of the fine structure constant, alpha. The high sensitivity is due to coherent contributions from…

Atomic Physics · Physics 2010-09-16 J. C. Berengut , V. A. Dzuba , V. V. Flambaum

We evaluate the feasibility of using magnetic-dipole (M1) transitions in highly-charged ions as a basis of an optical atomic clockwork of exceptional accuracy. We consider a range of possibilities, including M1 transitions between clock…

Atomic Physics · Physics 2015-06-23 V. I. Yudin , A. V. Taichenachev , A. Derevianko

We propose here a few selective highly charged ions (HCIs), namely Ni$^{12+}$ and Cu$^{13+}$, Pd$^{12+}$ and Ag$^{13+}$, that not only promise to be very high accurate optical clocks below $10^{-19}$ uncertainties, but also offer quality…

Atomic Physics · Physics 2018-04-25 Yan-mei Yu , B. K. Sahoo

Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify…

Atomic Physics · Physics 2015-08-12 U. I. Safronova , V. V. Flambaum , M. S. Safronova

Level crossings in the ground state of ions occur when the nuclear charge Z and ion charge Z_ion are varied along an isoelectronic sequence until the two outermost shells are nearly degenerate. We examine all available level crossings in…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong
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