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Maximally localized Wannier functions are the key tool for a variety of physical applications of Bloch states. Here we develop a simple and exact procedure to construct maximally localized Wannier functions for one dimensional periodic…

Strongly Correlated Electrons · Physics 2014-12-12 Yuri Lensky , Colin Kennedy

The electronic structure of solids can routinely be calculated by standard methods like density functional theory. However, in complicated situations like interfaces, grain boundaries or contact geometries one needs to resort to more…

Materials Science · Physics 2025-11-18 Henrik Dick , Thomas Dahm

This paper develops the so-called Weighted Energy-Dissipation (WED) variational approach for the analysis of gradient flows in metric spaces. This focuses on the minimization of the parameter-dependent global-in-time functional of…

Analysis of PDEs · Mathematics 2018-01-17 Riccarda Rossi , Giuseppe Savaré , Antonio Segatti , Ulisse Stefanelli

The eigenfunctions of the Laplace Beltrami operator (Manifold Harmonics) define a function basis that can be used in spectral analysis on manifolds. In [21] the authors recast the problem as an orthogonality constrained optimization problem…

Numerical Analysis · Mathematics 2018-04-23 Martin Huska , Damiana Lazzaro , Serena Morigi

We consider the time-independent Wigner functions of phase-space quantum mechanics (a.k.a. deformation quantization) for a Morse potential. First, we find them by solving the $\ast$-eigenvalue equations, using a method that can be applied…

Mathematical Physics · Physics 2010-02-03 B. Belchev , M. A. Walton

We present a powerful and easy-to-implement algorithm for solving constrained optimization problems that involve $L_1$/total-variation regularization terms, and both equality and inequality constraints. We discuss the relationship of our…

Optimization and Control · Mathematics 2015-05-22 Musa Maharramov , Stewart A. Levin

A standard task in solid state physics and quantum chemistry is the computation of localized molecular orbitals known as Wannier functions. In this manuscript, we propose a new procedure for computing Wannier functions in one-dimensional…

Mathematical Physics · Physics 2025-10-21 Abinand Gopal , Hanwen Zhang

Pulay terms arise in the Hellman-Feynman forces in electronic structure calculations when one employs a basis set made of localized orbitals that move with their host atoms. If the total energy of the system depends on a subspace population…

Materials Science · Physics 2018-05-23 Subhayan Roychoudhury , David D. O'Regan , Stefano Sanvito

We prove the applicability of the Weighted Energy-Dissipation (WED) variational principle [50] to nonlinear parabolic stochastic partial differential equations in abstract form. The WED principle consists in the minimization of a…

Optimization and Control · Mathematics 2021-01-19 Luca Scarpa , Ulisse Stefanelli

An electron moving on plane in a uniform magnetic field orthogonal to plane is known as the Landau problem. Wigner functions for the Landau problem when the plane is noncommutative are found employing solutions of the Schroedinger equation…

High Energy Physics - Theory · Physics 2014-11-18 O. F. Dayi , L. T. Kelleyane

We discuss a method for constructing generalized Wannier functions that are maximally localized at the minima of a one-dimensional periodic potential with a double-well per unit cell. By following the approach of (Marzari M and Vanderbilt D…

Quantum Gases · Physics 2013-07-04 Michele Modugno , Giulio Pettini

Spatially localized one-electron orbitals, orthogonal and nonorthogonal, are widely used in electronic structure theory to describe chemical bonding and speed up calculations. In order to avoid linear dependencies of localized orbitals, the…

Chemical Physics · Physics 2020-03-04 Ziling Luo , Rustam Z. Khaliullin

The electronic ground state of a periodic system is usually described in terms of extended Bloch orbitals, but an alternative representation in terms of localized "Wannier functions" was introduced by Gregory Wannier in 1937. The connection…

Materials Science · Physics 2012-11-28 Nicola Marzari , Arash A. Mostofi , Jonathan R. Yates , Ivo Souza , David Vanderbilt

The existence and construction of exponentially localised Wannier functions for insulators is a well-studied problem. In comparison, the case of metallic systems has been much less explored, even though localised Wannier functions…

Mathematical Physics · Physics 2019-02-04 Horia Cornean , David Gontier , Antoine Levitt , Domenico Monaco

Maximally localized Wannier functions (MLWFs) are widely used to construct first-principles tight-binding models that accurately reproduce the electronic structure of materials. Recently, robust and automated approaches to generate these…

Computational Physics · Physics 2023-11-02 Junfeng Qiao , Giovanni Pizzi , Nicola Marzari

We present a new method for minimizing the sum of a differentiable convex function and an $\ell_1$-norm regularizer. The main features of the new method include: $(i)$ an evolving set of indices corresponding to variables that are predicted…

Optimization and Control · Mathematics 2016-02-24 Tianyi Chen , Frank E. Curtis , Daniel P. Robinson

Wavelet systems on the generalized Vilenkin groups are considered. An algorithmic method for the construction of orthogonal wavelet bases is presented. These bases consist of compactly supported test functions (i.e. functions whose Fourier…

Functional Analysis · Mathematics 2025-06-24 M. Babushkin , M. Skopina

We present a new code to evaluate thermoelectric and electronic transport properties of extended systems with a maximally-localized Wannier function basis set. The semiclassical Boltzmann transport equations for the homogeneous infinite…

Materials Science · Physics 2013-11-22 Giovanni Pizzi , Dmitri Volja , Boris Kozinsky , Marco Fornari , Nicola Marzari

We characterise modulation spaces by suitable Wiener estimates on the short-time Fourier transforms of the involved functions and distributions. We use the results to refine some formulae on periodic distributions with Lebesgue estimates on…

Functional Analysis · Mathematics 2019-03-20 Joachim Toft

In many models in condensed matter physics and high-energy physics, one finds inhomogeneous phases at high density and low temperature. These phases are characterized by a spatially dependent condensate or order parameter. A proper…

High Energy Physics - Phenomenology · Physics 2017-08-03 Prabal Adhikari , Jens O. Andersen