Related papers: Entropy is in Flux
We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…
Here we deconstruct, and then in a reasoned way reconstruct, the concept of "entropy of a system," paying particular attention to where the randomness may be coming from. We start with the core concept of entropy as a COUNT associated with…
Entropy production is one of the most important characteristics of non-equilibrium steady states. We study here the steady-state entropy production, both at short times as well as in the long-time limit, of two important classes of…
We study nonequilibrium thermodynamic properties of a driven one-dimensional quantum fluid by combining nonlinear Luttinger liquid theory with the quantum kinetic equation. In particular, we derive an entropy production consistent with the…
This paper is an introduction to the von Neumann entropy in a historic approach. Von Neumann's gedanken experiment is repeated, which led him to the formula of thermodynamic entropy of a statistical operator. In the analysis of his ideas we…
Boltzmann's struggle with a derivation of the Second Law of Thermodynamics is sketched. So is his first derivation of the connection between entropy and probability in 1877. Planck's derivation and quantum mechanical modifications of…
Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to…
A definition of the thermodynamic entropy based on the time-dependent probability distribution of the macroscopic variables is developed. When a constraint in a composite system is released, the probability distribution for the new…
Entropy is one of the central quantities in thermodynamics, whose flow between two systems determines the statistics of energy transfers. In quantum systems entropy is non-linear in density matrix whose time evolution is cumbersome. Using…
Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…
The local entropy of a nonequilibrium system of independent fermions is investigated, and analyzed in the context of the laws of thermodynamics. It is shown that the local temperature and chemical potential can only be expressed in terms of…
Experimental and theoretical results about entropy limits for macroscopic and single-particle systems are reviewed. It is clarified when it is possible to speak about a quantum of entropy, given by the Boltzmann constant k, and about a…
Within an inherently classical perspective, there is always an unavoidable energy cost associated with the information deletion and this common lore is at the heart of the Landauer's conjecture that does not impose, per se, any relevant…
Entanglement and entropy are key concepts standing at the foundations of quantum and statistical mechanics, respectively. In the last decade the study of quantum quenches revealed that these two concepts are intricately intertwined.…
The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…
The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…
In a recent paper [Franzosi, Physica A {\bf 494}, 302 (2018)], we have suggested to use of the surface entropy, namely the logarithm of the area of a hypersurface of constant energy in the phase space, as an expression for the thermodynamic…
Entropy increase is fundamentally related to the breaking of time-reversal symmetry. By adding the 'extra dimension' associated with thermodynamic forces, we extend that discrete symmetry to a continuous symmetry for the dynamical…
We overview the notion of entropy in thermodynamics. We start from the smooth case using differential forms on the manifold, which is the natural language for thermodynamics. Then the axiomatic definition of entropy as ordering on a set…