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The mid-infrared (IR; 5-15~$\mu$m) spectrum of a wide variety of astronomical objects exhibits a set of broad emission features at 6.2, 7.7, 8.6, 11.3 and 12.7 $\mu$m. About 30 years ago it was proposed that these signatures are due to…

Astrophysics of Galaxies · Physics 2014-07-02 Marissa J. F. Rosenberg , Olivier Berné , Christiaan Boersma

Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules resulting from the union of aromatic rings and related species, which are likely responsible for strong infrared emission features (3.3, 6.2, 7.7, 8.6, 11.3 and 12.7…

Astrophysics of Galaxies · Physics 2021-11-05 I. García-Bernete , D. Rigopoulou , A. Alonso-Herrero , M. Pereira-Santaella , P. F. Roche , B. Kerkeni

Interstellar polycyclic aromatic hydrocarbon (PAHs) are an important component of the interstellar medium of galaxies, containing some 10 percent of the elemental carbon. Their vibrational emission dominates the mid-infrared spectra of…

Astrophysics of Galaxies · Physics 2026-03-06 A. G. G. M. Tielens

The search for large polycyclic aromatic hydrocarbons (PAHs) with over 100 carbon atoms is crucial to resolving the origin of unidentified infrared emission (UIE) bands. These bands are commonly observed in nebulae and the interstellar…

Astrophysics of Galaxies · Physics 2025-08-22 Yi Shao , Yong Zhang , Xu-Jia Ouyang , Chuan-Peng Zhang

In order to find out capable molecular source of astronomically well observed infrared (IR) spectrum, asymmetric molecular configuration polycyclic aromatic hydrocarbon (PAH) was analyzed by the density functional theory (DFT) analysis.…

Astrophysics of Galaxies · Physics 2015-10-27 Norio Ota

Polycyclic Aromatic Hydrocarbons (PAHs) are considered as a major constituent of interstellar dust. They have been proposed as the carriers of the Aromatic Infrared Bands (AIBs) observed in emission in the mid-IR. They likely have a…

Astrophysics of Galaxies · Physics 2009-04-22 C. Joblin , O. Berne , A. Simon , G. Mulas

Interstellar Polycyclic Aromatic Hydrocarbon (PAH) molecules exist in diverse forms depending on the local physical environment. Formation of ionized PAHs (anions and cations) is favourable in the extreme conditions of the ISM. Besides in…

Astrophysics of Galaxies · Physics 2017-12-27 Mridusmita Buragohain , Amit Pathak , Peter Sarre , Nand Kishor Gour

The 11.3 $\mu$m emission feature is a prominent member of the family of unidentified infrared emission (UIE) bands and is frequently attributed to out-of-plane bending modes of polycyclic aromatic hydrocarbon (PAH) molecules. We have…

Solar and Stellar Astrophysics · Physics 2015-07-15 SeyedAbdolreza Sadjadi , Yong Zhang , Sun Kwok

Polycyclic aromatic hydrocarbon (PAH) molecules, as revealed by the distinctive set of emission bands at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 $\mu$m characteristic of their vibrational modes, are abundant and widespread throughout the…

Astrophysics of Galaxies · Physics 2020-03-25 Aigen Li

The polycyclic aromatic hydrocarbon (PAH) hypothesis proposes that the aromatic infrared bands (AIBs) observed at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 mic originate from gas-phase PAH molecules. These bands exhibit consistent peak wavelengths…

Astrophysics of Galaxies · Physics 2025-11-03 Alan T. Tokunaga , Lawrence S. Bernstein , Takashi Onaka

Evolved stars are primary sources for the formation of polycyclic aromatic hydrocarbons (PAHs) and dust grains. Their circumstellar chemistry is usually designated as either oxygen-rich or carbon-rich, although dual-dust chemistry objects,…

Solar and Stellar Astrophysics · Physics 2015-12-23 N. L. J. Cox , P. Pilleri , O. Berne , J. Cernicharo , C. Joblin

We present a new method to decompose the emission features of polycyclic aromatic hydrocarbons (PAHs) from mid-infrared spectra using theoretical PAH templates in conjunction with modified blackbody components for the dust continuum and an…

Astrophysics of Galaxies · Physics 2018-06-26 Yanxia Xie , Luis C. Ho , Aigen Li , Jinyi Shangguan

Polycyclic aromatic hydrocarbon (PAH) emission has been found in both starbursts and modestly starforming galaxies, but the relation between starforming activity and PAH luminosity is still a matter of debate. The different correlation…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-14 Martin Haas , Christian Leipski , Ralf Siebenmorgen , Helmut Meusinger , Holger Drass , Rolf Chini

Polycyclic Aromatic Hydrocarbons are prevalent in the universe and interstellar medium but are primarily attributed to anthropogenic sources on Earth, such as fossil fuel combustion and firewood burning. Drawing upon the idea of PAHs as…

Earth and Planetary Astrophysics · Physics 2025-01-14 Dwaipayan Dubey , Ravi Kopparapu , Barbara Ercolano , Karan Molaverdikhani

We have obtained new STIS/HST spectra to search for structure in the ultraviolet interstellar extinction curve, with particular emphasis on a search for absorption features produced by polycyclic aromatic hydrocarbons (PAHs). The presence…

We present a charge distribution based model that computes the infrared spectrum of polycyclic aromatic hydrocarbon (PAH) molecules using recent measurements or quantum chemical calculations of specific PAHs. The model is applied to a…

Astrophysics of Galaxies · Physics 2022-06-15 Ameek Sidhu , A. G. G. M. Tielens , Els Peeters , Jan Cami

The observed variations in profiles of the interstellar aromatic infrared bands correlate with the object type and are indicative of PAH populations existing i n different sources. Spectroscopic studies on PAHs can provide tools for the int…

Astrophysics · Physics 2009-11-13 Amit Pathak , Shantanu Rastogi

Context: Polycyclic Aromatic Hydrocarbons, largely known as PAHs, are widespread in the universe and have been identified in a vast array of astronomical observations from the interstellar medium to protoplanetary discs. They are likely to…

Earth and Planetary Astrophysics · Physics 2023-10-11 Dwaipayan Dubey , Fabian Grübel , Rosa Arenales-Lope , Karan Molaverdikhani , Barbara Ercolano , Christian Rab , Oliver Trapp

We investigate the emission properties of polycyclic aromatic hydrocarbons (PAHs) in various metallicity environments with the Infrared Spectrograph on board Spitzer. Local giant HII regions are used as references as they enable access to…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 V. Lebouteiller , J. Bernard-Salas , D. G. Whelan , B. Brandl , F. Galliano , V. Charmandaris , S. Madden , D. Kunth
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