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The full potential of graphene in integrated circuits can only be realized with a reliable ultra-thin high-{\kappa} top-gate dielectric. Here, we report the first statistical analysis of the breakdown characteristics of dielectrics on…

We demonstrate the extensive study on how film density and crystallinity of molybdenum carbide ($MoC_{x}$) can be tailored during plasma-enhanced ALD (PEALD) by controlling either the plasma exposure time or the ion energy. We investigated…

Applied Physics · Physics 2019-11-13 Eldad Grady , Marcel Verheijen , Tahsin Faraz , Saurabh Karwal , W. M. M. Kessels , Ageeth A. Bol

The adoption of graphene in electronics, optoelectronics and photonics is hindered by the difficulty in obtaining high quality material on technologically-relevant substrates, over wafer-scale sizes and with metal contamination levels…

Bilayer graphene -- two coupled single graphene layers stacked as in graphite -- provides the only known semiconductor with a gap that can be tuned externally through electric field effect. Here we use a tight binding approach to study how…

Mesoscale and Nanoscale Physics · Physics 2010-04-29 Eduardo V. Castro , N. M. R. Peres , J. M. B. Lopes dos Santos , F. Guinea , A. H. Castro Neto

Recent intensive research on two-dimensional materials (2DMs) rekindle the interest in the intercalation of various atoms and molecules into layered compounds as a tool to manufacture 2DMs and tune their optoelectronic, magnetic and…

Mesoscale and Nanoscale Physics · Physics 2025-07-10 Arkady V. Krasheninnikov , Yung-Chang Lin , Kazu Suenaga

Chemically doped graphene could support plasmon excitations up to telecommunication or even visible frequencies. Apart from that, the presence of dopant may influence electron scattering mechanisms in graphene and thus impact the plasmon…

Materials Science · Physics 2017-10-06 Dino Novko

The optical properties of dielectric plates coated with gapped graphene are investigated on the basis of first principles of quantum electrodynamics. The reflection coefficients and reflectivities of graphene-coated plates are expressed in…

Materials Science · Physics 2017-01-27 G. L. Klimchitskaya , V. M. Mostepanenko

We study the interaction of electromagnetic (EM) radiation with single-layer graphene and a stack of parallel graphene sheets at arbitrary angles of incidence. It is found that the behavior is qualitatively different for transverse magnetic…

Mesoscale and Nanoscale Physics · Physics 2013-10-31 Yuliy V. Bludov , Nuno M. R. Peres , Mikhail I. Vasilevskiy

Direct growth of large-area vertically stacked two-dimensional (2D) van der Waal (vdW) materials is a prerequisite for their high-end applications in integrated electronics, optoelectronics and photovoltaics. Currently, centimetre- to even…

Graphene bilayer systems are known to exhibit a band gap when the layer symmetry is broken, by applying a perpendicular electric field. The resulting band structure resembles that of a conventional semiconductor with a parabolic dispersion.…

Mesoscale and Nanoscale Physics · Physics 2015-07-03 Søren Schou Gregersen , Jesper Goor Pedersen , Stephen R. Power , Antti-Pekka Jauho

The chemical modification of graphene with adatoms is of importance for nanoelectronics applications. Based on first-principles density-functional theory calculations with including van der Waals interactions, we present a comparative study…

Materials Science · Physics 2017-04-26 Seho Yi , Hyun-Jung Kim , Jin-Ho Choi , Jun-Hyung Cho

Photoelectron diffraction (PED) is a powerful spectroscopic technique that combines elemental resolution with a high sensitivity to the local atomic arrangement at crystal surfaces, thus providing unique fingerprints of selected atomic…

$\alpha$-graphyne is a two-dimensional sheet of $sp$-$sp^2$ hybridized carbon atoms in a honeycomb lattice. While the geometrical structure is similar to that of graphene, the hybridized triple bonds give rise to electronic structure that…

Materials Science · Physics 2017-08-04 Hyeondeok Shin , Jeongnim Kim , Hoonkyung Lee , Olle Heinonen , Anouar Benali , Yongkyung Kwon

Motivated by recent experiments [H. Zhou, \emph{et al.}, Science {\bf 375}, 774 (2022) and S. C. de la Barrera, \emph{et al.}, arXiv:2110.13907], here we propose a general mechanism for valley and/or spin degeneracy lifting of the…

Mesoscale and Nanoscale Physics · Physics 2022-05-09 Andras Szabo , Bitan Roy

Two-dimensional (2D) semiconductors are widely recognized as attractive channel materials for low-power electronics. However, an unresolved challenge is the integration of high-quality, ultrathin high-\k{appa} dielectrics that fully meet…

Cold atoms in an optical lattice with brick-wall geometry have been used to mimic graphene, a two-dimensional material with characteristic Dirac excitations. Here we propose to bring such artificial graphene into the proximity of a second…

The Diels-Alder surface modified top epitaxial graphene layer, with newly created pair of sp3 carbon centres, results in abrupt minimization of interlayer van der Waals interactions between two stacked graphene planes, and escapes the wafer…

Materials Science · Physics 2014-09-30 Santanu Sarkar

Materials can, in principle, be imaged at the level of individual atoms with aberration corrected transmission electron microscopy. However, such resolution can be attained only with very high electron doses. Consequently, radiation damage…

Materials Science · Physics 2015-06-17 Gerardo Algara-Siller , Simon Kurasch , Mona Sedighi , Ossi Lehtinen , Ute Kaiser

Edges naturally exist in a single-layer graphene sample. Similarly, individual graphene layers in a multilayer graphene sample contribute their own edges. We study the Raman spectrum at the edge of a graphene layer laid on n layer graphene…

Materials Science · Physics 2015-01-15 Q. -Q. Li , X. Zhang , W. -P. Han , Y. Lu , W. Shi , J. -B. Wu , P. -H. Tan

Graphene's structure bears on both the material's electronic properties and fundamental questions about long range order in two-dimensional crystals. We present an analytic calculation of selected area electron diffraction from multi-layer…

Mesoscale and Nanoscale Physics · Physics 2015-03-20 Brian Shevitski , Matthew Mecklenburg , William A. Hubbard , E. R. White , Ben Dawson , M. S. Lodge , Masa Ishigami , B. C. Regan