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Using the Car-Parrinello technique, ab initio molecular dynamics simulations are performed for liquid NaSn alloys in five different compositions (20, 40, 50, 57 and 80 % sodium). The obtained structure factors agree well with the data from…

Condensed Matter · Physics 2015-06-25 M. Schoene , R. Kaschner , G. Seifert

Thermodynamic properties of liquid water as well as hexagonal (Ih) and cubic (Ic) ice are predicted based on density functional theory at the hybrid-functional level, rigorously taking into account quantum nuclear motion, anharmonic…

Materials Science · Physics 2025-10-06 Bingqing Cheng , Edgar A. Engel , Jörg Behler , Christoph Dellago , Michele Ceriotti

We use ab initio simulations to study the static and dynamic properties of a sodium borosilicate liquid with composition 3Na_2O-B_2O_3-6SiO_2, i.e. a system that is the basis of many glass-forming materials. In particular we focus on the…

Disordered Systems and Neural Networks · Physics 2018-02-28 Laurent Pedesseau , Simona Ispas , Walter Kob

We use recently introduced three-point dynamic susceptibilities to obtain an experimental determination of the temperature evolution of the number of molecules, N_corr, that are dynamically correlated during the structural relaxation of…

Confinement can modify the dynamics, the thermodynamics and the structural properties of liquid water, the prototypical anomalous liquid. By considering a general anomalous liquid, suitable for globular proteins, colloids or liquid metals,…

Soft Condensed Matter · Physics 2015-06-19 Fabio Leoni , Giancarlo Franzese

As-rich GaAs (001) surfaces are successfully observed during As4-irradition by a system in which scanning tunneling microscopy (STM) and molecular beam epitaxy can be performed simultaneously. With a substrate temperature of 440 C and an…

We investigate structural order in glassy water by performing classical molecular dynamics simulations using the extended simple point charge (SPC/E) model of water. We perform isochoric cooling simulations across the glass transition…

Soft Condensed Matter · Physics 2009-11-11 Nicolas Giovambattista , Pablo G. Debenedetti , Francesco Sciortino , H. Eugene Stanley

It has recently been shown that the TIP4P/Ice model of water can be studied numerically in metastable equilibrium at and below its liquid-liquid critical temperature. We report here simulations along a subcritical isotherm, for which two…

Soft Condensed Matter · Physics 2021-06-02 Riccardo Foffi , John Russo , Francesco Sciortino

The structural and dynamical properties of four silicate liquids (silica, rhyolite, a model basalt and enstatite) are evaluated by ab initio molecular dynamics simulation using the density functional theory and are compared with classical…

Statistical Mechanics · Physics 2015-05-13 R. Vuilleumier , N. Sator , B. Guillot

The structural evolution and dynamics of silver nanodrops Ag${}_{2896}$ (4.4 nm in diameter) during rapid cooling conditions has been studied by means of molecular dynamics simulations and electronic density of state calculations. The…

Materials Science · Physics 2009-01-22 I. Lobato , J. Rojas , C. V. Landauro , J. Torres

Experiments and computer simulations have established that liquid water's surfaces can deviate in important ways from familiar bulk behavior. Even in the simplest case of an air-water interface, distinctive layering, orientational biases,…

Soft Condensed Matter · Physics 2022-07-15 Nathan L. Odendahl , Phillip L. Geissler

First-principles molecular dynamics is employed to describe the atomic structure of amorphous SiN, a non-stoichiometric compound belonging to the Si$_x$N$_{y}$ family. To produce the amorphous state via the cooling of the liquid, both the…

Materials Science · Physics 2022-05-19 Achille Lambrecht , Carlo Massobrio , Mauro Boero , Guido Ori , Evelyne Martin

We have revisited the composition dependence of principal properties of liquid water-DMSO mixtures by using the isobaric-isothermal molecular dynamics computer simulations. A set of non-polarizable semi-flexible models for the DMSO molecule…

Soft Condensed Matter · Physics 2022-10-10 M. Aguilar , H. Dominguez , O. Pizio

Isothermal-isobaric molecular dynamics simulations have been performed to examine an ample set of properties of the model water-N,N-dimethylformamide (DMF) mixture as a function of composition. The SPC-E and TIP4P-Ew water models together…

Soft Condensed Matter · Physics 2017-12-15 H. Dominguez , O. Pizio

We present neutron scattering results for the dynamic response by superfluid and normal-fluid 4He and the results of a simple perturbation-theory analysis which allows us to describe all aspects of the observed behavior by considering only…

Other Condensed Matter · Physics 2007-05-23 Wouter Montfrooij , Eric Svensson , Rolf Verberg , Roelof Crevecoeur , Ignatz de Schepper

We present the results of a molecular dynamics simulation study of thermodynamic and structural properties upon supercooling of a low concentration sodium chloride solution in TIP4P water and the comparison with the corresponding bulk…

Soft Condensed Matter · Physics 2008-06-25 D. Corradini , P. Gallo , M. Rovere

Dynamic heterogeneity as one of the most important properties in supercooled liquids has been found for several decades. However, its structural origin remains open for many systems. Here, we propose a new structural parameter to…

Disordered Systems and Neural Networks · Physics 2015-10-16 S. P. Pan , S. D. Feng , J. W. Qiao , W. M. Wang , J. Y. Qin

Many atomic liquids can form transient covalent bonds reminiscent of those in the corresponding solid states. These directional interactions dictate many important properties of the liquid state, necessitating a quantitative, atomic-scale…

Chemical Physics · Physics 2020-03-30 Richard C. Remsing , Michael L. Klein

Simulation (molecular dynamics and Car-Parrinello [Phys. Rev. Lett. 55, 2471 (1985)]) and diffraction (x-ray and neutron) studies on nitromethane are compared aiming at the determination of the liquid structure. Beyond that, the…

Soft Condensed Matter · Physics 2017-02-07 Tünde Megyes , Szabolcs Bálint , Tamás Grósz , Tamás Radnai , Imre Bakó , László Almásy

Liquid metals at extreme pressures and temperatures are widely interested in the high-pressure community. Based on density functional theory molecular dynamics, we conduct first-principles investigations on the equation of state (EOS) and…

Materials Science · Physics 2020-11-06 Shuai Zhang , Miguel A. Morales