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We demonstrate strong coupling between molecular excited states and surface plasmon modes of a slit array in a thin metal film. The coupling manifests itself as an anti-crossing behavior of the two newly formed polaritons. As the coupling…

Mesoscale and Nanoscale Physics · Physics 2012-08-17 Adi Salomon , Robert J. Gordon , Yehiam Prior , Tamar Seideman , Maxim Sukharev

There is growing interest in using strongly coupled organic microcavities to tune molecular dynamics, including the electronic and vibrational properties of molecules. However, very little attention has been paid to the utility of cavity…

Materials Science · Physics 2024-06-12 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

The first exact quantum simulation of a real molecular system (HD$^+$) under strong ro-vibrational coupling to a quantized optical cavity mode in thermal equilibrium is presented. Theoretical challenges in describing strongly coupled…

Quantum Physics · Physics 2022-08-03 Dominik Sidler , Michael Ruggenthaler , Angel Rubio

Cavity electromechanics relies on parametric coupling between microwave and mechanical modes to manipulate the mechanical quantum state, and provide a coherent interface between different parts of hybrid quantum systems. High coherence of…

Quantum Physics · Physics 2022-03-22 Yannick Seis , Thibault Capelle , Eric Langman , Sampo Saarinen , Eric Planz , Albert Schliesser

Cavity quantum electrodynamics advances the coherent control of a single quantum emitter with a quantized radiation field mode, typically piecewise engineered for the highest finesse and confinement in the cavity field. This enables the…

The coupling of resonant light and surface plasmons in metal layer coated optical microcavities results in the formation of hybrid photon-plasmon modes. Here, we comprehensively investigate the hybridization mechanism of photon-plasmon…

Cavity electro-(opto-)mechanics allows us to access not only single isolated but also multiple mechanical modes in a massive object. Here we develop a multi-mode electromechanical system in which a several membrane vibrational modes are…

We show how to simulate a model of many molecules with both strong coupling to many vibrational modes and collective coupling to a single photon mode. We do this by combining process tensor matrix product operator methods with a mean-field…

Quantum Gases · Physics 2022-10-24 Piper Fowler-Wright , Brendon W. Lovett , Jonathan Keeling

We review the recent developments of the polariton physics in microcavities featuring the exciton-photon strong coupling at room-temperature, and leading to the achievement of room-temperature polariton condensates. Such cavities embed…

Mesoscale and Nanoscale Physics · Physics 2016-09-21 Thierry Guillet , Christelle Brimont

Recent years have seen significant developments in the study of strong light-matter coupling including the control of chemical reactions by altering the vibrational normal modes of molecules. In the vibrational strong coupling regime the…

Quantum Physics · Physics 2021-08-27 John Bonini , Johannes Flick

We study the elastic response of a stationarily driven system of a cavity field strongly coupled with molecular excitons, taking into account the main dissipation channels due to the finite cavity linewidth and molecular vibrations. We show…

Quantum Physics · Physics 2021-02-24 Kalle S. U. Kansanen , J. Jussi Toppari , Tero T. Heikkilä

When the collective coupling of the rovibrational states in organic molecules and confined electromagnetic modes is sufficiently strong, the system enters into vibrational strong coupling, leading to the formation of hybrid light-matter…

Mesoscale and Nanoscale Physics · Physics 2017-01-04 Javier del Pino , Francisco J. Garcia-Vidal , Johannes Feist

We investigate experimentally and theoretically the collective coupling between atoms with multilevel ground state manifolds and an optical cavity mode. In our setup the cavity field optically pumps populations among the ground states. The…

We show that strong electron-electron interactions in cavity-coupled quantum materials can enable collectively enhanced light-matter interactions with ultrastrong effective coupling strengths. As a paradigmatic example we consider a…

Strongly Correlated Electrons · Physics 2019-09-04 Martin Kiffner , Jonathan Coulthard , Frank Schlawin , Arzhang Ardavan , Dieter Jaksch

For a standard two-level atom coupled to the quantized field of a resonant cavity, finite temperature effects lead to thermal occupation of the cavity modes that obfuscates measurement of the quantum nature of the atom-light interaction. In…

Quantum Physics · Physics 2022-01-26 Lindsey F. Keary , Jonathan D. Pritchard

The rate of non-radiative decay between two molecular electronic states is succinctly described by the energy gap law, which suggests an approximately-exponential dependence of the rate on the electronic energy gap. Here, we inquire whether…

Chemical Physics · Physics 2023-04-14 Yong Rui Poh , Sindhana Pannir-Sivajothi , Joel Yuen-Zhou

Microcavity exciton-polariton condensates under additional transverse confinement constitute a flexible optical platform to study the coupling mechanism between confined nonequilibrium and nonlinear states of matter. Driven far from…

Starting from a microscopic model, we investigate the optical spectra of molecules in strongly-coupled organic microcavities examining how they might self-consistently adapt their coupling to light. We consider both rotational and…

Mesoscale and Nanoscale Physics · Physics 2016-03-25 Justyna A. Cwik , Peter Kirton , Simone De Liberato , Jonathan Keeling

The influence of multiple vibrational modes on current fluctuations in electron transport through single-molecule junctions is investigated. Our analysis is based on a generic model of a molecular junction, which comprises a single…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. Schinabeck , R. Härtle , H. B. Weber , M. Thoss

The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an…

Quantum Physics · Physics 2016-06-09 Felipe Herrera , Frank C. Spano