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The increased decay rate of a two-level system weakly coupled to an optical cavity, known as the Purcell effect, is a cornerstone of cavity QED. However, the effect of cavity coupling is not well understood if the two-level system is…

Quantum Physics · Physics 2023-06-19 Charlie Nation , Valentina Notararigo , Alexandra Olaya-Castro

The emergence of spatial and temporal coherence of light emitted from solid-state systems is a fundamental phenomenon, rooting in a plethora of microscopic processes. It is intrinsically aligned with the control of light-matter coupling,…

Selectively exciting target molecules to high vibrational states is inefficient in the liquid phase, which restricts the use of IR pumping to catalyze ground-state chemical reactions. Here, we demonstrate that this inefficiency can…

Chemical Physics · Physics 2022-12-27 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

In the regime of ensemble vibrational strong coupling (VSC), a macroscopic number $N$ of molecular transitions couple to each resonant cavity mode, yielding two hybrid light-matter (polariton) modes, and a reservoir of $N-1$ dark states…

Chemical Physics · Physics 2020-04-03 Jorge Campos-Gonzalez-Angulo , Raphael F. Ribeiro , Joel Yuen-Zhou

We calculate experimentally measurable signatures of quantum correlations in a coupled molecular dimer that strongly interacts with its vibrational environment. We investigate intensity and mode-resolved photon coincidences for different…

Quantum Physics · Physics 2025-12-16 Priyankar Banerjee , Adam Burgess , Julian Wiercinski , Moritz Cygorek , Erik M. Gauger

In recent years it has become clear that the transport of excitons and charge carriers in molecular systems can be enhanced by coherent coupling with photons, giving rise to the formation of hybrid excitations known as polaritons. Such…

Materials Science · Physics 2023-01-19 M. Balasubrahmaniyam , Arie Simkovich , Adina Golombek , Guy Ankonina , Tal Schwartz

Intercavity polaritons, hybrid quasiparticles with spatially separated photonic and excitonic components, provide a platform to engineer structured light-matter states. We show that resonant driving of the middle polariton branch leads to a…

The experimental observation of quantum phenomena in strongly correlated many particle systems is difficult because of the short length- and timescales involved. Obtaining at the same time detailed control of individual constituents appears…

Quantum Physics · Physics 2007-05-23 Michael J. Hartmann , Fernando G. S. L. Brandao , Martin B. Plenio

Real and momentum space spectrally resolved images of microcavity polariton emission in the regime of condensation are investigated under non resonant excitation using a laser source with reduced intensity fluctuations on the timescale of…

We discuss the electronic transport through molecules in the Kondo regime. We concentrate here on the influence of molecular vibrations. Two types of vibrations are investigated: (i) the breathing internal molecular modes, where the…

Mesoscale and Nanoscale Physics · Physics 2009-12-21 J. Mravlje , A. Ramsak

Strongly interacting atom-cavity systems within a network with many nodes constitute a possible realization for a quantum internet which allows for quantum communication and computation on the same platform. To implement such large-scale…

Atomic Physics · Physics 2016-11-23 Ralf Ritter , Nico Gruhler , Wolfram Pernice , Harald Kübler , Tilman Pfau , Robert Löw

A light-matter hybrid quasiparticle, called a polariton, is formed when molecules are strongly coupled to an optical cavity. Recent experiments have shown that polariton chemistry can manipulate chemical reactions. Polariton chemistry is a…

Chemical Physics · Physics 2024-01-11 Xinyang Li , Nicholas Lubbers , Sergei Tretiak , Kipton Barros , Yu Zhang

Until recently it was believed that photosynthesis, a fundamental process for life on earth, could be fully understood with semi-classical models. However, puzzling quantum phenomena have been observed in several photosynthetic…

Laser cooling of large, complex molecules is a long-standing goal, instrumental for enabling new quantum technology and precision measurements. A primary consideration for the feasibility of laser cooling, which determines the efficiency…

Hybrid light-matter states have transformed photonics, yet their realization with driven collective vibrations in biological systems remains an open challenge. Here we show that optically pumped R-phycoerythrin proteins at room temperature…

We provide a simple method that enables readily acquired experimental data to be used to predict whether or not a candidate molecular material may exhibit strong coupling. Specifically, we explore the relationship between the hybrid…

Cavity optomechanics aims to establish optical control over vibrations of mechanical systems, to heat, cool or to drive them toward coherent, or nonclassical states. This field was recently extended to include molecular optomechanics, which…

Quantum Physics · Physics 2023-06-28 Mikołaj K. Schmidt , Michael J. Steel

The soft character of organic materials leads to strong coupling between molecular nuclear and electronic dynamics. This coupling opens the way to control charge transport in organic electronic devices by inducing molecular vibrational…

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

Chemical Physics · Physics 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

Harnessing strong light-matter interactions to control chemical reactions in confined electromagnetic fields offers a promising route toward deepening our understanding of chemical dynamics at the collective quantum-mechanical level, with…

Chemical Physics · Physics 2026-01-21 Yaling Ke
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