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Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

We use quantum estimation theory to derive a thermodynamic uncertainty relation in Markovian open quantum systems, which bounds the fluctuation of continuous measurements. The derived quantum thermodynamic uncertainty relation holds for…

Statistical Mechanics · Physics 2020-07-30 Yoshihiko Hasegawa

Fluctuation theorems have elevated the second law of thermodynamics to a statistical realm by establishing a connection between time-forward and time-reversal probabilities, providing invaluable insight into nonequilibrium dynamics. While…

Quantum Physics · Physics 2025-06-05 Hui Li , Jie Xie , Hyukjoon Kwon , Yixin Zhao , M. S. Kim , Lijian Zhang

The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from…

Statistical Mechanics · Physics 2009-11-11 A. Engel , R. Nolte

The universal quantum work relation connects a functional of an arbitrary observable averaged over the forward process to the free energy difference and another functional averaged over the time-reversed process. Here, we ask the question…

Quantum Physics · Physics 2012-04-18 Arun Kumar Pati , Mamata Sahoo , Biswajit Pradhan

This chapter reviews an information theoretic approach to deriving quantum fluctuation theorems. When a thermal system is driven from equilibrium, random quantities of work are required or produced: the Crooks equality is a classical…

Quantum Physics · Physics 2019-05-01 Z. Holmes

The estimate of free energy changes based on Bennett's acceptance ratio method is examined in several limiting cases and compared with other estimates based on the Jarzynski equality and on the Crooks relation. While the absolute amount of…

Statistical Mechanics · Physics 2015-06-12 Seongjin Kim , Yong Woon Kim , Peter Talkner , Juyeon Yi

For time-dependent states generated by an external operation, a generalized free energy may be introduced by the relative entropy with respect to an equilibrium state realized after sufficient relaxation from the time-dependent states.…

Statistical Mechanics · Physics 2013-02-13 Naoko Nakagawa , Shin-ichi Sasa

To define the work performed on a driven quantum system in a physically sound way has turned out to be a truly non-trivial task, except in some special cases of limited applicability. This topic has been in a focus of intense research…

Statistical Mechanics · Physics 2012-12-27 Jukka P. Pekola , Paolo Solinas , Alexander Shnirman , Dmitri V. Averin

Non-equilibrium quantum thermodynamics is essential to describe new devices that operate far from the regime where the usual thermodynamical laws are obeyed. When quantum fluctuations dominate, defining and measuring work and heat, two…

Fluctuation theorems are relations constraining the out-of-equilibrium fluctuations of thermodynamic quantities like the entropy production that were initially introduced for classical or quantum systems in contact with a thermal bath. Here…

Quantum Physics · Physics 2019-02-27 Sreenath K. Manikandan , Cyril Elouard , Andrew N. Jordan

There are two related theorems which hold even in far from equilibrium, namely fluctuation theorem and Jarzynski equality. Fluctuation theorem states the existence of symmetry of fluctuation of entropy production, while Jarzynski equality…

Statistical Mechanics · Physics 2009-11-10 T. Monnai

Quantum work fluctuation theorems are known to hold when the work is defined as the difference between the outcomes of projective measurements carried out on the Hamiltonian of the system at the initial and the final time instants of the…

Statistical Mechanics · Physics 2023-07-20 Sourabh Lahiri , Subhashish Banerjee , A. M. Jayannavar

Fluctuation theorems have become an important tool in single molecule biophysics to measure free energy differences from non-equilibrium experiments. When significant coarse-graining or noise affect the measurements, the determination of…

Statistical Mechanics · Physics 2016-03-09 Reinaldo García-García , Sourabh Lahiri , David Lacoste

The problem of estimating a parameter of a quantum system through a series of measurements performed sequentially on a quantum probe is analyzed in the general setting where the underlying statistics is explicitly non-i.i.d. We present a…

Quantum Physics · Physics 2015-12-01 Daniel Burgarth , Vittorio Giovannetti , Airi N. Kato , Kazuya Yuasa

Universality of classical thermodynamics rests on the central limit theorem, due to which, measurements of thermal fluctuations are unable to reveal detailed information regarding the microscopic structure of a macroscopic body. When small…

Quantum Physics · Physics 2024-02-28 Lucas Chibebe Céleri , Łukasz Rudnicki

The influence of dissipation on the fluctuation statistics of the total energy is investigated through both a phenomenological and a stochastic model for dissipative energy-transfer through a cascade of states. In equilibrium the states…

Statistical Mechanics · Physics 2013-06-27 Eric Bertin , Peter C. W. Holdsworth

We present a new method to measure the work $w$ performed on a driven quantum system and to sample its probability distribution $P(w)$. The method is based on a simple fact that remained unnoticed until now: Work on a quantum system can be…

Quantum Physics · Physics 2015-06-22 Augusto J. Roncaglia , Federico Cerisola , Juan Pablo Paz

Fluctuation theorems, such as the Jarzynski equality and the Crooks relation, are effective tools connecting non-equilibrium work statistics and equilibrium free energy differences. However, detailed hands-on, reproducible protocols for…

We overcome one of Bell's objections to `quantum measurement' by generalizing the definition to include systems outside the laboratory. According to this definition a {\sl generalized quantum measurement} takes place when the value of a…

Quantum Physics · Physics 2009-11-07 Ting Yu , Ian C. Percival