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Implementation of Effective Core Potentials (ECPs) into the molecular scattering suite UKRmol+ is presented together with a set of calculations for a range of targets relevant for plasma modeling. Continuum description in scattering and…

We use the $R$-matrix with time-dependence method to study detachment from F$^-$ in circularly-polarized laser fields of infrared wavelength. By decomposing the photoelectron momentum distribution into separate contributions from detached…

Atomic Physics · Physics 2019-11-04 G. S. J. Armstrong , D. D. A. Clarke , A. C. Brown , H. W. van der Hart

Imaging structures at the molecular level is a fast developing interdisciplinary research field that spans across the boundaries of physics and chemistry. High spatial resolution images of molecules can be obtained with photons or ultrafast…

Atomic Physics · Physics 2016-09-01 R. Puthumpally-Joseph , J. Viau-Trudel , M. Peters , T. T. Nguyen-Dang , O. Atabek , E. Charron

The combination of photoelectron spectroscopy and ultrafast light sources is on track to set new standards for detailed interrogation of dynamics and reactivity of molecules. A crucial prerequisite for further progress is the ability to not…

Photoelectron spectra and photoelectron angular distributions obtained in photoionization reveal important information on e.g. charge transfer or hole coherence in the parent ion. Here we show that optimal control of the underlying quantum…

Atomic Physics · Physics 2016-01-20 R. Esteban Goetz , Antonia Karamatskou , Robin Santra , Christiane P. Koch

The application of a matrix-based reconstruction protocol for obtaining Molecular Frame (MF) photoelectron angular distributions (MFPADs) from laboratory frame (LF) measurements (LFPADs) is explored. Similarly to other recent works on the…

Chemical Physics · Physics 2021-09-01 Margaret Gregory , Paul Hockett , Albert Stolow , Varun Makhija

We calculate the asymptotic high-energy amplitude for electrons scattering at one ion as well as at two colliding ions, respectively, by means of perturbation theory. We show that the interaction with one ion eikonalizes and that the…

Nuclear Theory · Physics 2016-09-08 U. Eichmann , J. Reinhardt , W. Greiner , S. Schramm

The polarization of soft and tender X-rays serves as a widely utilized probe for investigating diverse physical properties, such as magnetic order in materials. However, experimental methods for determining the polarization of tender X-rays…

Materials Science · Physics 2026-03-26 Yoshiyuki Ohtsubo , Hiroaki Kimura

We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra,…

Chemical Physics · Physics 2016-08-24 Matthias Germann , Stefan Willitsch

Relativistic tunnel ionization of atoms by intense, elliptically polarized light is considered. The relativistic version of the Landau-Dykhne formula is employed. The general analytical expression is obtained for the relativistic…

Atomic Physics · Physics 2009-10-31 J. Ortner

We present a theoretical method for calculating multiphoton ionization amplitudes and cross sections of few-electron atoms. The present approach is based on an extraction of partial wave amplitudes from a scattering wave function, which is…

Atomic Physics · Physics 2021-04-21 Andrej Mihelic , Martin Horvat

We present the angular distribution of electrons knocked out from an atom in a fast charge particle collision at small momentum transfer. It is determined not only by dipole but also by quadrupole transitions, the contribution of which can…

Atomic Physics · Physics 2015-06-03 M. Ya. Amusia , L. V. Chernysheva , E. Z. Liverts

The photoionization spectrum of an atom in a magnetic field is calculated by combining R-matrix propagation with local adiabatic basis expansions. This approach considerably increases the speed and the energy range over which calculations…

Atomic Physics · Physics 2009-11-13 F. Mota-Furtado , P. F. O'Mahony

We present the extension of the time-dependent configuration interaction singles (TDCIS) method to the computation of the electron kinetic-energy spectrum in photoionization processes. Especially for strong and long ionizing light pulses…

Atomic Physics · Physics 2014-04-17 Antonia Karamatskou , Stefan Pabst , Yi-Jen Chen , Robin Santra

UKRmol-scripts is a set of Perl scripts to automatically run the UKRmol+ codes, a complex software suite based on the R-matrix method to calculate fixed-nuclei photoionization and electron- and positron-scattering for polyatomic molecules.…

The complex Kohn variational method is extended to compute light-driven electronic transitions between continuum wavefunctions in atomic and molecular systems. This development enables the study of multiphoton processes in the perturbative…

Atomic Physics · Physics 2018-08-15 Nicolas Douguet , Barry I. Schneider , Luca Argenti

We report on a combined experimental and theoretical study of XUV ionization of atomic argon in the presence of a near-infrared laser field. The resulting energy- and angle- resolved photoemission spectra have been described in the…

Multiple scattering theory is applied to low-energy electron collisions with a complex target formed of two molecular scatterers. The total T-matrix is expressed in terms of the T-matrix for each isolated molecule. We apply the approach to…

Chemical Physics · Physics 2009-11-13 D. Bouchiha , L. G. Caron , J. D. Gorfinkiel , L. Sanche

We investigate angular emission distributions of the 1s-photoelectrons of N$_2$ ionized by linearly polarized synchrotron radiation at $h \nu=40$ keV. As expected, nondipole contributions cause a very strong forward-backward asymmetry in…

The toolbox for imaging molecules is well-equipped today. Some techniques visualize the geometrical structure, others the electron density or electron orbitals. Molecules are many-body systems for which the correlation between the…