Related papers: Simple Molecules and Clocks
Recent developments in frequency metrology and optical clocks have been based on electronic transitions in atoms and singly charged ions as references. These systems have enabled relative frequency uncertainties at a level of a few parts in…
Precise molecular transition frequencies are of great interest in the test of fundamental physics and also in various applications. Two well isolated ro-vibrational transitions of $^{12}$C$^{16}$O at 1.57 $\mu$m, R(9) and R(10) in the…
The precise measurement of molecular vibrational transition frequencies is useful in the search for variation in the proton-to-electron mass ratio {\mu}. Homonuclear diatomic molecules are particularly advantageous for precise measurement…
Accurate measurements of different transition frequencies between atomic levels of the electronic and hyperfine structure over time are used to investigate temporal variations of the fine structure constant $\alpha$ and the…
As relative systematic frequency uncertainties in trapped-ion spectroscopy are approaching the low $10^{-18}$ range, motional frequency shifts account for a considerable fraction of the uncertainty budget. Micromotion, a driven motion…
Atomic clocks use atomic transitions as frequency references. The susceptibility of the atomic transition to external fields limits clock stability and introduces systematic frequency shifts. Here, we propose to realize an atomic clock that…
The systematic shifts of the transition frequencies in the molecular hydrogen ions are of relevance to ultra-high-resolution radio-frequency, microwave and optical spectroscopy of these systems, performed in ion traps. We develop the…
Dependence of transition frequencies on the fine structure constant $\alpha=e^2/\hbar c$ is calculated for several many-electron systems which are used or planned to be used in the laboratory search for the time variation of the fine…
In 2003 we have measured the absolute frequency of the $(1S, F=1, m_F=\pm 1) \leftrightarrow (2S, F'=1, m_F'=\pm 1)$ two-photon transition in atomic hydrogen. We observed a variation of $(-29\pm 57)$ Hz over a 44 months interval separating…
We report precise measurements of ground-state, $\lambda$-doublet microwave transitions in the hydroxyl radical molecule (OH). Utilizing slow, cold molecules produced by a Stark decelerator we have improved over the precision of the…
Transition frequencies between low-lying energy levels in a single trapped $^{138}$Ba$^{+}$ ion have been measured with laser spectroscopy referenced to an optical frequency comb. By extracting the frequencies of one-photon and two-photon…
We present improved theoretical calculations of transition frequencies for the fundamental transitions $(L\!=\!0,v\!=\!1)\to(L'\!=\!0,v'\!=\!0)$ in the hydrogen molecular ions H$_2^+$ and HD$^+$ with a relative uncertainty $4\cdot10^{-11}$…
Weak transitions in the (2,0) overtone band of the HD molecule at $\lambda = 1.38 \, \mu$m were measured in saturated absorption using the technique of noise-immune cavity-enhanced optical heterodyne molecular spectroscopy. Narrow…
Many modern theories predict that the fundamental constants depend on time, position, or the local density of matter. We develop a spectroscopic method for pulsed beams of cold molecules, and use it to measure the frequencies of microwave…
Transition frequencies of atoms and ions are among the most accurately accessible quantities in nature, playing important roles in pushing the frontiers of science by testing fundamental laws of physics, in addition to a wide range of…
The lack of coherent room-temperature sources in the whole terahertz spectral window (0.3-10 THz) has significantly hampered the growth of scientific and technological applications in this range. Among them, high-precision frequency…
Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…
We perform accurate calculations of the dependence of transition frequencies in two valence electron atoms and ions on a variation of the fine structure constant, alpha. The relativistic Hartree-Fock method is used with many-body…
Trapped ions are ideally suited for precision spectroscopy, as is evident from the remarkably low systematic uncertainties of single-ion clocks. The major weakness of these clocks is the long averaging time, necessitated by the low signal…
We show how one can measure the signal from slow jumps of a single molecule between metastable positions using a setup where the molecule is fixed to one lead, and one of the coupling strengths is controlled externally. Such a measurement…