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Conventional nonlinear spectroscopy uses classical light to detect matter properties through the variation of its response with frequencies or time delays. Quantum light opens up new avenues for spectroscopy by utilizing parameters of the…

Quantum Physics · Physics 2017-02-01 Konstantin E. Dorfman , Frank Schlawin , Shaul Mukamel

Nonlinear spectroscopy employs a series of laser pulses to interrogate dynamics in large interacting many-body systems, and has become a highly successful method for experiments in chemical physics. Current quantum optical experiments…

Quantum Physics · Physics 2016-10-19 Frank Schlawin , Manuel Gessner , Shaul Mukamel , Andreas Buchleitner

High-dimensional chaos displayed by multi-component systems with a single time-delayed feedback is shown to be accessible to time series analysis of a scalar variable only. The mapping of the original dynamics onto scalar time-delay systems…

Entangled two-photon spectroscopy is expected to provide advantages compared with classical protocols. It is achieved by coherently controlling the spectral properties of energy-entangled photons. We present here an experimental setup that…

Quantum Physics · Physics 2021-08-25 Stefan Lerch , André Stefanov

Quantum light is increasingly recognized as a promising resource for developing optical measurement techniques. Particular attention has been paid to enhancing the precision of the measurements beyond classical techniques by using…

Chemical Physics · Physics 2023-10-03 Yuta Fujihashi , Kuniyuki Miwa , Masahiro Higashi , Akihito Ishizaki

In the framework of linear optics, light fields do not interact with each other in a medium. Yet, when their field amplitude becomes comparable to the electron binding energies of matter, the nonlinear motion of these electrons emits new…

Recent theoretical studies in quantum spectroscopy have emphasized the potential of non-classical correlations in entangled photon pairs for selectively targeting specific nonlinear optical processes in nonlinear optical responses. However,…

Chemical Physics · Physics 2026-04-21 Yuta Fujihashi , Ozora Iso , Ryosuke Shimizu , Akihito Ishizaki

Interferometric measurements of high-harmonics induced by multiple laser fields in an emerging field of research that promises optimized yield of harmonics, and time and space-resolved nonlinear spectroscopy. Most of the measurements have…

High harmonic spectroscopy has the potential to combine attosecond temporal with sub-Angstrom spatial resolution of the early nuclear and multielectron dynamics in molecules. It involves strong field ionization of the molecule by the IR…

Atomic Physics · Physics 2013-08-08 Valeria Serbinenko , Olga Smirnova

We calculate the frequency-dispersed nonlinear transmission signal of a phase-shaped visible pulse to fourth order in the field. Two phase profiles, a phase-step and phase-pulse, are considered. Two dimensional signals obtained by varying…

Chemical Physics · Physics 2015-06-22 Rachel Glenn , Shaul Mukamel

Optical signals obtained by the material response to classical laser fields are given by nonlinear response functions which can be expressed by sums over various quantum pathways of matter. We show that some pathways can be selected by…

Materials Science · Physics 2009-02-17 O. Roslyak C. A. Marx , S. Mukamel

The ability to detect anomalies in time series is considered highly valuable in numerous application domains. The sequential nature of time series objects is responsible for an additional feature complexity, ultimately requiring specialized…

Machine Learning · Computer Science 2021-03-01 Gabriel Rodriguez Garcia , Gabriel Michau , Mélanie Ducoffe , Jayant Sen Gupta , Olga Fink

Ultra-fast and multi-dimensional spectroscopy gives a powerful looking glass into the dynamics of molecular systems. In particular two-dimensional electronic spectroscopy (2DES) provides a probe of coherence and the flow of energy within…

Quantum Physics · Physics 2021-03-31 André Anda , Jared H. Cole

Recent advances in techniques for generating quantum light have stimulated research on novel spectroscopic measurements using quantum entangled photons. One such spectroscopy technique utilizes non-classical correlations among entangled…

Chemical Physics · Physics 2021-07-28 Yuta Fujihashi , Akihito Ishizaki

The controlled interaction between a single, trapped, laser-driven atom and the mode of a high-finesse optical cavity allows for the generation of temporally separated, entangled light pulses. Entanglement between the photon-number…

Quantum Physics · Physics 2009-11-13 David Vitali , Priscilla Canizares , Juergen Eschner , Giovanna Morigi

Cells receive signaling molecules by receptors and relay information via sensory networks so that they can respond properly depending on the type of signal. Recent studies have shown that cells can extract multi-dimensional information from…

Biological Physics · Physics 2018-02-14 Yoshihiko Hasegawa

We develop an ultrafast frequency-resolved Raman spectroscopy with entangled photons for polyatomic molecules in condensed phases, to probe the electronic and vibrational coherences. Using quantum correlation between the photons, the signal…

Quantum Physics · Physics 2021-06-23 Zhedong Zhang , Tao Peng , Xiaoyu Nie , Girish S. Agarwal , Marlan O. Scully

The coherent interaction between a laser-driven single trapped atom and an optical high-finesse resonator allows to produce entangled multi-photon light pulses on demand. The mechanism is based on the mechanical effect of light. The degree…

Quantum Physics · Physics 2009-11-11 Giovanna Morigi , Juergen Eschner , Stefano Mancini , David Vitali

Interpretation of time-resolved spectroscopies such as transient absorption (TA) or two-dimensional (2D) spectroscopy often relies on the perturbative description of light-matter interaction. In many cases the third order of nonlinear…

Entangled photons exhibit non-classical light-matter interactions that create new opportunities in materials and molecular science. For example, in entangled two-photon absorption, the intensity-dependence scales linearly as if only one…

Optics · Physics 2020-05-15 Szilard Szoke , Hanzhe Liu , Bryce P. Hickam , Manni He , Scott K. Cushing
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