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Modifications of photoionization arising from resonant electron-electron correlations between neighbouring atoms in an atomic sample are studied. The sample contains atomic species A and B, with the ionization potential of A being smaller…

Atomic Physics · Physics 2015-06-04 B. Najjari , C. Müller , A. B. Voitkiv

Time-delays in the photoionization of molecules are investigated. As compared to atomic ionization, the time-delays expected from molecular ionization present a much richer phenomenon, with a strong spatial dependence due to the anisotropic…

Atomic Physics · Physics 2017-02-14 P. Hockett , E. Frumker , D. M. Villeneuve , P. B. Corkum

The evolution of electron wavepackets determines the course of many physical and chemical phenomena and attosecond spectroscopy aims to measure and control such dynamics in real-time. Here, we investigate radial electron wavepacket motion…

Atomic Physics · Physics 2015-09-04 Niranjan Shivaram , Xiao-Min Tong , Henry Timmers , Arvinder Sandhu

In this Letter, we investigate the non-dipole effects in time delay of photoelectrons emitted by multi-electron atoms, negative ions, and respective endohedrals. We present the necessary general formulas in the frame of the random phase…

Atomic Physics · Physics 2020-12-02 M. Ya. Amusia , L. V. Chernysheva

Amplitude and phase of wavepackets encode the dynamics of quantum systems. However, the rapidity of electron dynamics on the attosecond timescale has precluded their complete measurement in the time domain. Here, we demonstrate that…

We present a combined theoretical and experimental work investigating the angle-resolved phases of the photoionization process driven by a two-color field consisting of an attosecond pulse train and an infrared pulse in an ensemble of…

How fast processes can we measure? Attosecond physics address the limit of measurable time in science. Atomic X-ray excited states offers a way to study extremely fast dynamics with chemical specificity. In black phosphorous an X-ray…

Materials Science · Physics 2020-03-31 Fredrik O. L. Johansson , Yasmine Sassa , Tomas Edvinsson , Andreas Lindblad

We apply a fundamental definition of time delay, as the difference between the time a particle spends within a finite region of a potential and the time a free particle spends in the same region, to determine results for photoionization of…

Atomic Physics · Physics 2015-06-12 Jing Su , Hongcheng Ni , Andreas Becker , Agnieszka Jaroń-Becker

When intense light irradiates a quantum system, an ionizing electron recollides with its parent ion within the same light cycle and, during that very brief (few femtosecond) encounter, its kinetic energy sweeps from low to high energy and…

Atomic Physics · Physics 2020-10-13 Graham G. Brown , Dong Hyuk Ko , Chunmei Zhang , P. B. Corkum

The implementation of attosecond photoelectron-photoion coincidence spectroscopy for the investigation of atomic and molecular dynamics calls for a high-repetition-rate driving source combined with experimental setups characterized by…

Several recent attoclock experiments have investigated the fundamental question of a quantum mechanically induced time delay in tunneling ionization via extremely precise photoelectron momentum spectroscopy. The interpretations of those…

A new method to generate short wavelength Free Electron Laser output with modulated polarisation at attosecond timescales is presented. Simulations demonstrate polarisation switching timescales that are four orders of magnitude faster than…

Accelerator Physics · Physics 2021-01-20 J. Morgan , B. W. J. McNeil

We explore stimulated photo-association in the context of attosecond pump-probe schemes of atomic matter. An attosecond pulse -- the probe -- is used to induce photo-association of an electronic wave packet which had been created before,…

Atomic Physics · Physics 2009-11-13 Paula Rivière , Camilo Ruiz , Jan-Michael Rost

Isotopic substitution in molecular systems can affect fundamental molecular properties including the energy position and spacing of electronic, vibrational and rotational levels, thus modifying the dynamics associated to their coherent…

Ab initio simulations of a range of interferometric experiments are used to identify a strong dependence on multiphoton phase shifts in above-threshold ionization. A simple rule of thumb for interaction phase shifts is derived to explain…

Atomic Physics · Physics 2021-03-31 Mattias Bertolino , Jan Marcus Dahlström

Attosecond spectroscopy comprises several techniques to probe matter through electrons and photons. One frontier of attosecond methods is to reveal complex phenomena arising from quantum-mechanical correlations in the matter system, in the…

Modern quantum optics primarily operates in the quasistationary regime, isolated from the intrinsic timescales of ultrafast optical fields. Pushing these boundaries into the femtosecond and attosecond domains is a critical frontier. Here,…

We photoionize nitrogen molecules with a train of extreme ultraviolet attosecond pulses together with a weak infrared field. We measure the phase of the two-color two-photon ionization transition (molecular phase) for different states of…

Multi-electron dynamics in atoms and molecules very often occur on sub- to few-femtosecond timescales. The available intensities of extreme-ultraviolet (XUV) attosecond pulses have previously only allowed the time-resolved investigation of…

Attosecond chemistry involves developing strategies to manipulate electronic coherent waves in molecules, which can influence the outcome of photoinduced reactions. While recent progress in this field calls for investigations of…

Chemical Physics · Physics 2026-04-22 Evan Munaro-Langloÿs , Franck Lépine , Victor Despré