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Impurity diffusion coefficients are entirely obtained from a low cost classical molecular statics technique (CMST). In particular, we show how the CMST is appropriate in order to describe the impurity diffusion behavior mediated by a…

Materials Science · Physics 2013-11-06 Viviana P. Ramunni

The earlier-suggested master equation approach is used to develop the consistent statistical theory of diffusion in alloys using the five-frequency model of FCC alloys as an example. Expressions for the Onsager coefficients in terms of…

Statistical Mechanics · Physics 2013-10-28 V. G. Vaks , A. Yu. Stroev , I. R. Pankratov , I. A. Zhuravlev

Impurity diffusion coefficients are entirely obtained from a low cost classical molecular statics technique (CMST). In particular, we show how CMST is appropriate in order to describe the impurity diffusion behavior mediated by a vacancy…

Materials Science · Physics 2014-06-10 Viviana P. Ramunni

The problem of estimation of the tracer diffusion coefficients is solved by utilizing a novel tracer-interdiffusion couple technique even in the absence suitable radioisotope of one of the components and absence of reliable thermodynamic…

The diffusion kinetics in a CoCrFeMnNi high entropy alloy is investigated by a combined radiotracer--interdiffusion experiment applied to a pseudo-binary Co$_{15}$Cr$_{20}$Fe$_{20}$Mn$_{20}$Ni$_{25}$ /…

This work investigates solute transport due to self-interstitial defects and radiation induced segregation tendencies in dilute ferritic alloys, by computing the transport coefficients of each system based on ab initio calculations of…

Materials Science · Physics 2024-08-28 Luca Messina , Thomas Schuler , Maylise Nastar , Mihai-Cosmin Marinica , Pär Olsson

A formalism using a double Laplace Fourier transform of the transport equation yields the return probabilities of the vacancy in the vicinity of the tracer atom in the presence of solute-vacancy interactions of arbitrary extension. Studying…

Materials Science · Physics 2016-10-11 J. L. Bocquet

This research establishes a systematic, high-throughput computational framework for designing radiation-resistant, dilute ternary copper-based alloys by addition of solutes that bind to vacancies and reduce their mobility, thus promoting…

Materials Science · Physics 2026-03-03 Vaibhav Vasudevan , Thomas Schuler , Pascal Bellon , Robert Averback

Using an ab initio approach, we explore the stability of small vacancy and vacancy-chromium clusters in dilute body-centred cubic Fe-Cr alloys. To explain experimental observations described in C.D. Hardie et al., J. Nucl. Mater. 439, 33…

Materials Science · Physics 2018-03-14 M. Yu. Lavrentiev , D. Nguyen-Manh , S. L. Dudarev

Tracer diffusion of the substitutional components in (CoCrFeNiMn)$_{1-x}$C$_x$ high-entropy alloys with x = 0.002, 0.005 and 0.008 (in at. fractions) is measured at elevated temperatures from 1173 to 1373 K. Two different characteristic…

Materials Science · Physics 2021-12-21 O. A. Lukianova , V. Kulitckii , Z. Rao , Z. Li , G. Wilde , S. V. Divinski

First principles density functional theory (DFT) investigation of native interstitials and the associated self-diffusion mechanisms in {\alpha}-Cr2O3 reveals that interstitials are more mobile than vacancies of corresponding species. Cr…

Recent density functional theory (DFT) calculations by Foerst et al. have predicted that vacancies in both low and high carbon steels have a carbon dimer bound to them. This is likely to change the thinking of metallurgists in the kinetics…

Materials Science · Physics 2015-06-15 A. T. Paxton , C. Elsaesser

We develop a version of the vacancy mediated tracer diffusion model, which follows the properties of the physical system of In atoms diffusing within the top layer of Cu(001) terraces. This model differs from the classical tracer diffusion…

Statistical Mechanics · Physics 2007-05-23 E. Somfai , R. van Gastel , S. B. van Albada , W. van Saarloos , J. W. M. Frenken

Estimating the diffusion coefficients experimentally in a four-component inhomogeneous alloy following the conventional diffusion couple method by intersecting three couples at the same composition is difficult unless a small composition…

Materials Science · Physics 2020-05-19 Anuj Dash , Neelamegan Esakkiraja , Aloke Paul

Tracer diffusion and hydrodynamic dispersion in two-dimensional fractures with self-affine roughness is studied by analytic and numerical methods. Numerical simulations were performed via the lattice-Boltzmann approach, using a new boundary…

Statistical Mechanics · Physics 2016-08-31 German Drazer , Joel Koplik

Impurity diffusion in Zr is potentially important for many applications of Zr alloys, and in particular for their use of nuclear reactor cladding. However, significant uncertainty presently exists about which elements are vacancy vs.…

Materials Science · Physics 2018-05-14 Hai-Jin Lu , Henry Wu , Nan Zou , Xiao-Gang Lu , Yan-Lin He , Dane Morgan

The mobility of vacancies in alloys may limit dislocation climb. Using a combined density functional theory and kinetic Monte Carlo approach we investigate vacancy diffusion in Ni-Re, Ni-W, and Ni-Ta binary alloys up to 10 at.% solute…

Materials Science · Physics 2018-12-13 Maximilian Grabowski , Jutta Rogal , Ralf Drautz

Transport phenomena are studied for a binary (AB) alloy on a rigid square lattice with nearest-neighbor attraction between unlike particles, assuming a small concentration $c_v$ of vacancies $V$ being present, to which $A(B)$ particles can…

Statistical Mechanics · Physics 2007-05-23 A. De Virgiliis , K. Binder

Diffusion plays a key role in microstructure evolution at multicomponent alloys: diffusion controls the kinetics of phase transformations and alloy homogenization. This study aims at developing computationally efficient approaches to…

Materials Science · Physics 2024-11-05 Timofei Miryashkin , Ivan Novoselov , Alexey Yanilkin

The experimental data in the literature for the hcp phase of the Mg-Al-Zn ternary system have been critically reviewed. Based on the concentration profiles from the literature, the diffusion coefficients have been re-extracted using the…

Materials Science · Physics 2016-08-09 J. Wang , N. Li , C. Wang , J. I. Beltran , J. LLorca , Y. Cui
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