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Related papers: Indirect ultraviolet photodesorption from CO:N2 bi…

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Observations of dark cloud cores have been carried out in the mid-infrared using ISOCAM and in the far-infrared using ISOPHOT, both aboard the Infrared Space Observatory. The cores are in most cases detected in emission at 200 and 170…

Astrophysics · Physics 2007-05-23 Aurore Bacmann , Philippe Andre , Derek Ward-Thompson

We model the temperature and chemical structure of molecular clouds as a function of depth into the cloud, assuming a cloud of constant density n illuminated by an external FUV (6 eV < E < 13.6 eV) flux G_0 (scaling factor in multiples of…

Astrophysics · Physics 2011-02-11 David Hollenbach , Michael J. Kaufman , Edwin A. Bergin , Gary J. Melnick

In astrochemical exploration, infrared (IR) spectroscopy is vital for understanding the composition and structure of ice in various space environments. This article explores the impact of incident angles on IR spectroscopy, focusing on…

Instrumentation and Methods for Astrophysics · Physics 2025-02-25 Cristóbal González Díaz , Hector Carrascosa , Guillermo M. Muñoz Caro

Cosmic-ray-induced sputtering is one of the important desorption mechanisms at work in astrophysical environments. The chemical evolution observed in high-density regions, from dense clouds to protoplanetary disks, and the release of…

Astrophysics of Galaxies · Physics 2021-04-07 E. Dartois , M. Chabot , T. Id Barkach , H. Rothard , P. Boduch , B. Augé , A. N. Agnihotri

The efficiency of radial transport of icy solid material from outer disk to the inner disk is currently unconstrained. Efficient radial transport of icy dust grains could significantly alter the composition of the gas in the inner disk. Our…

Earth and Planetary Astrophysics · Physics 2018-04-04 Arthur D. Bosman , Alexander G. G. M. Tielens , Ewine F. van Dishoeck

Freeze-out of the gas phase elements onto cold grains in dense interstellar and circumstellar media builds up ice mantles consisting of molecules that are mostly formed in situ (H2O, NH3, CO2, CO, CH3OH, and more). This review summarizes…

Astrophysics of Galaxies · Physics 2015-09-23 Adwin Boogert , Perry Gerakines , Douglas Whittet

We report the optical absorption characteristics and the photocurrent spectra for large-area molecular junctions containing different molecular structures and thicknesses. Through experimental assessment of the optical absorption of…

Chemical Physics · Physics 2021-04-12 V Mukundan , J A Fereiro , R L McCreery , A J Bergren

The H II region W40 harbors a small group of young, hot stars behind roughly 9 magnitudes of visual extinction. We have detected gaseous carbon monoxide (CO) and diatomic carbon (C_2) in absorption toward the star W40 IRS 1a. The 2-0 R0,…

Astrophysics · Physics 2009-10-31 R. Y. Shuping , T. P. Snow , R. Crutcher , B. L. Lutz

Core-excitation of water ice releases many different molecules and ions in the gas phase. Studying these desorbed species and the underlying mechanisms can provide useful information on the effects of X-ray irradiation in ice. We report a…

Chemical Physics · Physics 2020-10-20 R. Dupuy , G. Féraud , M Bertin , C. Romanzin , L. Philippe , T. Putaud , X. Michaut , R. Cimino , V. Baglin , J. -H. Fillion

We present a computational study into the adsorption properties of CO$_2$ on amorphous and crystalline water surfaces under astrophysically relevant conditions. Water and carbon dioxide are two of the most dominant species in the icy…

Astrophysics of Galaxies · Physics 2017-09-13 L. J. Karssemeijer , G. A. de Wijs , H. M. Cuppen

Two-pulse correlation experiments performed using pulses of different intensities on Pd(111) with different CO coverages showed that the CO photodesorption probability depends on whether the strong or the weak pulse arrives first to the…

The direct study of molecular gas in inner protoplanetary disks is complicated by uncertainties in the spatial distribution of the gas, the time-variability of the source, and the comparison of observations across a wide range of…

CO2 is the third most abundant ice component found on dust grains in star-forming regions and a common ingredient of exoplanet atmospheres. Characterization of its adsorption properties on ices through the binding energy (BE) is essential…

Earth and Planetary Astrophysics · Physics 2026-05-14 Alicja Bulik , V. Bariosco , E. Mates-Torres , P. Ugliengo , K. Furuya , C. Ceccarelli , A. Rimola

CO oxidation on Ru(0001) is a long-standing example of a reaction that, being thermally forbidden in ultra-high vacuum, can be activated by femtosecond laser pulses. In spite of its relevance, the precise dynamics of the photo-induced…

Materials Science · Physics 2022-09-08 Auguste Tetenoire , Christopher Ehlert , J. I. Juaristi , Peter Saalfrank , M. Alducin

The high resolution (R=25,000) infrared M band spectrum of the massive protostar NGC 7538 : IRS9 shows a narrow absorption feature at 4.779 um (2092.3 cm-1) which we attribute to the vibrational stretching mode of the 13CO isotope in pure…

Astrophysics · Physics 2009-11-07 A. C. A. Boogert , G. A. Blake , A. G. G. M. Tielens

Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…

Isotope effects associated with gas phase N2 photolysis are used to interpret Martian atmospheric evolution, icy satellite atmospheric chemistry and meteorite isotopic anomalies from nebular N2 photochemistry. To interpret observations at…

Chemical Physics · Physics 2011-10-18 B. H. Muskatel , F. Remacle , Mark. H. Thiemens , R. D. Levine

\ Nitrous oxide (N$_2$O) ice is likely to exist in trans-Neptunian objects such as Pluto and Triton, potentially formed through ultraviolet (UV) radiation from the Sun or cosmic ray irradiation of N$_2$ and CO ices. However, the…

Earth and Planetary Astrophysics · Physics 2025-04-04 Daiki Takama , Ryoichi Koga , Shohei Negishi , Biao Zhao , Yuan Li , Yasuhiro Hirahara , Fumiyuki Ito

The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is…

JWST has shown that CO2 and CO are common on the surfaces of objects in the Kuiper belt and have apparent surface coverages even higher than that of water ice, though water ice is expected to be significantly more abundant in the bulk…

Earth and Planetary Astrophysics · Physics 2023-06-30 Michael E. Brown , Wesley C. Fraser