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Brownian motion and viscoelasticity of semiflexible polymers is a subject that has been studied for many years. Still, rigorous analysis has been hindered due to the difficulty in handling the constraint that polymer chains cannot be…

Soft Condensed Matter · Physics 2024-05-22 Zhongqiang Xiong , Ryohei Seto , Masao Doi

We study pressurised self-avoiding ring polymers in two dimensions using Monte Carlo simulations, scaling arguments and Flory-type theories, through models which generalise the model of Leibler, Singh and Fisher [Phys. Rev. Lett. Vol. 59,…

Statistical Mechanics · Physics 2011-05-12 Mithun K. Mitra , Gautam I. Menon , R. Rajesh

The influence of an external flow on the relaxation dynamics of a single polymer is investigated theoretically and numerically. We show that a pronounced dynamical slowdown occurs in the vicinity of the coil-stretch transition, especially…

Chaotic Dynamics · Physics 2007-05-23 Antonio Celani , Alberto Puliafito , Dario Vincenzi

In a recent letter, a simple method was proposed to generate solvable models that predict the critical properties of statistical systems in hyperspherical geometries. To that end, it was shown how to reduce a random walk in $D$ dimensions…

High Energy Physics - Lattice · Physics 2018-07-06 S. Boettcher

We study the dynamics of one-dimensional active particles confined in a double-well potential, focusing on the escape properties of the system, such as the mean escape time from a well. We first consider a single-particle both in near and…

Statistical Mechanics · Physics 2022-03-15 Lorenzo Caprini , Fabio Cecconi , Umberto Marini Bettolo Marconi

We study the dynamics of the passage of a polymer through a membrane pore (translocation), focusing on the scaling properties with the number of monomers $N$. The natural coordinate for translocation is the number of monomers on one side of…

Soft Condensed Matter · Physics 2009-11-07 Jeffrey Chuang , Yacov Kantor , Mehran Kardar

We consider an inextensible, semiflexible polymer or worm-like chain, with persistence length $P$ and contour length $L$, fluctuating in a cylindrical channel of diameter $D$. In the regime $D\ll P\ll L$, corresponding to a long, tightly…

Soft Condensed Matter · Physics 2015-05-19 Theodore W. Burkhardt , Yingzi Yang , Gerhard Gompper

We have developed a theory of polymer entanglement using an extended Cahn-Hilliard functional, with two extra terms. One is a nonlocal attractive term, operating over mesoscales, which is interpreted as giving rise to entanglement, and the…

Soft Condensed Matter · Physics 2008-11-26 Shirish M. Chitanvis

We consider the escape of a flexible, self-avoiding polymer chain out of a confined geometry. By means of simulations, we demonstrate that the translocation time can be described by a simple scaling law that exhibits a nonlinear dependence…

Soft Condensed Matter · Physics 2009-11-11 Angelo Cacciuto , Erik Luijten

Building on the results of our computer simulation (ArXiv cond-mat/0503573)we develop a theoretical description of the motion of a bead, embedded in a network of semiflexible polymers, and responding to an applied force. The theory reveals…

Soft Condensed Matter · Physics 2013-05-29 N. Ter-Oganessian , D. A. Pink , A. Boulbitch

We investigate the crystallization of a single, flexible homopolymer chain using transition path sampling (TPS). The chain consists of N identical spherical monomers evolved according to Langevin dynamics. While neighboring monomers are…

Soft Condensed Matter · Physics 2016-08-17 Christian Leitold , Christoph Dellago

The non-equilibrium structural and dynamical properties of flexible polymers confined in a square microchannel and exposed to a Poiseuille flow are investigated by mesoscale simulations. The chain length and the flow strength are…

Soft Condensed Matter · Physics 2009-11-13 L. Cannavacciuolo , R. G. Winkler , G. Gompper

The motion involved in barrier crossing for protein folding are investigated in terms of the chain dynamics of the polymer backbone, completing the microscopic description of protein folding presented in the previous paper. Local reaction…

Soft Condensed Matter · Physics 2009-10-31 John J. Portman , Shoji Takada , Peter G. Wolynes

The thermal activation process by which a system passes from one local energy minimum to another is a recurring motif in physics, chemistry, and biology. For instance, biopolymer chains are typically modeled in terms of energy landscapes,…

Statistical Mechanics · Physics 2024-10-01 Sudeep Adhikari , K. S. D. Beach

The purpose of this paper is to investigate several analytical methods of solving first passage (FP) problem for the Rouse model, a simplest model of a polymer chain. We show that this problem has to be treated as a multi-dimensional…

Soft Condensed Matter · Physics 2015-12-09 Jing Cao , Jian Zhu , Zuowei Wang , Alexei E. Likhtman

In this paper we extend the Gaussian self-consistent method to permit study of the equilibrium and kinetics of conformational transitions for heteropolymers with any given primary sequence. The kinetic equations earlier derived by us are…

Soft Condensed Matter · Physics 2009-10-31 E. G. Timoshenko , Yu. A. Kuznetsov , K. A. Dawson

The achievement of local cooling is a prominent goal in the design of functional transport nanojunctions. One generic mechanism for local cooling is driving a system through a local uphill potential step. In this paper we examine the…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Philip R. Schiff , Abraham Nitzan

We consider an inextensible, semiflexible polymer or worm-like chain which is confined in the transverse direction by a parabolic potential and subject to a longitudinal force at the ends, so that the polymer is stretched out and…

Soft Condensed Matter · Physics 2015-05-28 Theodore W. Burkhardt

My means of extensive Monte Carlo simulations the mean radius of gyration and the end-to-end distance are calculated for a single chain in a solvent over a broad range of volume fractions, pressures and temperatures. Our results indicate…

Statistical Mechanics · Physics 2007-05-23 C. Ortiz-Estrada , G. Luna-Barcenas , G. Ramirez-Santiago , I. C. Sanchez , J. F. Alvarado

A correlation between two noise processes driving the thermally activated particles in a symmetric triple well potential, may cause a symmetry breaking and a difference in relative stability of the two side wells with respect to the middle…

Chemical Physics · Physics 2015-06-05 Pulak Kumar Ghosh , Bidhan Chandra Bag , Deb Shankar Ray