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We present exact and analytically accurate results for the problem of a flexible polymer chain in shear flow. Under such a flow the polymer tumbles, and the probability distribution of the tumbling times $\tau$ of the polymer decays…

Statistical Mechanics · Physics 2008-11-13 Dibyendu Das , Sanjib Sabhapandit

We study the dynamics of a knot in a semiflexible polymer confined to a narrow channel of width comparable to the polymers' persistence length. Using a combination of Brownian dynamics simulations and a coarse-grained stochastic model, we…

Soft Condensed Matter · Physics 2008-08-14 Wolfram Mobius , Erwin Frey , Ulrich Gerland

We study the diffusion of gas molecules through a two-dimensional network of polymers with the help of Monte Carlo simulations. The polymers are modeled as non-interacting random walks on the bonds of a two-dimensional square lattice, while…

Soft Condensed Matter · Physics 2007-05-23 B. Schmittmann , Manoj Gopalakrishnan , R. K. P. Zia

Polymer chains undergoing a continuous adsorption-desorption transition are studied through extensive computer simulations. A three-dimensional self-avoiding walk lattice model of a polymer chain grafted onto a surface has been treated for…

Statistical Mechanics · Physics 2018-05-30 P. H. L. Martins , J. A. Plascak , M. Bachmann

We present simulation data for the motion of a polymer chain through a regular lattice of impenetrable obstacles (Evans-Edwards model). Chain lengths range from N=20 to N=640, and time up to $10^{7}$ Monte Carlo steps. For $N \geq 160$ we…

Soft Condensed Matter · Physics 2016-08-17 A. Baumgärtner , U. Ebert , L. Schäfer

The non-linear response of entangled polymers to shear flow is complicated. Its current understanding is framed mainly as a rheological description in terms of the complex viscosity. However, the full picture requires an assessment of the…

Computational Physics · Physics 2018-08-21 Airidas Korolkovas , Philipp Gutfreund , Max Wolff

The properties of a semiflexible polymer with fixed ends exposed to oscillatory shear flow are investigated by simulations. The two-dimensionally confined polymer is modeled as a linear bead-spring chain, and the interaction with the fluid…

Soft Condensed Matter · Physics 2021-12-14 Antonio Lamura , Roland G. Winkler

The conformational and dynamical properties of active polymers in solution are determined by the nature of the activity, and the behavior of polymers with self-propelled, active Brownian particle-type monomers differs qualitatively from…

Soft Condensed Matter · Physics 2020-05-27 Aitor Martin-Gomez , Thomas Eisenstecken , Gerhard Gompper , Roland G. Winkler

Hydrodynamic interactions as modeled by Multi-Particle Collision Dynamics can dramatically influence the dynamics of fully flexible, ring-shaped polymers in ways not known for any other polymer architecture or topology. We show that steady…

Soft Condensed Matter · Physics 2019-09-09 M. Liebetreu , C. N. Likos

We propose a two-body spherically symmetric (isotropic) potential such that particles interacting by the potential self assemble into linear semiflexible polymeric chains without branching. By suitable control of the potential parameters we…

Soft Condensed Matter · Physics 2018-05-09 Alex Abraham , Apratim Chatterji

I develop a kinetic mechanism to explain chain folding in polymer crystallization which is based on the competition between the formation of stems, which is due to frequent occupations of trans states along the chains in the supercooled…

Soft Condensed Matter · Physics 2014-09-23 S. Stepanow

We study flexible polymer macromolecules in a crowded (porous) environment, modelling them as self-attracting self-avoiding walks (SASAW) on site-diluted percolative lattices in space dimensions d=2, 3. The influence of stretching force on…

Soft Condensed Matter · Physics 2009-12-09 V. Blavatska , W. Janke

To study the cooling behavior and the glass transition of polymer melts in bulk and with free surfaces a coarse-grained weakly semi-flexible polymer model is developed. Based on a standard bead spring model with purely repulsive…

Soft Condensed Matter · Physics 2019-09-09 Hsiao-Ping Hsu , Kurt Kremer

The transport of polymers with folded configurations across membrane pores is investigated theoretically by analyzing simple discrete stochastic models. The translocation dynamics is viewed as a sequence of two events: motion of the folded…

Statistical Mechanics · Physics 2009-11-13 Stanislav Kotsev , Anatoly B. Kolomeisky

We consider the thermal breakage of a tethered polymer chain of discrete segments coupled by Morse potentials under constant tensile stress. The chain dynamics at the onset of fracture is studied analytically by Kramers-Langer…

Soft Condensed Matter · Physics 2010-06-24 A. Ghosh , D. I. Dimitrov , V. G. Rostiashvili , A. Milchev , T. A. Vilgis

Polymer solutions subject to pressure driven flow and in nanoscale slit pores are systematically investigated using the dissipative particle dynamics approach. We investigated the effect of molecular weight, polymer concentration and flow…

Soft Condensed Matter · Physics 2015-06-25 J. A. Millan , W. Jiang , M. Laradji , Y. Wang

Transport of tracer particles through mesh-like environments such as biological hydrogels and polymer matrices is ubiquitous in nature. These tracers could be passive, such as colloids or active (self-propelled), such as synthetic…

Soft Condensed Matter · Physics 2022-12-08 Praveen Kumar , Rajarshi Chakrabarti

The density crossover scaling of various thermodynamic properties of solutions and melts of self-avoiding and highly flexible polymer chains without chain intersections confined to strictly two dimensions is investigated by means of…

Soft Condensed Matter · Physics 2012-09-03 N. Schulmann , H. Meyer , P. Polińska , J. Baschnagel , J. P. Wittmer

The drag of turbulent flows can be drastically decreased by addition of small amounts of high molecular weight polymers. While drag reduction initially increases with polymer concentration, it eventually saturates to what is known as the…

Fluid Dynamics · Physics 2018-03-28 George H. Choueiri , Jose M. Lopez , Bjoern Hof

We study the localisation of lattice polymer models near a permeable interface in two dimensions. Localisation can arise due to an interaction between the polymer and the interface, and can be altered by a preference for the bulk solvent on…

Statistical Mechanics · Physics 2024-07-24 C J Bradly , N R Beaton , A L Owczarek