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Charge transfer in polymer devices represents a crucial, though highly inaccessible stage of photocurrent generation. In this article we propose studying the properties and behaviour of organic solar cells through the modification of…

Applied Physics · Physics 2018-09-27 S. Oviedo-Casado , A. Urbina , J. Prior

An isolated single-junction solar cell's temperature in outer space depends only on its radiation exchange with its environment. We consider a cell with zero emissivity below its bandgap and unity above it -- an idealization so far…

Applied Physics · Physics 2021-01-07 Ido Frenkel , Avi Niv

We investigate the electronic dynamics of model organic photovoltaic (OPV) system consisting of polyphenylene vinylene (PPV) oligomers and [6,6]-phenyl C61-butyric acid methylester (PCBM) blend using a mixed molecular mechanics/quantum…

Materials Science · Physics 2015-09-21 Eric R. Bittner , Allen C. Kelley

Inorganic ferroelectric perovskite oxides are more stable than hybrid perovskites. However, their solar energy harvest efficiency is not so good. Here, by constructing a series of BiFeO3 based devices (solar cells), we investigated three…

Materials Science · Physics 2020-03-27 Chao He , Guocai Liu , Huiyan Zhao , Kun Zhao , Zuju Ma , Xingtao An

Bulk heterojunction (BHJ) organic solar cells have made remarkable inroads towards 20% efficiency, yet nonradiative recombination losses ({\Delta}Vnr) remain high compared to silicon and perovskite photovoltaics. Interfaces buried within…

Materials Science · Physics 2024-06-18 Gaurab J. Thapa , Mihirsinh Chauhan , Jacob P. Mauthe , Daniel B. Dougherty , Aram Amassian

The thermodynamic limit for the efficiency of solar cells is predominantly defined by the energy bandgap of the used semiconductor. In case of organic solar cells both energetics and kinetics of three different species play role: excitons,…

Applied Physics · Physics 2021-07-02 Oskar J Sandberg , Ardalan Armin

We investigate nongeminate recombination in organic solar cells based on copper phthalocyanine (CuPc) and C$_{60}$. Two device architectures, the planar heterojunction (PHJ) and the bulk heterojunction (BHJ), are directly compared in view…

Applied Physics · Physics 2021-06-21 A. Foertig , A. Wagenpfahl , T. Gerbich , D. Cheyns , V. Dyakonov , C. Deibel

Under open-circuit condition, the current is not extracted and the photogenerated carriers in principle disappear only by recombination. We study the open-circuit voltage $V_{\rm OC}$ and transient photovoltage under the effect of bulk…

Materials Science · Physics 2014-01-03 Kazuhiko Seki , Kazuhiro Marumoto , M. Tachiya

For many years the faith of organic photovoltaics has been linked to the one of fullerene, since fullerene has been considered the electron-acceptor of choice in bulk heterojunctions solar cells. In the last years, the number of molecules…

Materials Science · Physics 2020-08-11 Andrea Farina , Giuseppe M. Paternò , Francesco Scotognella

Hot-carrier solar cells use the photon excess energy, that is, the energy exceeding the absorber bandgap, to do additional work. These devices have the potential to beat the upper limit for the photovoltaic power conversion efficiency set…

Materials Science · Physics 2025-02-21 Priya Viji , Constantin Tormann , Clemens Göhler , Martijn Kemerink

The radiative recombination, Shokley-Read recombination, frontal-surface and rear-surface recombination and the recombination at the heterojunction boundaries and the recombination in the space charge region are considered in the…

Materials Science · Physics 2013-07-04 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

We present a pipeline to study the device performance of organic solar cells in silico. We introduce a mathematical model that includes the dynamics of excitons as well as their dissociation at bulk heterojunctions within the nanomorphology…

Electrical transients enabled by optical excitation and electric detection provide a distinctive opportunity to study the charge transport, recombination and even the hysteresis of a solar cell in a much wider time window ranging from…

We studied the recombination dynamics of charge carriers in organic bulk heterojunction solar cells made of the blend system poly(2,5-bis(3-dodecyl thiophen-2-yl) thieno[2,3-b]thiophene) (pBTCT-C12):[6,6]-phenyl-C61-butyric acid methyl…

We propose a model to explain the reduced bimolecular recombination rate found in state-of-the-art bulk heterojunction solar cells. When compared to the Langevin recombination, the experimentally observed rate is one to four orders of…

Materials Science · Physics 2009-08-09 C. Deibel , A. Wagenpfahl , V. Dyakonov

In this perspective, we explore the insights into the device physics of perovskite solar cells gained from modeling and simulation of these devices. We discuss a range of factors that influence the modeling of perovskite solar cells,…

Applied Physics · Physics 2020-08-04 Nir Tessler , Yana Vaynzof

Conventional models of planar and bulk heterojunction organic solar cells have been extended by introducing doping in the active layer. We have studied the performance of organic solar cells as a function of dopant concentration. For bulk…

Materials Science · Physics 2015-06-03 V. A. Trukhanov , V. V. Bruevich , D. Yu. Paraschuk

III-V materials show a wide range of gaps making them ideal for the design of high efficiency solar cells. This chapter reviews relevant growth methods and material properties of these materials and discusses methods of combining…

Materials Science · Physics 2013-01-08 James P. Connolly , Denis Mencaraglia

Non-equilibrium transport properties and energy conversion performance of a molecular photo-voltaic cell are analyzed using the Lindblad master equation within the open quantum systems approach. The method allows us to calculate the…

Mesoscale and Nanoscale Physics · Physics 2015-04-09 Shigeru Ajisaka , Bojan Zunkovic , Yonatan Dubi

Bulk-heterojunction (BHJ) non-fullerene organic solar cells prepared from sequentially deposited donor and acceptor layers (sq-BHJ) have recently been promising to be highly efficient, environmentally friendly, and compatible with large…