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We consider transitions of electron holes (vacancies in otherwise filled shells of atomic systems) in multiply-charged ions that, due to level-crossing of the holes, have frequencies within the range of optical atomic clocks. Strong E1…

Atomic Physics · Physics 2011-07-21 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…

Chemical Physics · Physics 2025-11-17 Carsten Zülch , Konstantin Gaul , Robert Berger

The goals of this study are 1) to test the best theoretical transition probabilities for Ca I (a relatively light alkaline earth spectrum) from a modern ab initio calculation using configuration interaction plus many body perturbation…

Solar and Stellar Astrophysics · Physics 2021-08-18 E. A. Den Hartog , J. E. Lawler , C. Sneden , J. J. Cowan , I. U. Roederer , J. Sobeck

Extremely variable quasars can also show strong changes in broad-line emission strength and are known as changing-look quasars (CLQs). To study the CLQ transition mechanism, we present a pilot sample of CLQs with X-ray observations in both…

QSO absorption spectra provide an extremely useful probe of possible cosmological variation in various physical constants. Comparison of H I 21cm absorption with corresponding molecular (rotational) absorption spectra allows us to constrain…

Astrophysics · Physics 2009-08-18 M. T. Murphy , J. K. Webb , V. V. Flambaum , M. J. Drinkwater , F. Combes , T. Wiklind

We calculated the dependence of the transition frequencies on the fine-structure constant $\alpha$ ($q$-factors) for Ni~II. Nickel is one of the few elements with high sensitivity to $\alpha$-variation, whose lines are observed at high…

Atomic Physics · Physics 2014-11-03 E. A. Konovalova , M. G. Kozlov , R. T. Imanbaeva

We demonstrate the first application of a liquid-metal ion source for collinear laser spectroscopy in proof-of-principle measurements on naturally abundant In$^+$. The superior beam quality, i.e., the actively stabilized current and energy…

Modern resonant spectroscopic experiments to measure transition frequencies in atoms have reached a level where a meticulous description of all aspects of the processes under study has become obligatory. The precision achieved in the…

Atomic Physics · Physics 2025-09-11 D. Solovyev , T. Zalialiutdinov , A. Anikin , L. Labzowsky

Spectra of quasars result primarily from interactions of natural light with atomic hydrogen. A visible absorption of a sharp and saturated spectral line in a gas requires a low pressure, so a long path without blushing as a cosmological…

Instrumentation and Methods for Astrophysics · Physics 2015-12-31 Jacques Moret-Bailly

In this paper, we present the details of the ab initio high-precision configuration interaction and many-body perturbation theory calculations that were used in a previous work to place limits on the dependence of the fine-structure…

Atomic Physics · Physics 2013-12-06 A. Ong , J. C. Berengut , V. V. Flambaum

Relativistic energy shifts of the low energy levels of Fe have been calculated using the Dirac-Hartree-Fock and configuration interaction techniques. The results are to be used in the search for the space-time variation of the fine…

Atomic Physics · Physics 2009-11-13 V. A. Dzuba , V. V. Flambaum

We present the results of a systematic search for quasars in the Catalina Real-time Transient Survey exhibiting both strong photometric and spectroscopic variability over a decadal baseline. We identify 73 sources with specific patterns of…

Detecting or placing upper limits on spacetime variations of fundamental constants requires quantifying every potential source of uncertainty. We continue our previous study into the impact of continuum variations on measurements of the…

Cosmology and Nongalactic Astrophysics · Physics 2024-10-02 John K. Webb , Chung-Chi Lee , Dinko Milaković , Darren Dougan , Vladimir A. Dzuba , Victor V. Flambaum

Evidence from a large sample of quasar absorption-line spectra in damped Lyman-alpha systems has suggested a possible time variation of the fine structure constant alpha. The most statistically significant portion of this sample involves…

Astrophysics · Physics 2009-09-15 Timothy P. Ashenfelter , Grant J. Mathews , Keith A. Olive

New branching fraction measurements based primarily on data from a cross dispersed echelle spectrometer are reported for 84 lines of Co II. The branching fractions for 82 lines are converted to absolute atomic transition probabilities using…

Solar and Stellar Astrophysics · Physics 2018-10-10 J. E. Lawler , T. Feigenson , C. Sneden , J. J. Cowan , G. Nave

State-resolved laser spectroscopy at the 10$^{-12}$ precision level recently reported in $arXiv$:2406.18719 determined the fractional change in nuclear quadrupole moment between the ground and isomeric state of $^{229}\rm{Th}$, $\Delta…

Transition frequencies and fine-structure splittings of the $2\,{}^3\!S_1 \rightarrow 2\,{}^3\!P_{\!J}$ transitions in helium-like $^{12}\mathrm{C}^{4+}$ were measured by collinear laser spectroscopy on a 1-ppb level. Accuracy is increased…

Strong constraints on possible variations in fundamental constants can be derived from HI 21-cm and molecular rotational absorption lines observed towards quasars. With the aim of forming a statistical sample of constraints we have begun a…

Astrophysics · Physics 2016-08-16 S. J. Curran , J. K. Webb , M. T. Murphy , Y. M. Pihlström

Analysis of high-resolution stellar spectra relies heavily upon atomic data. These include energy levels, wavelengths, cross-sections for various types of interactions between particles and photons, such as photoionization and collision…

Solar and Stellar Astrophysics · Physics 2011-04-12 Maria Bergemann

Nowadays, several opacity codes are able to provide data for stellar structure models, but the computed opacities may show significant differences. In this work, we present state-of-the-art precise spectral opacity calculations, illustrated…

Solar and Stellar Astrophysics · Physics 2019-04-30 Jean-Christophe Pain , Franck Gilleron , Maxime Comet
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