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We have measured transition frequencies, isotope shifts and hyperfine structure splittings in the $3 d^{2}\left({ }^{3\!}F\right) 4 s\,{ }^{4} F_J\rightarrow 3 d^{2}\left({ }^{3\!} F\right) 4 p \,^{4} G_{J+1}$ transitions in Ti$^+$ ions for…

Precise radial velocity measurements (delta v/c ~ 10^{-7}) of FeII lines in damped Ly-alpha systems from very high quality VLT/UVES spectra of quasars HE0515-4414 and Q1101-264 are used to probe cosmological time dependence of the fine…

We study atomic systems that are in the frequency range of optical atomic clocks and have enhanced sensitivity to potential time-variation of the fine structure constant, alpha. The high sensitivity is due to coherent contributions from…

Atomic Physics · Physics 2010-09-16 J. C. Berengut , V. A. Dzuba , V. V. Flambaum

The remarkable detection of a spatial variation in the fine-structure constant, alpha, from quasar absorption systems must be independently confirmed by complementary searches. In this letter, we discuss how terrestrial measurements of…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. V. Flambaum

The atomic spectra and structure of the open d- and f-shell elements are extremely complex, where tens of thousands of transitions between fine structure energy levels can be observed as spectral lines across the infrared and UV per…

Atomic Physics · Physics 2025-01-23 M. Ding , S. Z. J. Lim , X. Yu , C. P. Clear , J. C. Pickering

Searches for spacetime variations of fundamental constants have entered an era of unprecedented precision. New, high quality quasar spectra require increasingly refined analytic methods. In this article, a continuation in a series to…

Cosmology and Nongalactic Astrophysics · Physics 2024-01-03 John K. Webb , Chung-Chi Lee

The physical state of the intergalactic medium can be probed in great detail with the intervening absorption systems seen in quasar spectra. The properties of the Hydrogen absorbers depend on many cosmological parameters, such as the…

Astrophysics · Physics 2009-11-11 Tom Theuns

Precision spectroscopy of atomic and molecular ions offers a window to new physics, but is typically limited to species with a cycling transition for laser cooling and detection. Quantum logic spectroscopy has overcome this limitation for…

We study electronic transitions in highly-charged Cf ions that are within the frequency range of optical lasers and have very high sensitivity to potential variations in the fine-structure constant, alpha. The transitions are in the optical…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

(Abridged) Many-multiplet (MM) method applied to three inhomogeneous samples of Keck/HIRES quasar absorption spectra gives a shift in the value of the fine-structure constant of Delta alpha/alpha = (-5.4+/-1.2) 10^{-6} in the redshift range…

Astrophysics · Physics 2017-08-23 Sergei A. Levshakov

High-precision spectroscopy of large stellar samples plays a crucial role for several topical issues in astrophysics. Examples include studying the chemical structure and evolution of the Milky Way galaxy, tracing the origin of chemical…

Instrumentation and Methods for Astrophysics · Physics 2015-06-23 U. Heiter , K. Lind , M. Asplund , P. S. Barklem , M. Bergemann , L. Magrini , T. Masseron , Š. Mikolaitis , J. C. Pickering , M. P. Ruffoni

Cosmological variations in the fine structure constant, alpha, can be probed through precise velocity measurements of metallic absorption lines from intervening gas clouds seen in spectra of distant quasars. Data from the Keck/HIRES…

Astrophysics · Physics 2019-08-13 Paolo Molaro , Michael T. Murphy , Sergei Levshakov

A new method for examining the possible space-time variation of the fine structure constant ($\alpha$) is proposed. The technique uses a relatively simple measurement with an optical resonator to compare atom-stabilized optical frequency…

Atomic Physics · Physics 2007-05-23 J. R. Torgerson

Absorption line systems detected in quasar spectra can be used to compare the value of the fine-structure constant, {\alpha}, measured today on Earth with its value in distant galaxies. In recent years, some evidence has emerged of small…

Intervening metal absorption lines in the spectra of z > 6 quasars are fundamental probes of the ionization state and chemical composition of circumgalactic and intergalactic gas near the end of the reionization epoch. Large absorber…

With close pairs of quasars at different redshifts, a background quasar sightline can be used to study a foreground quasar's environment in absorption. We search 149 moderate resolution background quasar spectra, from Gemini, Keck, the MMT,…

This work presents a method for the ab initio calculation of isotope shift in atoms and ions with one valence electron above closed shells. As a zero approximation we use relativistic Hartree-Fock and then calculate correlation corrections.…

Atomic Physics · Physics 2009-08-18 J. C. Berengut , V. A. Dzuba , V. V. Flambaum

We present extensive calculations of radiative transition rates and electron impact collision strengths for Fe II. The data sets involve 52 levels from the $3d\,^7$, $3d\,^64s$, and $3d\,^54s^2$ configurations. Computations of $A$-values…

High-resolution spectroscopy on the $A^2\Pi$ - $X^2\Sigma^+$ electronic system of $^{138}$Ba$^{19}$F is performed using a cold molecular beam produced by a buffer gas source. The hyperfine structure in both $X^2\Sigma^+$ ground and $A^2\Pi$…

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