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We derive and validate a quantitative analytical model of the near-field electrostatic effects in the vicinity (>=3\AA) of two-dimensional (2D) materials. In solving the Poisson equation of a near-planar point charge ansatz for the…

Materials Science · Physics 2022-05-11 Qunfei Zhou , Michele Kotiuga , Pierre Darancet

In this work we use first-principles density-functional theory (DFT) calculations combined with the maximally localized Wannier function tight binding Hamiltonian (MLWF-TB) and Bethe-Salpeter equation (BSE) formalism to investigate…

This study presents a comprehensive analysis of the band structure in NiPS$_3$, a van der Waals layered antiferromagnet, utilizing high-resolution synchrotron-based angle-resolved photoemission spectroscopy (ARPES) and corroborative density…

Understanding the fundamental processes of light-matter interaction is important for detection of explosives and other energetic materials, which are active in the infrared and terahertz (THz) region. We report a comprehensive study on…

The electronic structure of the ferroelectric crystal, NaNO$_2$, is studied by means of first-principles, local density calculations. Our ab-initio, non-relativistic calculations employed a local density functional approximation (LDA)…

Materials Science · Physics 2012-10-16 C. E. Ekuma , M. Jarrell , J. Moreno , L. Franklin , G. L. Zhao , J. T. Wang , D. Bagayoko

Graphene on $L1_0$-FePd(001), which has been experimentally studied in recent years, is a heterogeneous interface with a significant lattice symmetry mismatch between the honeycomb structure of graphene and tetragonal alloy surface. In this…

Materials Science · Physics 2022-09-14 Mitsuharu Uemoto , Hayato Adachi , Hiroshi Naganuma , Tomoya Ono

In the present work, the atomic and the electronic structures of Au3N, AuN and AuN2 are investigated using first-principles density-functional theory (DFT). We studied cohesive energy vs. volume data for a wide range of possible structures…

Materials Science · Physics 2015-11-24 Mohammed S. H. Suleiman , Daniel P. Joubert

Motivated by the successful synthesis of isolated ZrS2 and HfS2 transition metal dichalcogenide (TMD) monolayers and inspired by their nearly identical lattice constants, we construct and investigate a vertical ZrS2/HfS2 van der Waals (vdW)…

Materials Science · Physics 2025-12-23 Mohammad Ali Mohebpour , Carmine Autieri , Meysam Bagheri Tagani

We report a facile `metric' for the identification of structurally and dynamically (positive definite phonon structure) stable inorganic compounds. The metric considers charge-imbalance within the local substructures in crystalline…

Materials Science · Physics 2020-11-19 R. Villarreal , P. Singh , R. Arroyave

A number of diverse bulk properties of the zincblende and wurtzite III-V nitrides AlN, GaN, and InN, are predicted from first principles within density functional theory using the plane-wave ultrasoft pseudopotential method, within both the…

Materials Science · Physics 2009-10-31 A. Zoroddu , F. Bernardini , P. Ruggerone , V. Fiorentini

The band structure and electronic properties in a series of vinylene-linked heterocyclic conducting polymers are investigated using density functional theory (DFT). In order to accurately calculate electronic band gaps, we utilize hybrid…

Materials Science · Physics 2015-03-13 Bryan M. Wong , Joseph G. Cordaro

We present a theoretical study of the structural, electronic and transport properties of bulk Bi2Te3 within density functional theory taking into account the van der Waals interactions (vdW) and the quasiparticle self-energy corrections. It…

Materials Science · Physics 2014-08-20 L. Cheng , H. J. Liu , J. Zhang , J. Wei , J. H. Liang , J. Shi , X. F. Tang

We report using density functional theory (DFT), the ground-state properties of the recently synthesized and characterized Sr$_3$[C$_2$N]$_2$ crystal. The nearly colorless, centrosymmetric Sr$_3$[C$_2$N]$_2$ crystallizes in a monoclinic…

Computational Physics · Physics 2020-01-28 James Sifuna , George S. Manyali , Elicah Wabululu , Carolyne Songa , Alloysious Otieno , Stephen Sironik

Vivianite (Fe$_3$(PO$_4$)$_2$8H$_2$O) is a naturally occurring layered material with significant environmental and technological relevance. This work presents a comprehensive theoretical investigation of its two-dimensional (2D)…

Ammonium DiNitramide (ADN) is one of the most promising green energetic oxidizers for future rocket propellant formulations. In the present work, we report a detailed theoretical study on structural, elastic, and vibrational properties of…

Materials Science · Physics 2016-09-05 N. Yedukondalu , Vikas D. Ghule , G. Vaitheeswaran

Comparative molecular dynamics simulations of a hexamer cluster of the protic ionic liquid ethylammonium nitrate are performed using density functional theory (DFT) and density functional-based tight binding (DFTB) methods. The focus is on…

Chemical Physics · Physics 2017-03-24 Tobias Zentel , Oliver Kühn

SnTaS2 is a recently discovered layered semimetal exhibiting type-II low transition temperature superconductivity. Except some superconductivity related parameters, most of the physical properties, namely, elastic, mechanical, bonding,…

Materials Science · Physics 2022-07-13 M. I. Naher , M. Mahamudujjaman , A. Tasnim , R. S. Islam , S. H. Naqib

Hydrogen-rich materials offer a compelling avenue towards room temperature superconductivity, albeit under ultra-high pressure. However, the experimental investigation of the electronic band structure remains elusive, due to the inherent…

NiPS3 is an exfoliable van-der-Waals intralayer antiferromagnet with zigzag-type spin arrangement. It is distinct from other TMPS3 (TM: transition metal) materials by optical excitations into a strongly correlated state that is tied to the…

In the present study we have investigated the structural properties, electronic band dispersion, elastic constants, acoustic behavior, phonon spectrum, optical properties, and a number of thermophysical parameters of binary topological…

Materials Science · Physics 2022-01-04 M. I. Naher , S. H. Naqib