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Potassium 1,1$'$-dinitroamino-5,5$'$ bistetrazolate (K$_2$DNABT) is a nitrogen rich (50.3 $\%$ by weight, \ce{K2C2N12O4}) green primary explosive with high performance characteristics namely velocity of detonation (D = 8.33 km/s),…

Materials Science · Physics 2015-10-08 N. Yedukondalu , G. Vaitheeswaran

Layered indium selenides ($In_{2}Se_{3}$) have recently been discovered to host robust out-of-plane and in-plane ferroelectricity in the $\alpha$ and $\beta$' phases, respectively. In this work, we utilise angle-resolved photoelectron…

We present density functional theory calculations on the crystal structure, equation of state, vibrational properties and electronic structure of nitrogen-rich solid energetic material guanidinium 2-methyl-5-nitraminotetrazolate (G-MNAT).…

Materials Science · Physics 2015-06-18 K. Ramesh Babu , G. Vaitheeswaran

By performing constant-pressure variable-cell ab initio molecular dynamics simulations we find a quadrupolar orthorhombic structure, of $Pca2_1$ symmetry, for the broken symmetry phase (phase II) of solid H2 at T=0 and P =110 - 150 GPa. We…

Materials Science · Physics 2009-10-30 Jorge Kohanoff , Sandro Scandolo , Guido L. Chiarotti , Erio Tosatti

We used the binding energy-bond-charge model to study the atomic bonding and electrical properties of the two-dimensional graphene/BN van der Waals heterostructure. We manipulated its atomic bonding and electrical properties by…

Materials Science · Physics 2022-03-14 Jiannan Wang , Liangjing Ge , Anlin Deng , Hongrong Qiu , Hanze Li , Yunhu Zhu , Maolin Bo

We investigate the adsorption of graphene sheets on h-BN substrates by means of first-principles calculations in the framework of adiabatic connection fluctuation-dissipation theory in the random phase approximation. We obtain adhesion…

Mesoscale and Nanoscale Physics · Physics 2011-12-14 B. Sachs , T. O. Wehling , M. I. Katsnelson , A. I. Lichtenstein

We compute the electronic band structure and optical properties of boron arsenide using the relativistic quasiparticle self-consistent $GW$ approach, including electron-hole interactions through solution of the Bethe-Salpeter equation. We…

Materials Science · Physics 2019-06-07 John Buckeridge , David O. Scanlon

We performed first-principles density functional theory (DFT) and GW calculations to investigate electronic structures of bulk and few-layer PdSe2. We obtained the quasiparticle band structure of bulk PdSe2, and the obtained energy gap…

Materials Science · Physics 2021-09-02 Han-gyu Kim , Hyoung Joon Choi

We report a density-functional theory study of the structural and electronic properties of Cd2V2O7 under high-pressure conditions. The calculations have been performed by using first-principle calculations with the CRYSTAL program. The…

Materials Science · Physics 2022-05-23 Daniel Diaz-Anichtchenko , Daniel Errandonea

We obtain the quasiparticle band structure of ABA and ABC-stacked graphene trilayers through ab initio density functional theory (DFT) and many-body quasiparticle calculations within the GW approximation. To interpret our results, we fit…

Mesoscale and Nanoscale Physics · Physics 2014-02-10 Marcos G. Menezes , Rodrigo B. Capaz , Steven G. Louie

In this review, we present recent works on materials whose common point is the presence of electronic bands of very low dispersion, called "flat bands", which are due to specific atomic order effects without electron interactions. These…

We study the electronic and optical properties of strained single-layer SnC in the density functional theory (DFT) and tight-binding models. We extract the hopping parameters tight-binding Hamiltonian for monolayer SnC by considering the…

Mesoscale and Nanoscale Physics · Physics 2017-09-20 Y. Mogulkoc , M. Modarresi , A. Mogulkoc , Y. O. Ciftci , B. Alkan

The structural, dynamical, and thermodynamical properties of diamond, graphite and layered derivatives (graphene, rhombohedral graphite) are computed using a combination of density-functional theory (DFT) total-energy calculations and…

Materials Science · Physics 2009-11-10 Nicolas Mounet , Nicola Marzari

Heterointerfaces of cubic boron nitride (cBN) with diamond have garnered significant interest due to their ultra-wide bandgaps and small lattice mismatch ($\sim1.5$\%), offering promising advancements in high-power and high-frequency…

In the search for new renewable energy to replace fossil fuels, Hydrogen is one of the most promising candidates for clean energy production. But cheap Hydrogen separation and storage is still a big challenge. Photoelectrochemical devices…

Materials Science · Physics 2022-11-10 R. C. Bastidas Briceño , V. I. Fernandez , R. E. Alonso

A DFT study of the synthesized MAX phase Zr2SeC has been carried out for the first time to explore its physical properties for possible applications in many sectors. The studied properties are compared with prior known MAX phase Zr2SC. The…

Materials Science · Physics 2021-03-16 M. A. Ali , Muhammad Waqas Qureshi

The tin-selenide and tin-sulfide classes of materials undergo multiple structural transitions under high pressure leading to periodic lattice distortions, superconductivity, and topologically non-trivial phases, yet a number of…

Materials Science · Physics 2020-10-23 Gyanu Prasad Kafle , Christoph Heil , Hari Paudyal , Elena R. Margine

In this paper we investigate the electronic and superconducting properties in nickelate compounds of NiO2 through Perturbative Density Functional Theory (P-DFT) and multi-band BCS theory. We consider three different cases of study (i) the…

Superconductivity · Physics 2021-12-16 Julian Faundez , C. A. Aguirre , S. G. Magalhães , J. Barba-Ortega

Titanium dioxide (TiO2) is a wide band gap semiconducting material which is promising for photocatalysis. Here we present first-principles calculations to study the pressure dependence of structural and electronic properties of two TiO2…

Materials Science · Physics 2017-06-21 Yong Yang

We utilized a simple, robust, first principle method, based on basis set optimization with the BZW-EF method, to study the electronic and related properties of transition metal mono-nitrides: ScN and YN. We solved the KS system of equations…

Materials Science · Physics 2012-09-04 C. E. Ekuma , D. Bagayoko , M. Jarrell , J. Moreno