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It is shown, by DFT calculations, that the uniform functionalization of upper layer of graphite by hydrogen or fluorine does not change essentially its bonding energy with the underlying layers, whereas the functionalization by phenyl…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 D. W. Boukhvalov , M. I. Katsnelson

Following recently published study of Prezhdo and coworkers (JPC Letters, 2014, 5, 4129-4133), we report a systematic investigation of how monovalent and divalent ions influence valence electronic structure of graphene. Pure density…

Materials Science · Physics 2014-12-10 Guilherme Colherinhas , Eudes Eterno Fileti , Vitaly V. Chaban

Graphene is a truly two-dimensional material with exceptional electronic, mechanical, and optical properties. As such, it consists of surface only and can be probed by the well developed surface-science techniques as, e.g., scanning…

Mesoscale and Nanoscale Physics · Physics 2012-04-18 Markus Morgenstern

Graphene, being one-atom thick, is extremely sensitive to the presence of adsorbed atoms and molecules and, more generally, to defects such as vacancies, holes and/or substitutional dopants. This property, apart from being directly usable…

Materials Science · Physics 2011-04-08 Rocco Martinazzo , Simone Casolo , Gian Franco Tantardini

The use of a novel three-dimensional graphene structure allows circumventing the limitations of the two-dimensional nature of graphene and its application in hydrogen absorption. Here we investigate hydrogen-bonding on monolayer graphene…

We present derivation and implementation of the Multi-Configurational Strong-Field Approximation with Gaussian nuclear Wave Packets (MC-SFA-GWP) -- a version of the molecular strong-field approximation which treats all electronic and…

Chemical Physics · Physics 2017-11-10 Serguei Patchkovskii , Michael S. Schuurman

Using inelastic electron tunneling spectroscopy with the scanning tunneling microscope (STM-IETS) and density functional theory calculations (DFT), we investigated properties of a single H2 molecule trapped in nanocavities with controlled…

Materials Science · Physics 2018-10-12 Hui Wang , Shaowei Li , Haiyan He , Arthur Yu , Freddy Toledo , Zhumin Han , W. Ho , Ruqian Wu

The hybrid photon-atom integrated circuits, which include photonic microcavities and trapped single neutral atom in their evanescent field, are of great potential for quantum information processing. In this platform, the atoms provide the…

Twist, as a simple and unique degree of freedom, could lead to enormous novel quantum phenomena in bilayer graphene. A small rotation angle introduces low-energy van Hove singularities (VHSs) approaching the Fermi level, which result in…

Materials Science · Physics 2018-02-07 Wei-Jie Zuo , Jia-Bin Qiao , Dong-Lin Ma , Long-Jing Yin , Gan Sun , Jun-Yang Zhang , Li-Yang Guan , Lin He

Using the tight-binding model, we investigate the influence of vacancy disorder on electrical transport in graphene Hall bars in the presence of quantizing magnetic fields. Disorder, induced by a random distribution of monovacancies, breaks…

Mesoscale and Nanoscale Physics · Physics 2016-12-21 M. D. Petrović , F. M. Peeters

We employ scanning probe microscopy to reveal atomic structures and nanoscale morphology of graphene-based electronic devices (i.e. a graphene sheet supported by an insulating silicon dioxide substrate) for the first time. Atomic resolution…

Materials Science · Physics 2008-11-05 Masa Ishigami , J. H. Chen , W. G. Cullen , M. S. Fuhrer , E. D. Williams

We discuss self-consistently obtained ground-state electronic properties of monolayers of graphene and a number of beyond graphene compounds, including films of transition-metal dichalcogenides (TMDs), using the recently proposed strongly…

Materials Science · Physics 2017-04-27 I. G. Buda , C. Lane , B. Barbiellini , A. Ruzsinszky , J. Sun , A. Bansil

Extensive scanning tunnelling microscopy and spectroscopy experiments complemented by first principles and parameterized tight binding calculations provide a clear answer to the existence, origin and robustness of van Hove singularities…

Recent atomic force microscopy (AFM) experiments~[ACS Nano {\bf 2014}, 8, 12410-12417] conducted on graphene-coated SiO$_2$ demonstrated that monolayer graphene (G) can effectively screen dispersion van der Waals (vdW) interactions deriving…

Materials Science · Physics 2018-06-13 Alberto Ambrosetti , Pier Luigi Silvestrelli

Twisted bilayer graphene (TBG) exhibits a wide range of intriguing physical properties, such as superconductivity, ferromagnetism, and superlubricity. Depending on the twist angle, periodic moir\'e superlattices form in twisted bilayer…

Mesoscale and Nanoscale Physics · Physics 2022-06-07 Vahid Morovati , Zhiming Xue , Kenneth M. Liechti , Rui Huang

Graphene clusters consisting of 24 to 150 carbon atoms and hydrogen termination at the zigzag boundary edges have been studied, as well as clusters disordered by vacancy(s). Density Function Theory and Gaussian03 software were used to…

Mesoscale and Nanoscale Physics · Physics 2012-11-21 N. Kheirabadi , A. Shafiekhani

We employ the Green's function technique to investigate the vacancy-induced quasi-localized magnetic moment formation in mono-layer graphene starting with the Dirac Hamiltonian, which focuses on the {\pi}- orbitals only, involving the…

Mesoscale and Nanoscale Physics · Physics 2012-05-08 Partha Goswami , Ajay Pratap Singh Gahlot

Monolayer and multilayer graphene are promising materials for applications such as electronic devices, sensors, energy generation and storage, and medicine. In order to perform large-scale atomistic simulations of the mechanical and thermal…

Materials Science · Physics 2019-11-27 Mingjian Wen , Ellad B. Tadmor

The properties of single-walled carbon nanotubes (SWCNTs) and graphene can be modified by the presence of covalently bound impurities. Although this can be achieved by introducing chemical additives during synthesis, that often hinders…

Atomic-scale topography of epitaxial multilayer graphene grown on 4H-SiC(0001) was investigated using scanning tunneling microscopy (STM). Bunched nano-ridges ten times smaller than previously recorded were observed throughout the surface,…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 P. Xu , M. L. Ackerman , S. D. Barber , J. K. Schoelz , D. Qi , P. M. Thibado , V. D. Wheeler , L. O. Nyakiti , R. L. Myers-Ward , C. R. Eddy, , D. K. Gaskill