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The hydrogen dynamics on a graphene sheet is studied in the presence of carbon vacancies. We analyze the motion of atomic H by means of molecular dynamics (MD) simulations, using a tight-binding Hamiltonian fitted to density-functional…

Chemical Physics · Physics 2022-09-29 Carlos P. Herrero , Jose A. Verges , Rafael Ramirez

We present scanning tunneling microscopy (STM) images of single-layer graphene crystals examined under ultrahigh vacuum conditions. The samples, with lateral dimensions on the micron scale, were prepared on a silicon dioxide surface by…

The stability of hydrogenated monolayer graphene was investigated via X-ray photoemission spectroscopy (XPS) for two different environmental conditions: ultra-high vacuum (UHV) and ambient pressure. The study is carried out by measuring the…

Quasi free standing monolayer graphene (QFMLG) grown on SiC by selective Si evaporation from the Si-rich SiC(0001) face and H intercalation displays irregularities in STM and AFM analysis, appearing as localized features, which we…

Mesoscale and Nanoscale Physics · Physics 2018-04-27 Tommaso Cavallucci , Yuya Murata , Makoto Takamura , Hiroki Hibino , Stefan Heun , Valentina Tozzini

Removing a single-carbon vacancy introduces (quasi-)localized states for both and electrons in graphene. Interactions between the localized dangling bond and quasilocalized electrons of a single-carbon vacancy in graphene are predicted to…

Materials Science · Physics 2018-11-07 Yu Zhang , Fei Gao , Shiwu Gao , Lin He

Atomic vacancies have a strong impact in the mechanical, electronic and magnetic properties of graphene-like materials. By artificially generating isolated vacancies on a graphite surface and measuring their local density of states on the…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 M. M. Ugeda , I. Brihuega , F. Guinea , J. M. Gomez-Rodriguez

We have used scanning tunneling microscopy (STM) to investigate two types of hydrogen defect structures on monolayer graphene supported by hexagonal boron nitride (h-BN) in a gated field-effect transistor configuration. The first H-defect…

The remarkable electronic properties of graphene have fueled the vision of a graphene-based platform for lighter, faster and smarter electronics and computing applications. One of the challenges is to devise ways to tailor its electronic…

Well-known effect of mechanical stiffness degradation under the influence of point defects in macroscopic solids can be controversially reversed in the case of low-dimensional materials. Using atomistic simulation, we showed here that a…

Mesoscale and Nanoscale Physics · Physics 2015-08-18 Dmitry G. Kvashnin , Pavel B. Sorokin

Understanding the coupling of graphene with its local environment is critical to be able to integrate it in tomorrow's electronic devices. Here we show how the presence of a metallic substrate affects the properties of an atomically…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 M. M. Ugeda , D. Fernández-Torre , I. Brihuega , P. Pou , A. J. Martínez-Galera , R. Pérez , J. M. Gómez-Rodríguez

Nitrogen-vacancy (NV) centers in diamond are among the most promising solid-state qubit candidates, owing to their exceptionally long spin coherence times, efficient spin-photon coupling, room-temperature operation, and steadily advancing…

Quantum Physics · Physics 2025-04-21 Arjun Raghavan , Seokjin Bae , Nazar Delegan , F. Joseph Heremans , Vidya Madhavan

We present an investigation of the atomic and electronic structure of graphene monolayer islands on the 6H-SiC(000-1)(3x3) (SiC(3x3)) surface reconstruction using scanning tunneling microscopy (STM) and spectroscopy (STS). The orientation…

Materials Science · Physics 2010-01-04 F. Hiebel , P. Mallet , L. Magaud , J. -Y. Veuillen

We report an approach for three-dimensional imaging of single vacancies using high precision quantitative high-angle annular dark-field Z-contrast scanning transmission electron microscopy (STEM). Vacancies are identified by both the…

The interlayer gallery between two adjacent sheets of van der Waals materials is expected to modify properties of atoms and molecules confined at the atomic interfaces. Here, we directly image individual hydrogen atom intercalated between…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 Wen-Xiao Wang , Yi-Wen Wei , Si-Yu Li , Xinqi Li , Xiaosong Wu , Ji Feng , Lin He

Adsorption of hydrogen atoms to a carbon atom vacancy in graphene is investigated by means of periodic \emph{first principles} calculations, up to the fully hydrogenated state where six H atoms chemically bind to the vacancy. Addition of a…

Materials Science · Physics 2013-12-30 M. Casartelli , S. Casolo , G. F. Tantardini , R. Martinazzo

Irradiation with high-energy ions has been widely suggested as a tool to engineer properties of graphene. Experiments show that it indeed has a strong effect on its transport, magnetic and mechanical characteristics. However, to use ion…

Mesoscale and Nanoscale Physics · Physics 2014-11-07 Ossi Lehtinen , I-Ling Tsai , Rashid Jalil , Rahul R. Nair , Juhani Keinonen , Ute Kaiser , Irina V. Grigorieva

Utilizing a combination of low-temperature scanning tunneling microscopy/spectroscopy (STM/STS) and electronic structure calculations, we characterize the structural and electronic properties of single atomic vacancies within several…

Tuning the chemical potential of a solid to the vicinity of a van Hove singularity (vHS) is a well-established route to discovering emergent quantum phases. In monolayer graphene, the use of electron-donating metal layers has recently…

Mesoscale and Nanoscale Physics · Physics 2025-02-13 Raymond Blackwell , Zengyi Du , Takuya Okugawa , Asish Kundu , Zebin Wu , Ilya Drozdov , Angel Rubio , Dante Kennes , Kazuhiro Fujita , Abhay Pasupathy

The density of electronic one-particle states in monolayer graphene is studied by performing the Hybrid Monte-Carlo simulations of the tight-binding model for electrons on the pi orbitals of carbon atoms which make up the graphene lattice.…

Strongly Correlated Electrons · Physics 2013-07-01 P. V. Buividovich

The quantum Hall conductance in monolayer graphene on an epitaxial SrTiO3 (STO) thin film is studied to understand the role of oxygen vacancies in determining the dielectric properties of STO. As the gate voltage sweep range is gradually…

Materials Science · Physics 2017-05-17 Kyeong Tae Kang , Haeyong Kang , Jeongmin Park , Dongseok Suh , Woo Seok Choi
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