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We present Einstein coefficient spectra and a detailed-balance derivation of generalized Einstein relations between them that is based on the connection between spontaneous and stimulated emission. If two broadened levels or bands overlap…

Chemical Physics · Physics 2024-09-05 Jisu Ryu , Sarang Yeola , David M. Jonas

The Stokes-Einstein relation (SER) is one of the most robust and widely employed results from the theory of liquids. Yet sizable deviations can be observed for self-solvation, which cannot be explained by the standard hydrodynamic…

Statistical Mechanics · Physics 2018-06-15 Benoit Charbonneau , Patrick Charbonneau , Grzegorz Szamel

The aforementioned celebrated model, though a breakthrough in Stochastic processes and a great step toward the construction of the Brownian motion leads to a paradox: infinite propagation speed and violation of the 2nd law of…

Analysis of PDEs · Mathematics 2022-09-13 Isanka Garli Hevage , Akif Ibragimov , Zeev Sobol

The success of the shear-transformation-zone (STZ) theory in accounting for broadly peaked, frequency-dependent, glassy viscoelastic response functions is based on the theory's first-principles prediction of a wide range of internal STZ…

Statistical Mechanics · Physics 2011-08-23 J. S. Langer

Among the numerous anomalies of water, the acceleration of dynamics under pressure is particularly puzzling. Whereas the diffusivity anomaly observed in experiments has been reproduced in several computer studies, the parallel viscosity…

We present a systematic study of the self-diffusion coefficient for a fluid of particles interacting via the square-well pair potential by means of molecular dynamics simulations in the canonical (N,V,T) ensemble. The discrete nature of the…

Soft Condensed Matter · Physics 2018-11-14 Alexis Torres-Carbajal , Victor M. Trejos , Luz Adriana Nicasio-Collazo

Molecular dynamics computer simulation has been used to compute the self-diffusion coefficient, and shear viscosity of soft-sphere fluids, in which the particles interact through the soft-sphere or inverse power pair potential. The…

Soft Condensed Matter · Physics 2010-03-22 Yu. D. Fomin , V. V. Brazhkin , V. N. Ryzhov

This paper is a follow-up of article [6], on the derivation of accurate effective models for viscous dilute suspensions. The goal is to identify an effective Stokes equation providing a $o(\lambda^2)$ approximation of the exact…

Analysis of PDEs · Mathematics 2020-04-21 David Gérard-Varet , Amina Mecherbet

In this article, a special static spherically symmetric perfect fluid solution of Einstein's equations is provided. Though pressure and density both diverge at the origin, their ratio remains constant. The solution presented here fails to…

General Physics · Physics 2009-09-29 F. Rahaman , M. Kalam , S. Chakraborty , K. Maity , B. Raychaudhuri

One of the most enigmatic science question concerning inertial particle transport by a turbulent boundary layer flow is the value of the turbulent Schmidt number as the ratio of particle diffusivity and turbulent eddy viscosity. Using…

Fluid Dynamics · Physics 2021-12-14 Julien Chauchat , David Hurther , Thibaud Revil-Baudard , Zhen Cheng , Tian-Jian Hsu

The theories of Brownian motion, the Debye rotational diffusion model, and hydrodynamics together provide us with the Stokes--Einstein--Debye (SED) relation between the rotational relaxation time of the $\ell$-th degree Legendre polynomials…

Soft Condensed Matter · Physics 2019-06-03 Takeshi Kawasaki , Kang Kim

Asymptotic behavior of a class of nonlinear Schr\"odinger equations are studied. Particular cases of 1D weakly focusing and Bose-Einstein condensates are considered. A statistical approach is presented to describe the stationary probability…

Condensed Matter · Physics 2009-11-10 Christophe Josserand

There remains a useful relation between diffusion and mobility for a Langevin particle in a periodic medium subject to nonconservative forces. The usual fluctuation-dissipation relation easily gets modified and the mobility matrix is no…

Statistical Mechanics · Physics 2015-03-17 Marco Baiesi , Christian Maes , Bram Wynants

We report measurements of the shear viscosity $\eta$ in water up to $150\,\mathrm{MPa}$ and down to $229.5\,\mathrm{K}$. This corresponds to more than $30\,\mathrm{K}$ supercooling below the melting line. The temperature dependence is…

Soft Condensed Matter · Physics 2023-09-19 Alexandre Mussa , Romain Berthelard , Frédéric Caupin , Bruno Issenmann

A steady self-diffusion process in a gas of hard spheres at equilibrium is analyzed. The system exhibits a constant gradient of labeled particles. Neither the concentration of these particles nor its gradient are assumed to be small. It is…

Statistical Mechanics · Physics 2015-06-17 J. Javier Brey , M. J. Ruiz-Montero

In this paper, we study the diffusion approximation for singularly perturbed stochastic reaction-diffusion equation with a fast oscillating term. The asymptotic limit for the original system is obtained, where an extra Gaussian term…

Probability · Mathematics 2021-06-08 Longjie Xie , Li Yang

By confining water in nanopores, so narrow that the liquid cannot freeze, it is possible to explore its properties well below its homogeneous nucleation temperature TH ~ 235 K. In particular, the dynamical parameters of water can be…

Soft Condensed Matter · Physics 2007-05-23 Sow-Hsin Chen , Francesco Mallamace , Chung-Yuan Mou , Matteo Broccio , Carmelo Corsaro , Antonio Faraone , Li Liu

The Einstein relation describes the response of a diffusing particle to a small constant external force. It states that, as the force tends to zero, the ratio of the limiting velocity to the force magnitude converges to the diffusivity…

Probability · Mathematics 2026-05-26 Ahmed Bou-Rabee , Ruizhe Xu

We investigate the origin of the violation of the Stokes-Einstein (SE) relation in two-dimensional Yukawa liquids. Using comprehensive molecular dynamics simulations, we identify the time scales supporting the violation of the SE relation…

Soft Condensed Matter · Physics 2021-04-13 Zahra Ghannad

A constructive numerical approximation of the two-dimensional unsteady stochastic Navier-Stokes equations of an incompressible fluid is proposed via a pseudo-compressibility technique involving a parameter $\epsilon$. Space and time are…

Numerical Analysis · Mathematics 2022-05-02 Jad Doghman