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We study the dynamics of water confined between hydrophobic flat surfaces at low temperature. At different pressures, we observe different behaviors that we understand in terms of the hydrogen bonds dynamics. At high pressure, the formation…

Soft Condensed Matter · Physics 2015-05-13 Giancarlo Franzese , Francisco de los Santos

The lifetime of a hydrogen bond between water and dimethyl sulfoxide (DMSO) is found to be considerably longer than that between two water molecules in the neat water. This is counter-intuitive because the charge on the oxygen in DMSO is…

Soft Condensed Matter · Physics 2024-04-22 Sangita Mondal , Biman Bagchi

We investigate the addition of stiffness to the lattice model of hydrogen-bonded polymers in two and three dimensions. We find that, in contrast to polymers that interact via a homogeneous short-range interaction, the collapse transition is…

Soft Condensed Matter · Physics 2009-11-13 J Krawczyk , AL Owczarek , T Prellberg

The interactions of a hydrophilic surface with water can significantly influence the characteristics of the liquid water interface. In this manuscript, we explore this influence by studying the molecular structure of liquid water at a…

Soft Condensed Matter · Physics 2022-09-19 Sucheol Shin , Adam P. Willard

Protein-protein interactions (protein functionalities) are mediated by water, which compacts individual proteins and promotes close and temporarily stable large-area protein-protein interfaces. Proteins are peptide chains decorated by amino…

Soft Condensed Matter · Physics 2008-02-26 J. C. Phillips

Statistical analysis of protein-protein interactions shows anomalously high frequency of homodimers [Ispolatov, I., et al. (2005) Nucleic Acids Res 33, 3629-35]. Furthermore, recent findings [Wright, C.F., et al. (2005) Nature 438, 878-81]…

Biomolecules · Quantitative Biology 2007-05-23 D. B. Lyjatsky , E. I. Shakhnovich

The interfacial behaviour of water remains a central question to fields as diverse as protein folding, friction and ice formation[1,2]. While the structural and dynamical properties of water at interfaces differ strongly from those in the…

Mesoscopic structure of the periodically alternating layers of stretched homopolymer chains surrounded by perpendicularly oriented oligomeric tails is studied for the systems with both strong (ionic) and weak (hydrogen) interactions. We…

Soft Condensed Matter · Physics 2009-11-10 A. I. Olemskoi , I. Krakovsky , A. Savelyev

Hydrophobic domains provide specific microenvironment for essential functional activities in life. Herein, we studied how the coassembling of peptides with catecholamines regulate the hydrophobic domain-containing nanostructures for…

Biomolecules · Quantitative Biology 2023-07-04 Ruoyang Zhao , Feng Gao , Maoyu Li , Xingkun Niu , Shihao Liu , Xinmin Zhao , Liping Wang , Jun Guo , Feng Zhang

Folding channels and free-energy landscapes of hydrophobic-polar heteropolymers are discussed on the basis of a minimalistic off-lattice coarse-grained model. We investigate how rearrangements of hydrophobic and polar monomers in a…

Soft Condensed Matter · Physics 2009-11-13 Stefan Schnabel , Michael Bachmann , Wolfhard Janke

Under dehydration conditions, amphipathic Late Embryogenesis Abundant (LEA) proteins fold spontaneously from a random conformation into alpha-helical structures and this transition is promoted by the presence of membranes. To gain insight…

Biological Physics · Physics 2012-06-27 Sergey Pogodin , Nigel K. H. Slater , Vladimir A. Baulin

The stability of a $\beta$-sheeted conformation and its transition into a random coil are studied with a 2D lattice biopolymer model. At low temperature and low external force, the polymer folds back and forth on itself and forms a…

Soft Condensed Matter · Physics 2007-05-23 Haijun Zhou

The viscosity dependence of the folding rates for four sequences (the native state of three sequences is a beta-sheet, while the fourth forms an alpha-helix) is calculated for off-lattice models of proteins. Assuming that the dynamics is…

Soft Condensed Matter · Physics 2009-10-30 D. K. Klimov , D. Thirumalai

We study the phase behavior of single homopolymers in a simple hydrophobic/hydrophilic off-lattice model with sequence independent local interactions. The specific heat is, not unexpectedly, found to exhibit a pronounced peak well below the…

Soft Condensed Matter · Physics 2009-10-31 Anders Irbäck , Erik Sandelin

Applying the contact density chain-growth algorithm to lattice heteropolymers, we identify the conformational transitions of a nongrafted hydrophobic-polar heteropolymer with 103 residues in the vicinity of a polar, a hydrophobic, and a…

Soft Condensed Matter · Physics 2009-11-13 Michael Bachmann , Wolfhard Janke

Small molecules are often found to exhibit extraordinarily diverse biological activities. Metformin is one of them. It is widely used as anti-diabetic drug for type-two diabetes. In addition to that, metformin hydrochloride shows…

Biomolecules · Quantitative Biology 2018-02-08 Sayantan Mondal , Rudra N Samajdar , Saumyak Mukherjee , Aninda J Bhattacharyya , Biman Bagchi

Free-energy landscapes for short peptides -- specifically for variants of the pH Low Insertion Peptide (pHLIP) -- in the heterogeneous environment of a lipid bilayer or cell membrane are constructed, taking into account a set of dominant…

Soft Condensed Matter · Physics 2022-07-22 Ganga P. Sharma , Aaron C. Meyer , Suhail Habeeb , Michael Karbach , Gerhard Müller

Hydrogen bonding plays a role in the microphase separation behavior of many block copolymers, such as those used in lithography, where the stronger interactions due to H-bonding can lead to a smaller period for the self-assembled…

Soft Condensed Matter · Physics 2018-05-28 E. Patyukova , T. Rottreau , R. Evans , P. D. Topham , M. J. Greenall

Hydrodynamic interactions (HIs) are important in biophysics research because they influence both the collective and the individual behaviour of microorganisms and self-propelled particles. For instance, HIs at the micro-swimmer level…

Fluid Dynamics · Physics 2022-03-30 Maria Tătulea-Codrean , Eric Lauga

Motivated by single molecule experiments on biopolymers we explore equilibrium morphologies and force-extension behavior of copolymers with hydrophobic segments using Langevin dynamics simulations. We find that the interplay between…

Soft Condensed Matter · Physics 2013-10-15 Ankur Mishra , Ajay S. Panwar , Buddhapriya Chakrabarti