Related papers: Electro-Osmotic Flow of Semidilute Polyelectrolyte…
We study the reentrant condensation of polyelectrolytes in dilute solutions of small multivalent salts, whose phase-transition mechanism remains poorly understood. Motivated by recent full atomic simulation results reported by the Caltech…
It is shown using a method based on a modified version of the mean field theory of Miklavic Marcelja that it should be possible for osmotic pressure due to the counterions associated with the two polyelectrolyte polymer brush coated…
We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…
Corona charging a free-standing polymer film can produce a quasi-permanent potential difference across the film thickness, while the absolute amplitude of surface voltage may be highly sensitive to the free charges. To precisely control the…
Osmotic transport in nanoconfined aqueous electrolytes provides new venues for water desalination and "blue energy" harvesting; the osmotic response of nanofluidic systems is controlled by the interfacial structure of water and electrolyte…
We study the ionic equilibria and interactions of neutral semi-permeable spherical shells immersed in electrolyte solutions, including polyions. Although the shells are uncharged, only one type of ions of the electrolyte can permeate them,…
Understanding confined flows of complex fluids requires simultaneous access to the mechanical behaviour of the liquid and the boundary condition at the interfaces. Here, we use evanescent wave microscopy to investigate near-surface flows of…
We develop a nonlinear model for electroosmotic transport in a constricted microchannel with a compliant lower wall, with applications to soft microfluidics, bio-inspired sensing, and energy harvesting. The formulation couples…
This study has numerically investigated the charge-heterogeneity effects in the electroviscous flow of symmetric ($1$:$1$) electrolyte liquid through a uniform slit microfluidic device. The Poisson's, Nernst-Planck (N-P), Navier-Stokes…
In this study we consider the problem of the interface motion under the capillary-gravity and an external electric forces. The infinitely deep fluid layer is assumed to be viscous, perfectly conducting and the flow to be incompressible. The…
We investigate the pseudo-Casimir force acting between two charged surfaces confining a single polyelectrolyte chain with opposite charge. We expand the exact free energy to the second order in the local electrostatic field as well as the…
The kinetic behavior of a phase field model of electrochemistry is explored for advancing (electrodeposition) and receding (electrodissolution) conditions in one dimension. We described the equilibrium behavior of this model in [J. E.…
Motivated by experiments on a hydrodynamic regime in electron transport, we study the effect of an oscillating electric field in such a setting. We consider a long two-dimensional channel of width $L$, whose geometrical simplicity allows an…
We investigate the mobility of nanometer-size solutes in water in a uniform external electric field. General arguments are presented to show that a closed surface cutting a volume from a polar liquid will carry an effective non-zero surface…
The behavior of electrolyte solutions close to a charged surface is studied theoretically. A modified Poisson-Boltzmann equation which takes into account the volume excluded by the ions in addition to the electrostatic interactions is…
It has been established that the Coulomb interactions can transform the electron gas into a viscous fluid. This fluid is realized in a number of platforms, including graphene and two-dimensional semiconductor heterostructures. The defining…
Two overall neutral surfaces with positive and negative charged domains ("patches") have been shown in recent experiments to exhibit long-range attraction when immersed in an ionic solution. Motivated by the experiments, we calculate…
In this paper, we develop a general mathematical framework for the electro-osmosis problem to design simultaneous microscale electric and hydrodynamic cloaking in a Hele-Shaw configuration. A novel approach to achieving simultaneously…
We derive a mathematical model of a nematic electrolyte based on the Leslie-Ericksen theory of liquid crystal flow. Our goal is to investigate the nonlinear electrokinetic effects that occur because the nematic matrix is anisotropic, in…
The concept of the partial osmotic pressure of ions in an electrolyte solution is critically examined. In principle these can be defined by introducing a solvent-permeable wall and measuring the force per unit area which can certainly be…