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Since the discovery of superconductivity in a high-entropy alloy (HEA) Ti-Zr-Nb-Hf-Ta in 2014, the community of superconductor science has explored new HEA superconductors to find the merit of the HEA states on superconducting properties.…

Superconductivity · Physics 2021-03-16 Y. Mizuguchi , A. Yamashita

Double half-heusler alloys are the new class of compounds which can be seen as transmuted version of two single half-heusler with higher flexibility of tuning their properties. Here, we report a detailed study of thermoelectric (TE)…

Materials Science · Physics 2025-03-05 Bhawna Sahni , Aftab Alam

It is generally assumed that one solute atom will occupy only one lattice site in a substitutional solid solution. We here report an interesting discovery by first-principles calculations that a large solute atom can replace multiple matrix…

Materials Science · Physics 2018-06-12 W. T. Geng , Q. Zhan

Atomic scale computer simulations using density functional theory were used to investigate the behaviour of tin in the tetragonal phase oxide layer on Zr-based alloys. The $Sn_{Zr}^{\times}$ site defect was shown to be dominant across most…

Materials Science · Physics 2015-02-25 B. D. C. Bell , S. T. Murphy , P. A. Burr , R. W. Grimes , M. R. Wenman

In 2006, a novel cobalt-based superalloy was discovered [1] with mechanical properties better than some conventional nickel-based superalloys. As with conventional superalloys, its high performance arises from the precipitate-hardening…

By means of density-functional calculations, we systematically investigated 24 transition metals for possible metastable phases in body-centered tetragonal structure (bct), including face-centered cubic (fcc) and body-centered cubic (bcc)…

Evolutionary structure searches revealed a plethora of stable and low-enthalpy metastable phases in the S-P-H ternary phase diagram under pressure. A wide variety of crystalline structure types were uncovered ranging from those possessing…

Superconductivity · Physics 2022-05-04 Nisha Geng , Tiange Bi , Eva Zurek

Evolutionary crystal structure prediction searches have been employed to explore the ternary Li-F-H system at 300 GPa. Metastable phases were uncovered within the static lattice approximation, with LiF$_3$H$_2$, LiF$_2$H, Li$_3$F$_4$H,…

Materials Science · Physics 2021-04-07 Tiange Bi , Andrew Shamp , Tyson Terpstra , Russell J. Hemley , Eva Zurek

A computational search for stable structures among both $\alpha$ and $\beta$ phases of ternary ATB4 borides (A= Mg, Ca, Sr, Ba, Al, Ga, and Zn, T is 3d or 4d transition elements) has been performed. We found that $\alpha$-ATB4 compounds…

Materials Science · Physics 2023-10-31 Yang Sun , Zhen Zhang , Andrew P Porter , Kirill Kovnir , Kai-Ming Ho , Vladimir Antropov

Superconductivity in transition metal nitrides (TMNs) has been investigated for a long time, such as zirconium nitride (ZrN) with a superconducting transition temperature Tc of 10 K. Recently, a phase diagram has been revealed in ZrNx with…

Superconductivity · Physics 2023-07-07 Zheng-Wei Liao , Xin-Wei Yi , Jing-Yang You , Bo Gu , Gang Su

Intermetallic compounds Zr7Ni10 and Hf7Ni10 have been studied by perturbed angular correlation (PAC) spectroscopy considering the fact that Zr7Ni10 has application as hydrogen storage material in fuel cell. In stoichiometric Zr7Ni10, the…

Materials Science · Physics 2018-11-14 S. K. Dey , C. C. Dey , S. Saha , G. Bhattacharjee , D. Banerjee , D. Toprek

In this work, we investigate the hydrogen-storage properties of Zr-decorated $\gamma$-graphyne monolayer employing Density Functional Theory (DFT) for green energy storage. We predict that each Zr atom decorated on graphyne sheet (2D) can…

Materials Science · Physics 2023-12-29 Mukesh Singh , Alok Shukla , Brahmananda Chakraborty

High entropy alloys (HEAs) are multicomponent compounds whose high configurational entropy allows them to solidify into a single phase, with a simple crystal lattice structure. Some HEA's exhibit desirable properties, such as high specific…

Materials Science · Physics 2017-06-29 Rui Feng , Peter K. Liaw , Michael C. Gao , Michael Widom

Properties of point defects resulting from the incorporation of inert-gas atoms in bcc tungsten are investigated systematically using first-principles density functional theory (DFT) calculations. The most stable configuration for the…

Materials Science · Physics 2015-10-29 Duc Nguyen-Manh , S. L. Dudarev

This research aims to identify an alternative solution for the Nd$_2$Fe$_{14}$B magnet in light of the scarcity of rare earth (RE) resources. The investigation uses density functional theory (DFT) calculations to assess the effect of…

Materials Science · Physics 2026-04-30 Nico Yannik Merkt

In materials science, it is often assumed that ground state crystal structures predicted by density functional theory are the easiest polymorphs to synthesize. Ternary nitride materials, with many possible metastable polymorphs, provide a…

The stability and bonding of the ternary complex K$_2$PtCl$_6$ structure hydrides is discussed using first principles density functional calculations. The cohesion is dominated by ionic contributions, but ligand field effects are important,…

Materials Science · Physics 2009-11-10 S. V. Halilov , D. J. Singh , M. Gupta , R. Gupta

The phase diagram and equation of state of dense nitrogen are of interest in understanding the fundamental physics and chemistry under extreme conditions, including planetary processes, and in discovering new materials. We predict several…

Materials Science · Physics 2013-12-02 Jian Sun , Miguel Martinez-Canales , Dennis D. Klug , Chris J. Pickard , Richard J. Needs

The synthesis of ternary nitrides is uniquely difficult, in large part because elemental N$_2$ is relatively inert. However, lithium reacts readily with other metals and N$_2$, making Li-M-N the most numerous sub-set of ternary nitrides.…

Doped HfO2 and HfO2-ZrO2 compounds are gaining significant interest thanks to their ferroelectric properties in ultrathin films. Here, we show that ZrO2 could be a playground for doping and strain engineering to increase the thickness in…

Materials Science · Physics 2022-09-01 Ali El Boutaybi , Thomas Maroutian , Ludovic Largeau , Sylvia Matzen , Philippe Lecoeur