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We calculate the s-wave scattering length and effective range and the p-wave scattering volume for $^7$Li atoms interacting with $^{133}$Cs atoms via the X$^1\Sigma^+_g$ molecular potential. The length and volume are found by fitting the…

Atomic Physics · Physics 2015-04-07 M. J. Jamieson , H. Ouerdane

Dispersion coefficients between the alkali metal atoms (Li-Rb) and alkaline-earth metal atoms (Be-Sr) are evaluated using matrix elements computed from frozen core configuration interaction calculations. Besides dispersion coefficients with…

Atomic Physics · Physics 2015-06-15 Jun Jiang , Yongjun Cheng , J. Mitroy

In a recent work [Phys. Rev. Lett. 98, 023004 (2007)] we have investigated the influence of attractive van der Waals interaction on the pair distribution and Penning ionization dynamics of ultracold Rydberg gases. Here we extend this…

Atomic Physics · Physics 2009-11-13 Thomas Amthor , Markus Reetz-Lamour , Christian Giese , Matthias Weidemüller

In a framework for long-range density-functional theory we present a unified full-field treatment of the asymptotic van der Waals interaction for atoms, molecules, surfaces, and other objects. The only input needed consists of the electron…

Condensed Matter · Physics 2009-10-31 Erika Hult , Henrik Rydberg , Bengt I. Lundqvist , David C. Langreth

We investigate the potential energy curves of rare-gas dimers with various ranges and strengths of interparticle interactions (nuclear-electron, electron-electron, and nuclear-nuclear interactions). Our investigation is based on the highly…

Chemical Physics · Physics 2016-02-05 Yu-Ting Chen , Kerwin Hui , Jeng-Da Chai

We study long range interactions between two Rydberg atoms and predict the existence of ultralong range Rydberg dimers with equilibrium distances of many thousand Bohr radii. We calculate the dispersion coefficients $C_{5}$, $C_{6}$ and…

Atomic Physics · Physics 2009-11-07 Christophe Boisseau , Ionel Simbotin , Robin Cote

We report a theoretical study on the long-range additive and nonadditive potentials for a three-body hybrid atom-atom-ion system composed of one ground $S$ state Li atom, one excited $P$ state Li atom and one ground $S$ state Li$^+$ ion,…

Atomic Physics · Physics 2021-09-02 Pei-Gen Yan , Li-Yan Tang , Zong-Chao Yan , James F. Babb

We report on measurements of the anisotropic dynamical polarizability of Dy near the 626-nm intercombination line, employing modulation spectroscopy in a one-dimensional optical lattice. To eliminate large systematic uncertainties resulting…

To investigate the role of long-range van der Waals interactions in static friction, we derive an analytic expression for the coefficient of static friction $\mu_s$ between two thin layers of polarizable materials under zero load. For…

Mesoscale and Nanoscale Physics · Physics 2022-09-14 Ram Narayanan , Prachi Parashar , K. V. Shajesh , S. Vijayakumar

We investigate the dynamics of polar systems coupled to classical external beams in the ultrastrong coupling regime. The permanent dipole moments (PDMs) sustained by polar systems can couple to the electromagnetic field, giving rise to a…

Optics · Physics 2025-05-13 Piotr Gładysz , Karolina Słowik

Many organic molecules possess large permanent dipole moments that differ depending on the electronic state. These permanent dipoles influence both intermolecular coupling and interactions with the optical fields, yet they are often…

Quantum Physics · Physics 2025-08-18 Matthew Freed , Dominic M. Rouse , Andrea Rocco , Jim Al-Khalili , Marian Florescu , Adam Burgess

Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron…

Materials Science · Physics 2009-11-11 Janos G. Angyan , Iann C. Gerber , Andreas Savin , Julien Toulouse

Theories for the effective polarisability of a small particle in a medium are presented using different levels of approximation: we consider the virtual cavity, real cavity and the hard-sphere models as well as a continuous interpolation of…

A method for determination of atomic dipole matrix elements of principal transitions from the value of dispersion coefficient C_6 of molecular potentials correlating to two ground-state atoms is proposed. The method is illustrated on atomic…

Atomic Physics · Physics 2009-11-07 Andrei Derevianko

We present a comprehensive theoretical study of the electronic structures of the Yb atom and the Yb$_2$ molecule, respectively, focusing on their ground and lowest-lying electronically excited states. Our study includes various…

The excited-state properties in a series of coumarin solar cell dyes are investigated with a long-range-corrected (LC) functional which asymptotically incorporates Hartree-Fock exchange. Using time-dependent density functional theory…

Chemical Physics · Physics 2010-12-21 Bryan M. Wong , Joseph G. Cordaro

Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

Quantum Physics · Physics 2015-06-11 Harald R. Haakh , Stefan Scheel

The study of long-range interactions is increasingly becoming essential due to its various applications in cold atomic physics. These interactions can be conveniently expressed in terms of dispersion coefficients. In the present work,…

Atomic Physics · Physics 2022-01-19 Neelam Shukla , Harpreet Kaur , Bindiya Arora , Rajesh Srivastava

The isotropic and anisotropic coefficients $C^{l,m}_n$ of the long-range spherical expansion $\sim 1/R^n$ ($R$ -- the intermolecular distance) of the dispersion and inductions intermolecular energies are calculated using the first…

Chemical Physics · Physics 2023-04-04 Leonid Shirkov , Michał Tomza

We revisit the derivation of multipole contributions to the atom-wall interaction previously presented in [G. Lach et al., Phys. Rev. A 81, 052507 (2010)]. A careful reconsideration of the angular-momentum decomposition of the second-,…

Atomic Physics · Physics 2024-01-12 Ulrich D. Jentschura