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Cd-doped La(O,F)BiS2 single crystals were grown using a CsCl/KCl flux. The grown crystals have a plate-like shape with ~1-2 mm square size in a well-developed ab-plane. The Cd doping in the crystals was successfully characterized by single…

Superconductivity · Physics 2017-06-16 Masanori Nagao , Masashi Tanaka , Satoshi Watauchi , Yoshihiko Takano , Isao Tanaka

Recently, two-fold symmetric in-plane anisotropy of the superconducting properties have been observed in a single crystal of BiCh2-based (Ch: S, Se) layered superconductor LaO0.5F0.5BiSSe having a tetragonal (four-fold-symmetric) in-plane…

The superconducting and normal-state properties of La$_{1-x}$Sm$_{x}$O$_{0.5}$F$_{0.5}$BiS$_{2}$ (0.1 $\leqslant$ $x$ $\leqslant$ 0.9) have been studied via electrical resistivity, magnetic susceptibility, and specific heat measurements. By…

Superconductivity · Physics 2015-04-15 Y. Fang , D. Yazici , B. D. White , M. B. Maple

We have demonstrated a pressure-induced phase transition from a low-Tc phase to a high-Tc phase in a single crystal of the superconductor LaO0.5F0.5BiSe2. The high-Tc phase appears at 2.16 GPa and the maximum superconducting transition…

From field-angle dependent Andreev reflection spectroscopy on single crystals of La(O,F)BiSeS, which belongs to the recently discovered BiCh 2 (Ch = S, Se) based layered superconductors, we found that the superconductivity in La(O,F)BiSeS…

We study the impact of hydrostatic pressure on superconductivity of new BiS2 based layered REO0.5F0.5BiS2 (RE-La, Pr, and Nd) compounds through the measurements of dc electrical resistivity. The REO0.5F0.5BiS2 (RE-La, Pr and Nd) compounds…

Superconductivity · Physics 2015-02-25 Rajveer Jha , H. Kishan , V. P. S. Awana

In the iron arsenide compound BaFe2As2, superconductivity can be induced either by a variation of its chemical composition, e.g., by replacing Fe with Co, or by a reduction of the unit-cell volume through the application of hydrostatic…

F-substituted NdOBiS2 superconducting single crystals were grown using CsCl/KCl flux. This is the first example of the single-crystal growth of a BiS2-based superconductor. The obtained single crystals had a plate-like shape with a size of…

We examined Lead (Pb) Substitution effect on a single crystal of a layered superconductor LaO0.5F0.5BiS2. Pb concentration dependence of the lattice constant showed slight anomaly at about 8% and 9% substitution of Pb for Bi. These samples…

Superconductivity · Physics 2017-12-06 S. Otsuki , S. Demura , Y. Sakai , Y. Fujisawa , H. Sakata

We have investigated Se substitution effect to superconductivity of an optimally-doped BiS2-based superconductor Eu0.5La0.5FBiS2. Eu0.5La0.5FBiS2-xSex samples with x = 0-1 were synthesized. With increasing x, in-plane chemical pressure is…

We perform first-principles band structure calculations for the tetragonal and monoclinic structures of LaO$_{0.5}$F$_{0.5}$BiS$_2$. We find that the Bi $6p_{x,y}$ bands on two BiS$_2$ layers exhibit a sizable splitting at the X = ($\pi$,…

Superconductivity · Physics 2016-08-08 Masayuki Ochi , Ryosuke Akashi , Kazuhiko Kuroki

The layered compound LaOBiSSe was successfully synthesized by a two-step solid-state reaction method, which is isostructural with the quaternary compound LaOBiS2 indicated by the powder X-ray diffraction characterization, and the crystal…

Superconductivity · Physics 2014-05-01 Xiao-Chuan Wang , Dong-Yun Chen , Qi Guo , Jia Yu , Bin-Bin Ruan , Qing-Ge Mu , Gen-Fu Chen , Zhi-An Ren

Single crystals of Ba_{1-x}Rb_{x}Fe_2As_2 with x=0.05-0.1 have been grown from Sn flux and are bulk superconductors with T_c up to 23 K. The crystal structure was determined by X-ray diffraction analysis, and Sn is found to be incorporated…

Superconductivity · Physics 2009-04-07 Z. Bukowski , S. Weyeneth , R. Puzniak , P. Moll , S. Katrych , N. D. Zhigadlo , J. Karpinski , H. Keller , B. Batlogg

We report the upper critical field (Bc2) in the BiCh2-based superconductors CeOBiS1.7Se0.3 and PrO0.5F0.5BiS2-xSex (x = 0, 0.3). Single crystals of CeOBiS1.7Se0.3 and PrO0.5F0.5BiS2-xSex (x = 0, 0.3) were grown using the flux method.…

Superconductivity · Physics 2022-09-22 Ryosuke Kiyama , Kazuhisa Hoshi , Yosuke Goto , Masanori Nagao , Yoshikazu Mizuguchi

We present scanning tunneling microscopy and spectroscopy measurements on a cleaved surface of the LaO0.9F0.1BiSe2 single crystals. Tunneling spectra show a finite local density of states at EF, which is consistent with metallic…

Superconductivity · Physics 2018-08-15 N Ishida , S Demura , Y Fujisawa , S Ohta , K Miyata , H Sakata

Polycrystalline samples of F-substituted LnOBiS2 (Ln = La, Ce, Pr, Nd, Yb) compounds were synthesized by solid-state reaction. The samples were characterized by x-ray diffraction measurements and found to have the ZrCuSiAs crystal…

Superconductivity · Physics 2013-01-18 D. Yazici , K. Huang , B. D. White , A. H. Chang , A. J. Friedman , M. B. Maple

The high anisotropy in RO1-aFaBiS2 (R denotes a rare-earth element) superconductors demonstrates their potential use as intrinsic Josephson junctions, considering the weak coupling among BiS2-PrO(F)-BiS2…

Superconductivity · Physics 2015-07-27 Masanori Nagao , Akira Miura , Satoshi Watauchi , Yoshihiko Takano , Isao Tanaka

We report superconductivity in the novel 112-type iron-based compound Ca1-xLaxFeAs2. Single-crystal X-ray diffraction analysis revealed that the compound crystallizes in a monoclinic structure (space group P21), in which Fe2As2 layers…

In this paper, we reported the structural properties and superconductivity of Mg(B1-xCx)2 compounds. Powder x-ray diffraction results indicate that the samples crystallize in a hexagonal AlB2-type structure. Due to the chemical activity of…

Materials Science · Physics 2009-11-07 Shao-ying Zhang , Jian Zhang , Tong-yun Zhao , Chuan-bing Rong , Bao-gen Shen , Zhao-hua Cheng

"F-free" CeOBiS$_2$ single crystals have successfully grown, thoroughly eliminating a concern about F-contamination by using a high-purity CsCl flux. The obtained crystals have a plate-like shape with a size of 1.0-3.0 mm in the…