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In this contribution we show that a suitably defined nonequilibrium entropy of an N-body isolated system is not a constant of the motion in general and its variation is bounded, the bounds determined by the thermodynamic entropy, i.e., the…

Statistical Mechanics · Physics 2009-11-13 A. Perez-Madrid

The interplay of non-classical volume, von Neumann entropy, entropy production, and ergotropy is investigated in various open quantum systems. Two categories of open quantum system models are utilized: spin-spin and spin-boson interaction…

Quantum Physics · Physics 2025-10-20 Jai Lalita , Subhashish Banerjee

We present a method of estimating the rate of entropy production in underdamped dynamics by decomposing it into contributions originating in different non-equilibrium effects. Specifically, a non-zero average velocity, a non-thermal width…

Statistical Mechanics · Physics 2025-12-01 Mario A. Ciampini , Jakob Rieser , Nikolai Kiesel , Andreas Dechant

Stochastic entropy production, which quantifies the difference between the probabilities of trajectories of a stochastic dynamics and its time reversals, has a central role in nonequilibrium thermodynamics. In the theory of probability, the…

Statistical Mechanics · Physics 2020-03-04 Ying-Jen Yang , Hong Qian

The stochastic entropy generated during the evolution of a system interacting with an environment may be separated into three components, but only two of these have a non-negative mean. The third component of entropy production is…

Statistical Mechanics · Physics 2013-05-30 Ian J. Ford , Richard E. Spinney

Entropy, its production, and its change in a dynamical system can be understood from either a fully stochastic dynamic description or from a deterministic dynamics exhibiting chaotic behavior. By taking the former approach based on the…

Mathematical Physics · Physics 2025-08-26 Hong Qian , Zhongwei Shen

Out-of-equilibrium systems continuously generate entropy, with its rate of production being a fingerprint of non-equilibrium conditions. In small-scale dissipative systems subject to thermal noise, fluctuations of entropy production are…

Statistical Mechanics · Physics 2023-01-19 Prajwal Padmanabha , Daniel Maria Busiello , Amos Maritan , Deepak Gupta

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati

An essential quantity in quantum information theory is the von Neumann entropy which depends entirely on the quantum density operator. Once known, the density operator reveals the statistics of observables in a quantum process, and the…

Systems and Control · Electrical Eng. & Systems 2023-09-08 Mark Balas , Vinod P. Gehlot , Tristan D. Griffith

Recent studies have pointed out the intrinsic dependence of figures of merit of thermodynamic relevance -- such as work, heat and entropy production -- on the amount of quantum coherences that is made available to a system. However, whether…

Quantum Physics · Physics 2023-02-03 G. Zicari , B. Çakmak , Özgür E. Müstecaplıoğlu , M. Paternostro

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

Statistical Mechanics · Physics 2009-11-13 Stefan Thurner , Rudolf Hanel

In this paper, we review the concept of entropy in connection with the description of quantum unstable systems. We revise the conventional definition of entropy due to Boltzmann and extend it so as to include the presence of complex-energy…

Quantum Physics · Physics 2018-05-09 Osvaldo Civitarese , Manuel Gadella

Recently, Di\'osi et al. (Int. J. Quant. Inf. 4, 99 (2006)) introduced a simple, yet very interesting model for reservoirs, in order to study the relationship between thermodynamic entropy production of a system and the corresponding von…

Mathematical Physics · Physics 2017-06-15 J. Z. Bernád , A. B. Frigyik

In this paper we discuss the meaning of the Schnakenberg formula for entropy production in non-equilibrium systems. To this end we consider a non-equilibrium system as part of a larger isolated system which includes the environment. We…

Statistical Mechanics · Physics 2015-09-30 Robert Ziener , Amos Maritan , Haye Hinrichsen

We define correlational (von Neumann) entropy for an individual quantum state of a system whose time-independent hamiltonian contains random parameters and is treated as a member of a statistical ensemble. This entropy is representation…

chao-dyn · Physics 2013-01-16 Valentin V. Sokolov , B. Alex Brown , Vladimir Zelevinsky

It is well known that a Shannon based definition of information entropy leads in the classical case to the Boltzmann entropy. It is tempting to regard the Von Neumann entropy as the corresponding quantum mechanical definition. But the…

Quantum Physics · Physics 2009-11-10 Alexander Stotland , Andrei A. Pomeransky , Eitan Bachmat , Doron Cohen

*First-principles derivation of the entropy production in erectric static conduction. *The second-order (symmetric) density matrix contributes to the entropy production. *New schemes of steady states formulated using a relaxation-type von…

Statistical Mechanics · Physics 2011-03-31 Masuo Suzuki

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

One of the major goals of quantum thermodynamics is the characterization of irreversibility and its consequences in quantum processes. Here, we discuss how entropy production provides a quantification of the irreversibility in open quantum…

The question of deriving general force/flux relationships that apply out of the linear response regime is a central topic of theories for nonequilibrium statistical mechanics. This work applies an information theory perspective to compute…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers