Statistical mechanical theory of an oscillating isolated system. The relaxation to equilibrium
Statistical Mechanics
2009-11-13 v2
Abstract
In this contribution we show that a suitably defined nonequilibrium entropy of an N-body isolated system is not a constant of the motion in general and its variation is bounded, the bounds determined by the thermodynamic entropy, i.e., the equilibrium entropy. We define the nonequilibrium entropy as a convex functional of the set of n-particle reduced distribution functions (n=0,......., N) generalizing the Gibbs fine-grained entropy formula. Additionally, as a consequence of our microscopic analysis we find that this nonequilibrium entropy behaves as a free entropic oscillator. In the approach to the equilibrium regime we find relaxation equations of the Fokker-Planck type, particularly for the one-particle distribution function.
Keywords
Cite
@article{arxiv.0709.1214,
title = {Statistical mechanical theory of an oscillating isolated system. The relaxation to equilibrium},
author = {A. Perez-Madrid},
journal= {arXiv preprint arXiv:0709.1214},
year = {2009}
}