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Effects of coupling between a molecular exciton and a surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons are investigated using the nonequilibrium Green's function method.…

Materials Science · Physics 2013-06-12 Kuniyuki Miwa , Mamoru Sakaue , Hideaki Kasai

Plexciton is the formation of new hybridized energy states originated from the coupling between plasmon and exciton. To reveal the optical properties of both exciton and plexciton, we develop a classic oscillator model to describe the…

Optics · Physics 2022-07-12 Yuqing Cheng , Mengtao Sun

We aim to clarify the role that absorption plays in nonlinear optical processes in a variety of metallic nanostructures and show how it relates to emission and conversion efficiency. We define a figure of merit that establishes the…

The coupling between molecular exciton and gap plasmons plays a key role in single molecular electroluminescence induced by a scanning tunneling microscope (STM). But it has been difficult to clarify the complex experimental phenomena. By…

Mesoscale and Nanoscale Physics · Physics 2018-11-21 Lei-Lei Nian , Jing-Tao Lü

We investigate theoretically the effects of interaction between an optical dipole (semiconductor quantum dot or molecule) and metal nanoparticles. The calculated absorption spectra of hybrid structures demonstrate strong effects of…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Jie-Yun Yan , Wei Zhang , Suqing Duan , Xian-Geng Zhao , Alexander O. Govorov

The optical response of an artificial hybrid molecule system composed of two metallic nanoparticles (MNPs) and a semiconductor quantum dot (SQD) is investigated theoretically due to the plasmon-exciton-plasmon coupling effects on the…

Quantum interference effects and decoherence mechanisms in single-molecule junctions are analyzed employing a nonequilibrium Green's function approach. Electrons tunneling through quasi-degenerate states of a nanoscale molecular junction…

Mesoscale and Nanoscale Physics · Physics 2011-07-25 R. Härtle , M. Butzin , O. Rubio-Pons , M. Thoss

Absorption is usually expected to be detrimental to quantum coherence effects. However, the situation for complex absorption spectra has been little studied yet. We consider the resonance fluorescence of excitons in a semiconductor quantum…

Quantum Physics · Physics 2016-03-24 P. Grünwald , W. Vogel

We study plasmon-exciton interaction by using topological singularities to spatially confine, selectively deliver, cotrap and optically probe colloidal semiconductor and plasmonic nanoparticles. The interaction is monitored in a single…

Mesoscale and Nanoscale Physics · Physics 2017-04-26 P. J. Ackerman , Haridas Mundoor , I. I. Smalyukh , Jao van de Lagemaat

The way molecules absorb, transfer, and emit light can be modified by coupling them to optical cavities. The extent of the modification is often defined by the cavity-molecule coupling strength, which depends on the number of coupled…

Optics · Physics 2021-06-11 Adarsh B Vasista , Kishan S Menghrajani , William L Barnes

The electronic excitation of molecules triggers diverse phenomena such as luminescence and photovoltaic effects, which are the bases of various energy-converting devices. Understanding and control of the excitations at the single-molecule…

Chemical Physics · Physics 2017-07-12 Hiroshi Imada , Kuniyuki Miwa , Miyabi Imai-Imada , Shota Kawahara , Kensuke Kimura , Yousoo Kim

We have developed a model in order to account for electron-vibrational effects on absorption, luminescence of molecular aggregates and exciton-polaritons in nanofibers. The model generalizes the mean-field electron-vibrational theory…

Mesoscale and Nanoscale Physics · Physics 2019-03-22 Boris D. Fainberg

We show that individual vibrational modes in single-molecule junctions with asymmetric molecule-lead coupling can be selectively excited by applying an external bias voltage. Thereby, a non-statistical distribution of vibrational energy can…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 R. Volkovich , R. Härtle , M. Thoss , U. Peskin

Excitation energy transfer is crucially involved in a variety of systems. During the process, the non-Condon vibronic coupling and the surrounding solvent interaction may synergetically play important roles. In this work, we study the…

Chemical Physics · Physics 2021-06-24 Zi-Hao Chen , Yao Wang , Rui-Xue Xu , YiJing Yan

We discuss coherent exciton-polariton states in long molecular chains that are formed due to the interaction of molecular excitations with both vacuum photons and surface excitations of the neighboring reflecting substrate. The resonance…

Other Condensed Matter · Physics 2009-11-13 Yu. N. Gartstein , V. M. Agranovich

The strong coupling between intense laser fields and valence electrons in molecules causes a distortion of the potential energy hypersurfaces which determine the motion of nuclei in a molecule and influences possible reaction pathways. The…

Surface lattice resonance supported on plasmonic nanoparticle arrays enhances light-matter interactions for applications such as photoluminescence enhancement. The photoluminescence process is enhanced through confining light beyond the…

Optics · Physics 2024-06-14 Joshua T. Y. Tse , Shunsuke Murai , Katsuhisa Tanaka

This study investigated spectral changes in the absorption cross-sections of single strong coupling systems composed of single silver nanoparticle dimers and a few dye molecules during the quenching of surface-enhanced resonant Raman…

Optics · Physics 2019-06-10 Tamitake Itoh , Yuko S. Yamamoto , Takayuki Okamoto

Representation of molecular vibrational degrees of freedom by independent harmonic oscillators, when describing electronic spectra or electronic excitation energy transport, raises unfavourable effects as vibrational energy relaxation…

Chemical Physics · Physics 2018-07-26 Mantas Jakučionis , Vladimir Chorošajev , Darius Abramavičius

The interpretation of nanoplasmonic effects on molecular properties, such as metal-enhanced absorption or fluorescence, typically assumes a fully coherent picture (in the quantum-mechanical sense) of the phenomena. Yet, there may be…

Chemical Physics · Physics 2019-07-29 Emanuele Coccia , Stefano Corni
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