Correlated vibration-solvent effects on the non-Condon exciton spectroscopy
Abstract
Excitation energy transfer is crucially involved in a variety of systems. During the process, the non-Condon vibronic coupling and the surrounding solvent interaction may synergetically play important roles. In this work, we study the correlated vibration-solvent influences on the non-Condon exciton spectroscopy. Statistical analysis is elaborated for the overall vibration-plus-solvent environmental effects. Analytic solutions are derived for the linear absorption of monomer systems. General simulations are accurately carried out via the dissipaton-equation-of-motion approach. The resulted spectra in either the linear absorption or strong field regime clearly demonstrate the coherence enhancement due to the synergetic vibration-solvent correlation.
Keywords
Cite
@article{arxiv.2104.06786,
title = {Correlated vibration-solvent effects on the non-Condon exciton spectroscopy},
author = {Zi-Hao Chen and Yao Wang and Rui-Xue Xu and YiJing Yan},
journal= {arXiv preprint arXiv:2104.06786},
year = {2021}
}
Comments
13 pages, 3 figures