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Few- and single-layer MoS2 host substantial densities of defects. They are thought to influence the doping level, the crystal structure, and the binding of electron-hole pairs. We disentangle the concomitant spectroscopic expression of all…

To reduce Schottky-barrier-induced contact and access resistance, and the impact of charged impurity and phonon scattering on mobility in devices based on 2D transition metal dichalcogenides (TMDs), considerable effort has been put into…

First-principles band structure investigations of the electronic, optical and magnetic properties of Mo-doped In$_2$O$_3$ reveal the vital role of magnetic interactions in determining both the electrical conductivity and the Burstein-Moss…

Materials Science · Physics 2007-05-23 J. E. Medvedeva

Two-dimensional (2D) semiconductors are likely to dominate next-generation electronics due to their advantages in compactness and low power consumption. However, challenges such as high contact resistance and inefficient doping hinder their…

Materials Science · Physics 2024-10-11 Raagya Arora , Ariel R. Barr , Daniel T. Larson , Michele Pizzochero , Efthimios Kaxiras

Theoretical work has suggested that monolayer MoS2 doped with Mn should behave as a two-dimensional dilute magnetic semiconductor, which would open up possibilities for spintronic applications, device physics, and novel ground states. The…

We present an atomistic model for predicting the distribution of doping electric charges in layered molybdenum disulfide (MoS$_{2}$). This model mimics the charge around each ion as a net Gaussian-spatially-distributed charge plus an…

Mesoscale and Nanoscale Physics · Physics 2018-10-18 Yida Yang , Michel Devel , Zhao Wang

The potential application of the single-layer MoS2 as photocatalyst was revealed in this work based on first-principles calculations. It is found that the pristine single-layer MoS2 is a good candidate for photocatalyst, and its catalyzing…

Materials Science · Physics 2013-05-15 Yunguo Li , Yan-ling Li , Carlos Moyses Araujo , Wei Luo , Rajeev Ahuja

Bi$_2$Se$_3$ is one of the most promising topological insulators, but it suffers from intrinsic n-doping due to Se-vacancies, which shifts the Fermi level into the bulk conduction band, leading to topologically trivial carriers. Recently it…

Materials Science · Physics 2023-10-25 Cheng Fan , Kazuyuki Sakamoto , Peter Krüger

Atom controlled sub-nanometer MoS$_2$ pores have been recently fabricated. Oxidative environments are of particular interest for MoS$_2$ applications in electronics, sensing and energy storage. In this work we carried out first-principles…

Materials Science · Physics 2023-01-31 Murilo Kendjy Onita , Flavio Bento de Oliveira , Andreia Luisa da Rosa

Adsorption of molecular oxygen on B-, N-, Al-, Si-, P-, Cr- and Mn-doped graphene is theoretically studied using density functional theory in order to clarify if O2 can change the possibility of using doped graphene for gas sensors,…

Mesoscale and Nanoscale Physics · Physics 2015-03-14 Jiayu Dai , Jianmin Yuan

Dopability in semiconductors plays a crucial role in device performance. Using the first-principles density-functional theory calculations, we investigate systematically the doping properties of layered MX2 (M= Mo, W; X=S, Te) by replacing…

Materials Science · Physics 2018-04-27 Dan Guo , Kaike Yang , Tao Shen , Jin Xiao , Li-Ming Tang , Zhongming Wei , Guanghui Zhou , Hui-Xiong Deng

We investigate electromechanical properties of two-dimensional MoS$_2$ monolayers in the 1H, 1T, and 1T$^\prime$ structures as a function of charge doping by using density functional theory. We find isotropic elastic moduli in the 1H and 1T…

Materials Science · Physics 2018-02-14 Nguyen T. Hung , Ahmad R. T. Nugraha , Riichiro Saito

Structural and electronic properties of pristine and transition metal doped ZnS monolayer are investigated within the framework of density functional theory. The pristine ZnS monolayer is showing direct band gap of about 2.8 eV. The…

Materials Science · Physics 2017-11-16 Rajneesh Chaurasiya , Ambesh Dixit

By extracting the permittivity of monolayer MoS2 from experiments, the optical absorption of monolayer MoS2 prepared on top of one-dimensional photonic crystal (1DPC) or metal films is investigated theoretically. The 1DPC and metal films…

Optics · Physics 2016-02-01 Jiang-Tao Liu , Tong-Biao Wang , Xiao-Jing Li , Nian-Hua Liu

Two-dimensional (2D) $\beta$-TeO$_2$ has gained attention as a promising material for optoelectronic and power device applications, thanks to its transparency and high hole mobility. However, the underlying mechanism behind its $p$-type…

Mesoscale and Nanoscale Physics · Physics 2025-01-08 Rafael Costa-Amaral , Soungmin Bae , Vu Thi Ngoc Huyen , Yu Kumagai

Density functional theory calculations have been carried out to investigate single-layer phosphorene functionalized with two kinds of organic molecules, i.e. an electrophilic molecule tetracyano-p-quinodimethane (TCNQ) as electron acceptor…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 Ruiqi Zhang , Bin Li , Jinlong Yang

The electronic structures of boron nitride nanotubes (BNNTs) doped by organic molecules are investigated with density functional theory. Electrophilic molecule introduces acceptor states in the wide gap of BNNT close to the valence band…

Materials Science · Physics 2009-11-13 Wei He , Zhenyu Li , Jinlong Yang , J. G. Hou

We describe a photogating effect in mono- and few-layer MoS2, which allows the control of the charge carrier density by almost two orders of magnitude without electrical contacts. Our Raman studies are consistent with physisorbed…

We report on the first demonstration of p-type doping in large area few-layer films of (0001)-oriented chemical vapor deposited (CVD) MoS2. Niobium was found to act as an efficient acceptor up to relatively high density in MoS2 films. For a…

Doping is an effective way to modify the electronic property of two-dimensional (2D) materials and endow them with new functionalities. However, wide-range control of the substitutional doping concentration with large scale uniformity…