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A local approximation for dynamic polarizability leads to a nonlocal functional for the long-range dispersion interaction energy via an imaginary-frequency integral. We analyze several local polarizability approximations and argue that the…

Chemical Physics · Physics 2015-03-17 Oleg A. Vydrov , Troy Van Voorhis

We consider the system of three ${}^4$He atoms to assess whether a pure van der Waals potential can be used as a starting point for an effective field theory to describe three-body processes in ultracold atomic systems. Using a long-range…

Quantum Gases · Physics 2021-08-11 Daniel Odell , Arnoldas Deltuva , Lucas Platter

We consider the van der Waals interaction between two ground-state atoms embedded in adjacent semi-infinite magnetodielectric media, with emphasis on medium effects on it. We demonstrate that, in this case, at small atom-atom distances the…

Quantum Physics · Physics 2009-11-13 M. S. Tomas

The 1%-accurate calculations of the van der Waals interaction between an atom and a cavity wall are performed in the separation region from 3 nm to 150 nm. The cases of metastable He${}^{\ast}$ and Na atoms near the metal, semiconductor or…

Quantum Physics · Physics 2009-11-11 A. O. Caride , G. L. Klimchitskaya , V. M. Mostepanenko , S. I. Zanette

We calculate the van der Waals dispersive interaction between a neutral but polarizable atom and a perfectly conducting isolated sphere in the nonretarded case. We make use of two separate models, one being the semiclassical…

Quantum Physics · Physics 2009-03-13 M. M. Taddei , T. N. C. Mendes , C. Farina

When an atom in vacuum is near a surface of a dielectric the energy of a fluctuating electromagnetic field depends on a distance between them resulting, as known, in the force called van der Waals one. Besides this fluctuation phenomenon…

Quantum Physics · Physics 2015-05-27 B. Ivlev

The structure and stability of atomic and molecular systems with van der Waals (vdW) bonding are often determined by the interplay between attractive dispersion interactions and repulsive interactions caused by electron confinement. Arising…

Chemical Physics · Physics 2022-02-17 Ornella Vaccarelli , Dmitry V. Fedorov , Martin Stöhr , Alexandre Tkatchenko

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

Quantum Physics · Physics 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

We consider the dispersion interaction between two ground-state hydrogen atoms, interacting with the quantum electromagnetic field in the vacuum state, in the presence of an external static electric field, both in the nonretarded and in the…

Quantum Physics · Physics 2020-01-10 G. Fiscelli , L. Rizzuto , R. Passante

The van der Waals-London's law, for a collection of atoms at large separation, states that their interaction energy is pairwise attractive and decays proportionally to one over their distance to the sixth. The first rigorous result in this…

Mathematical Physics · Physics 2014-10-23 Ioannis Anapolitanos

We apply the DDC formalism [proposed by Dalibard, Dupont-Roc and Cohen-Tannoudji] to study the average rate of change of energy of two identical two-level atoms interacting with the vacuum massless scalar field in synchronized motion along…

Quantum Physics · Physics 2020-01-22 Wenting Zhou , Hongwei Yu

A quantum electrodynamic calculation of the interaction of an excited-state atom with a ground-state atom is performed. For an excited reference state and a lower-lying virtual state, the contribution to the interaction energy naturally…

Quantum Physics · Physics 2017-05-19 U. D. Jentschura , V. Debierre

In the ultra-cold regime Van der Waals forces between neutral atoms can be represented by short range effective interactions. We show that universal low energy scaling features of the underlying vdW long range force stemming from two photon…

Other Condensed Matter · Physics 2015-05-20 E. Ruiz Arriola

It is well known that for the case of two neutral but electrically polarizable atoms the consideration or not of retardation effects on the dispersive van der Waals force between them leads essentially to different power laws for the…

Atomic Physics · Physics 2007-05-23 C. Farina , F. C. Santos , A. C. Tort

The van der Waals (vdW) interaction plays a prominent role between neutral objects at separations where short ranged chemical forces are negligible. This type of dispersive coupling is determined by the interplay between geometry and…

Mesoscale and Nanoscale Physics · Physics 2022-06-02 Dai-Nam Le , Pablo Rodriguez-Lopez , Lilia M. Woods

The long-range quadrupole-quadrupole ($\sim R^{-5}$) and leading dispersion ($\sim R^{-6}$) interactions between all pairs of excited Hg($6s6p$) $^3P_0$, $^3P_1$, $^3P_2$, and $^1P_1$ atoms are determined. The quadrupole moments are…

Atomic Physics · Physics 2009-11-13 James S. Cohen , Andrei Derevianko

We report on the observation of ultralong range interactions in a gas of cold Rubidium Rydberg atoms. The van-der-Waals interaction between a pair of Rydberg atoms separated as far as 100,000 Bohr radii features two important effects:…

We consider a molecule in the Born-Oppenheimer approximation interacting with a plate of infinite thickness, i.e, a half--space, which is perfectly conducting or dielectric. It is well--known in the physics literature that in this case the…

Mathematical Physics · Physics 2022-08-17 Ioannis Anapolitanos , Mariam Badalyan , Dirk Hundertmark

The onset of retardation effects in atom-wall interactions is studied. It is shown that the transition range from the 1/z^3 short-range (van der Waals) interaction to the 1/z^4 long-range (Casimir) retarded interaction critically depends on…

Other Condensed Matter · Physics 2024-03-18 T. Das , C. A. Ullrich , U. D. Jentschura

The noncontact (van der Waals) friction is an interesting physical effect which has been the subject of controversial scientific discussion. The "direct" friction term due to the thermal fluctuations of the electromagnetic field leads to a…

Quantum Physics · Physics 2016-10-13 U. D. Jentschura , M. Janke , M. DeKieviet