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We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

Soft Condensed Matter · Physics 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

In this paper, we present a 2D numerical model developed to simulate the dynamics of soft, deformable particles. To accommodate significant particle deformations, the particle surface is represented as a narrow shell composed of mass points…

Computational Physics · Physics 2025-04-01 Yohann Trivino , Vincent Richefeu , Farhang Radjai , Komlanvi Lampoh , Jean-Yves Delenne

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

Soft Condensed Matter · Physics 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

We propose that several mechanisms contribute to friction in a polymer melt adsorbed at a structured surface. The first one is the well known disentanglement of bulk polymer chains from the surface layer. However, if the surface is ideal at…

Soft Condensed Matter · Physics 2007-05-23 X. Zhou , D. Andrienko , L. Delle Site , K. Kremer

Deformable colloids and macromolecules adsorb at interfaces, as they decrease the interfacial energy between the two media. The deformability, or softness, of these particles plays a pivotal role in the properties of the interface. In this…

The adsorption of a single multi-block $AB$-copolymer on a solid planar substrate is investigated by means of computer simulations and scaling analysis. It is shown that the problem can be mapped onto an effective homopolymer adsorption…

Soft Condensed Matter · Physics 2008-06-27 Swati Bhattacharya , Hsiao-Ping Hsu , Andrey Milchev , Vakhtang G. Rostiashvili , Thomas A. Vilgis

We analyze the effective triplet interactions between the centers of star polymers in a good solvent. Using an analytical short distance expansion inspired by scaling theory, we deduce that the triplet part of the three-star force is…

Soft Condensed Matter · Physics 2015-06-24 Christian von Ferber , Arben Jusufi , Christos N. Likos , Hartmut Lowen , Martin Watzlawek

The effective interaction between charged colloidal particles confined between two planar like-charged walls is investigated using computer simulations of the primitive model describing asymmetric electrolytes. In detail, we calculate the…

Soft Condensed Matter · Physics 2016-08-15 E. Allahyarov , I. D'Amico , H. Löwen

We study the conformation and topological properties of cyclical star polymers with $f$ ring arms, each made of $n$ beads. We find that the conformational properties of unlinked cyclical star polymers are compatible to those of linear star…

Soft Condensed Matter · Physics 2024-09-04 Davide Breoni , Emanuele Locatelli , Luca Tubiana

A self-interacting polymer with one end attached to a sticky surface has been studied by means of a flat-histogram stochastic growth algorithm known as FlatPERM. We examined the four-dimensional parameter space of the number of monomers up…

Statistical Mechanics · Physics 2009-11-10 J. Krawczyk , A. L. Owczarek , T. Prellberg , A. Rechnitzer

We present the exact solutions of various directed walk models of polymers confined to a slit and interacting with the walls of the slit via an attractive potential. We consider three geometric constraints on the ends of the polymer and…

Statistical Mechanics · Physics 2009-11-11 R Brak , A L Owczarek , A Rechnitzer , S G Whittington

We analyze the structural behavior of a single polymer chain grafted to an attractive, flexible surface. Our model is composed of a coarse-grained bead-and-spring polymer and a tethered membrane. By means of extensive parallel tempering…

Soft Condensed Matter · Physics 2011-09-26 Steffen Karalus , Wolfhard Janke , Michael Bachmann

Equilibrium adsorption of disk-like particles on patterned adhesive surfaces is studied using Monte Carlo simulations. The surface is represented as a two-dimensional plane with circular adhesive domains arranged either regularly or…

Soft Condensed Matter · Physics 2026-05-05 Nazar Kukarkin , Taras Patsahan

The behavior of colloidal particles with a hard core and a soft shell has attracted the attention for researchers in the physical-chemistry interface not only due the large number of applications, but due the unique properties of these…

Soft Condensed Matter · Physics 2021-02-23 Murilo S. Marques , José Rafael Bordin

The conformational behavior of a coarse-grained finite polymer chain near an attractive spherical surface was investigated by means of multicanonical Monte Carlo computer simulations. In a detailed analysis of canonical equilibrium data…

Soft Condensed Matter · Physics 2018-01-03 Handan Arkin , Wolfhard Janke

We consider a coarse-grained (CG) model with pairwise interactions, suitable to describe low-density solutions of star-branched polymers of functionality $f$. Each macromolecule is represented by a CG molecule with $(f+1)$ interaction…

Soft Condensed Matter · Physics 2017-08-02 Roberto Menichetti , Andrea Pelissetto , Ferdinando Randisi

We employ a three-dimensional molecular dynamics to simulate translocation of a polymer through a nanopore driven by an external force. The translocation is investigated for different three pore diameter and two different external forces.…

Computational Physics · Physics 2019-12-03 Mohammadreza Niknam Hamidabad , Rouhollah Haji Abdolvahab

We show how to coarse grain polymers in a good solvent as single particles, interacting with density-independent or density-dependent interactions. These interactions can be between the centres of mass, the mid-points or end-points of the…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis , P. G. Bolhuis , R. Finken , V. Krakoviack , E. J. Meijer , J. P. Hansen

We consider the response of an adsorbed polymer that is pulled by an AFM within a simple geometric framework. We separately consider the cases of i) fixed polymer-surface contact point, ii) sticky case where the polymer is peeled off from…

Soft Condensed Matter · Physics 2009-11-11 Andreas Serr , Roland R. Netz

Single-chain Monte Carlo simulations of amphiphilic diblock star copolymers were carried out in continuous space using implicit solvents. Two distinct architectures were studied: stars with the hydrophobic blocks attached to the core, and…

Soft Condensed Matter · Physics 2009-11-10 Ronan Connolly , Edward G. Timoshenko , Yuri A. Kuznetsov