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We present a multiscale modelling framework that integrates density functional theory (DFT) with a phase-field model (PFM) to explore the intricate dynamics of grain growth in nanocrystalline {\alpha}-Fe single-phase alloy in the presence…

Materials Science · Physics 2024-06-13 Sandip Guin , Albert Linda , Yu-Chieh Lo , Somanth Bhowmick , Rajdip Mukherjee

Discrete particle simulation methods have been used to study axial segregation in a horizontal rotating cylinder that is partially filled with a mixture of two different kinds of granular particles. Under suitable conditions segregation was…

Soft Condensed Matter · Physics 2016-08-31 D. C. Rapaport

Grain boundaries (GBs) are a prolific microstructural feature that dominates the functionality of a wide class of materials. The change in functionality at a GB is a direct result of unique local atomic arrangements, different from those in…

Grain boundary diffusion in severely deformed Al-based AA5024 alloy is investigated. Different states are prepared by combination of equal channel angular processing and heat treatments, with the radioisotope $^{57}$Co being employed as a…

Germanium antimony telluride has been the most used and studied phase-change material for electronic memory due to its suitable crystallization temperature, amorphous to crystalline resistance contrast, and stability of the amorphous phase.…

Materials Science · Physics 2020-01-23 Shalini Tripathi , Paul Kotula , Manish Singh , Chanchal Ghosh , Gokhan Bakan , Helena Silva , Barry Carter

Compared to the widely investigated crystalline polymorphs of gallium oxide (Ga2O3), knowledge about its amorphous state is still limited. With the help of a machine-learning interatomic potential, we conducted large-scale atomistic…

Materials Science · Physics 2024-04-29 Jiahui Zhang , Junlei Zhao , Jesper Byggmästar , Erkka J. Frankberg , Antti Kuronen

Solute segregation at low-angle grain boundaries (LAGBs) critically affects the microstructure and mechanical properties of magnesium (Mg) alloys. In modern alloys containing multiple substitutional elements, understanding solute-solute…

Alloying a material and hence segregating solutes to grain boundaries is one way to tailor a material to the demands of its application. Direct observation of solute segregation is necessary to understand how the interfacial properties are…

Materials Science · Physics 2023-05-03 Lena Langenohl , Tobias Brink , Gunther Richter , Gerhard Dehm , Christian H. Liebscher

Electric fields and currents, which are used in innovative materials processing and electrochemical energy conversion, can often alter microstructures in unexpected ways. However, little is known about the underlying mechanisms. Using…

Materials Science · Physics 2021-05-12 Jiuyuan Nie , Chongze Hu , Qizhang Yan , Jian Luo

Disconnections, long recognized as the key mediators of grain boundary (GB) kinetics in polycrystalline materials, have traditionally been understood to nucleate through thermal or mechanical activation. In this work, using atomistic…

Materials Science · Physics 2026-03-09 Zuoyong Zhang , Chuang Deng

Grain boundaries (GBs) profoundly influence the properties and performance of materials, emphasizing the importance of understanding the GB structure and phase behavior. As recent computational studies have demonstrated the existence of…

Materials Science · Physics 2025-01-28 Enze Chen , Tae Wook Heo , Brandon C. Wood , Mark Asta , Timofey Frolov

Segregated impurities at grain boundaries can dramatically change the mechanical behavior of metals, while the mechanism is still obscure in some cases. Here, we suggest an unified approach to investigate segregation and its effects on the…

Materials Science · Physics 2017-12-20 Yunguo Li , Pavel Korzhavyi , Rolf Sandström , Christina Lilja

In this work, we quantify the impact of grain boundary (GB) and surface diffusion on fission gas bubble evolution and fission gas release in UO$_2$ nuclear fuel using simulations with a hybrid phase field/cluster dynamics model. We begin…

Faceted grain boundaries exhibit unusual segregation and migration tendencies. To gain a deeper understanding of how solute atoms interact with faceted interfacial structures during migration, this study probes the migration behavior of a…

Materials Science · Physics 2020-11-20 Megan J. McCarthy , Timothy J. Rupert

Grain boundaries in ultrafine grained (UFG) materials processed by severe plastic deformation (SPD) are often called "non-equilibrium" grain boundaries. Such boundaries are characterized by excess grain boundary energy, presence of long…

Materials Science · Physics 2012-03-30 Xavier Sauvage , Gerhard Wilde , Sergiy Divinski , Zenji Horita , Ruslan Valiev

Li$_6$PS$_5$Cl is a promising candidate for the solid electrolyte in all-solid-state Li-ion batteries. In applications, this material is in a polycrystalline state with grain boundaries (GBs) that can affect ionic conductivity. While…

Materials Science · Physics 2024-12-02 Yongliang Ou , Yuji Ikeda , Lena Scholz , Sergiy Divinski , Felix Fritzen , Blazej Grabowski

Grain boundary structural transitions can lead to significant changes in the properties and performance of materials. In multi-principal element alloys, understanding these transitions becomes complex due to phenomena such as local chemical…

Materials Science · Physics 2024-03-13 Ian Geiger , Diran Apelian , Xiaoqing Pan , Penghui Cao , Jian Luo , Timothy J. Rupert

Segregation to grain boundaries affects their cohesion, corrosion and embrittlement and plays a critical role in heterogeneous nucleation. In order to quantitatively study segregation and phase separation at grain boundaries, we derive a…

The control of solute segregation at grain boundaries (GBs) is essential in engineering alloy properties, however the structure-activity relationship of the key parameter-the segregation energies-still remains elusive. Here we propose the…

Materials Science · Physics 2022-10-20 Xin Li , Wang Gao , Qing Jiang

The initiation of intergranular corrosion at various types of grain boundaries (GBs) was studied at the nanometer scale on microcrystalline copper in 1 mM HCl aqueous solution. In situ Electrochemical Scanning Tunneling Microscopy (ECSTM)…

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