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A systematic study of phase separation effects in polycrystalline La_0.5 Ca_0.5 Mn O_3 obtained under different thermal treatments is reported. Samples with average grain size ranging from 200 to 1300 nm were studied. Magnetic and…

Materials Science · Physics 2009-10-31 P. Levy , F. Parisi , G. Polla , D. Vega , G. Leyva , H. Lanza , R. S. Freitas , L. Ghivelder

The phase behavior of grain boundaries can have a strong influence on interfacial properties. Little is known about the emergence of grain boundary phases in elemental metal systems and how they transform. Here, we observe the nanoscale…

We show that molecular dynamics (MD) simulations are capable of reproducing the drag of solute segregation atmospheres by moving grain boundaries (GBs). Although lattice diffusion is frozen out on the MD timescale, the accelerated GB…

Materials Science · Physics 2020-08-13 R. K. Koju , Y. Mishin

Grain boundaries (GBs) in metals usually increase electrical resistivity due to their distinct atomic arrangement compared to the grain interior. While the GB structure has a crucial influence on the electrical properties, its relationship…

Materials Science · Physics 2022-01-19 Hanna Bishara , Subin Lee , Tobias Brink , Matteo Ghidelli , Gerhard Dehm

Solute segregation along grain boundaries (GBs) profoundly affects their thermodynamic and kinetic behaviors in polycrystalline materials. Recently, the spectral approach has emerged as a powerful tool to predict GB segregation. However,…

Materials Science · Physics 2025-05-27 Zuoyong Zhang , Chuang Deng

Grain boundaries often exhibit ordered atomic structures. Increasing amounts of evidence have been provided by transmission electron microscopy and atomistic computer simulations that different stable and metastable grain boundary…

Materials Science · Physics 2023-02-14 Tobias Brink , Lena Langenohl , Hanna Bishara , Gerhard Dehm

Atomic migration from metallic contacts, and subsequent filament formation, is recognised as a prevailing mechanism leading to resistive switching in memristors based on two-dimensional materials (2DMs). This study presents a detailed…

The interfacial structure of a silicon grain boundary (Si-GB) plays a decisive role on its chemical functionalization and has implications in diverse physical-chemical properties of the material. Therefore, GB interface is particularly…

Materials Science · Physics 2023-01-02 Rita Maji , Eleonora Luppi , Elena Degoli

Interfacial segregation can stabilize grain structures and even lead to grain boundary complexion transitions. However, understanding of the complexity of such phenomena in polycrystalline materials is limited, as most studies focus on…

Materials Science · Physics 2021-07-02 P Garg , Z Pan , V Turlo , TJ Rupert

Nanostructured tungsten has been reported as a possible alternative plasma-facing material due to its potential ability to self-heal radiation-induced defects, a property that is attributed to its high density of grain boundaries (GB).…

Faceted grain boundaries, where grain boundary area is increased in the name of producing low-energy segments, can exhibit new and unexpected migration trends. For example, several faceted $\Sigma$3 boundaries have demonstrated anti-thermal…

Materials Science · Physics 2020-06-24 Megan J. McCarthy , Timothy J. Rupert

Grain boundaries (GBs), an important constituent of polycrystalline materials, have a wide range of manifestion and significantly affect the properties of materials. Fully understanding the effects of GBs is stalemated due to lack of…

Materials Science · Physics 2021-03-19 Cheng-yan Liu , Zhi-ming Li , Xin-gao Gong

Coincidence Site Lattice (CSL) grain boundaries (GBs) are believed to be low-energy, resistant to intergranular fracture, as well as to hydrogen embrittlement. Nevertheless, the behavior of CSL-GBs are generally confused with their angular…

Materials Science · Physics 2018-10-09 Mohamed H. Hamza , Mohamed A. Hendy , Tarek M. Hatem , Jaafar A. El-Awady

A new model for predicting the effective thermal conductivity of polycrystalline materials is presented. In contrast to existing models, our new model is based on the thin-interface description of grain boundaries (GBs) and treats GBs as an…

Materials Science · Physics 2020-07-22 fergany Badry , Karim Ahmed

Grain growth in polycrystalline materials can be impeded by grain boundary (GB) stagnation. Using atomistic simulations, we observed that during GB migration, the disruptive jumps of a few GB atoms can disturb the original ordered…

Materials Science · Physics 2024-08-19 Xinyuan Song , Chuang Deng

The accumulation of helium bubbles at grain boundaries (GBs) critically degrades the mechanical integrity of structural materials in nuclear reactors. While GBs act as sinks for radiation-induced defects, their inherent structural…

Materials Science · Physics 2025-09-10 Yang Zhang , Peter Hatton , Blas P. Uberuaga , Jason R. Trelewicz

Segregation-induced structural transitions in metallic grain boundaries are studied with hybrid atomistic Monte Carlo/molecular dynamics simulations using Cu-Zr as a model system, with a specific emphasis on understanding the effect of…

Materials Science · Physics 2016-04-27 Zhiliang Pan , Timothy J. Rupert

Segregation of impurities to grain boundaries plays an important role in both the stability and macroscopic behavior of polycrystalline materials. The research objective in this work is to better characterize the energetics and length…

Materials Science · Physics 2013-09-02 N. R. Rhodes , M. A. Tschopp , K. N. Solanki

Atomic-scale simulations are performed to study the effect of solute segregation on the shear-induced motion of select grain boundaries in the classical $\alpha$-Fe/C system. At shear rates larger than the solute diffusion rate, we observe…

Materials Science · Physics 2013-08-27 Changjian Wang , Moneesh Upmanyu

We present the results of first-principles calculations of selected structural and thermodynamic properties of a set of grain boundaries (GBs) in zirconium, spanning a range of misorientation angles and boundary planes. We performed…

Materials Science · Physics 2020-09-14 Adam J Plowman , Christopher P Race