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There are two silver perovskite oxides: AgNbO3 and AgTaO3. AgNbO3 has a noncentrosymmetric group of Pmc21 at room temperature with a ferri-electric ordering of polarization. Such a ferri-electric state with small polarization can be changed…

Materials Science · Physics 2011-08-31 Desheng Fu , Mitsuru Itoh

The improper ferroelectricity in YMnO$_3$ and other related multiferroic hexagonal manganites are known to cause topologically protected ferroelectric domains that give rise to rich and diverse physical phenomena. The local structure and…

By means of density-functional simulations for half-doped manganites, such as pseudocubic Pr0.5Ca0.5MnO3 and bilayer PrCa2Mn2O7, we discuss the occurrence of ferroelectricity and we explore its crucial relation to the crystal structure and…

Strongly Correlated Electrons · Physics 2013-10-07 Kunihiko Yamauchi , Silvia Picozzi

In hybrid improper ferroelectric systems, polarization arises from the onset of successive nonpolar lattice modes. In this work, measurements and modeling were performed to determine the spatial symmetries of the phases involved in the…

Materials Science · Physics 2019-07-03 S. Liu , H. Zhang , S. Ghose , M. Balasubramanian , Zhenxian Liu , S. G. Wang , Y-S. Chen , B. Gao , J. Kim , S. -W. Cheong , T. A. Tyson

We study the interplay of structural and polar distortions in hexagonal YMnO3 and short-period PbTiO3/SrTiO3 superlattices by means of first-principles calculations at constrained electric displacement field D. We find that in YMnO3 the…

Materials Science · Physics 2015-06-05 Massimiliano Stengel , Craig J. Fennie , Philippe Ghosez

Eu1-xYxMnO3 exhibits, unlike other magnetoelectric systems, very distinctive features. Its magnetoelectric properties is driven by the magnetic spin of the Mn3+ ion, but they can be drastically changed by varying the content of Y3+, which…

Strongly Correlated Electrons · Physics 2015-05-14 J. Agostinho Moreira , A. Almeida , W. S. Ferreira , M. R. Chaves , B. Kundys , R. Ranjith , W. Prellier , S. M. F. Vilela , P. B. Tavares

We refined the crystal structure of AMnO3, with A = Y, Er, Yb and Lu by single crystal x-ray diffraction. Our results show some distinct differences with previous reports on LuMnO3 and YbMnO3. We show that the ferroelectric behaviour is…

Strongly Correlated Electrons · Physics 2007-05-23 Bas B. van Aken , Auke Meetsma , Thomas T. M. Palstra

Conventional perovskite-type ferroelectrics are based on octahedral units of oxygen, and often comprise toxic Pb to achieve robust ferroelectricity. Here, we report the ferroelectricity in a silicate-based compound, Bi2SiO5 (BSO), induced…

Neutron powder diffraction and single crystal x-ray resonant magnetic scattering measurements suggest that Dy plays an active role in enhancing the ferroelectric polarization in multiferroic DyMnO3 above TNDy = 6.5 K. We observe the…

Strongly Correlated Electrons · Physics 2007-05-23 O. Prokhnenko , R. Feyerherm , E. Dudzik , S. Landsgesell , N. Aliouane , L. C. Chapon , D. N. Argyriou

Cu3Nb2O8 is an unusual multiferroic compound that undergoes a series of magnetic ordering at low temperatures. Concurrent development of electric polarization has been reported at TN1 ~25 K corresponding to a non-collinear helicoidal…

Strongly Correlated Electrons · Physics 2015-06-22 G. Sharma , J. Saha , S. D. Kaushik , V. Siruguri , S. Patnaik

We used first-principles calculations to investigate the existence and origin of the ferroelectric in- stability in the ABF3 fluoro-perovskites. We find that many fluoro-perovskites have a ferroelectric instability in their high symmetry…

Materials Science · Physics 2014-09-03 A. C. Garcia-Castro , N. A. Spaldin , A. H. Romero , E. Bousquet

Measurements of the structure of hexagonal RMnO3 (R=rare earths (Ho) and Y) for temperatures significantly above the ferroelectric transition temperature (TFE) were conducted to determine the nature of the transition. The local and long…

Materials Science · Physics 2015-05-30 T. A. Tyson , T. Wu , H. Y. Chen , J. Bai , K. H. Ahn , K. I. Pandya , S. B. Kim , S. -W. Cheong

Ferroelectricity is usually found in compound materials composed by different elements. Here, based on first-principles calculations, we reveal the first example of spontaneous electrical polarization and ferroelectricity in stable…

Materials Science · Physics 2017-06-20 Chengcheng Xiao , Fang Wang , Shengyuan A. Yang , Yunhao Lu

Magnetic and dielectric properties of the hexagonal triangular lattice antiferromagnet 2H-AgFeO2 have been studied by neutron diffraction, magnetic susceptibility, specific heat, pyroelectric current, and dielectric constant measurements.…

Strongly Correlated Electrons · Physics 2019-03-05 Noriki Terada , Dmitry D. Khalyavin , Pascal Manuel , Yoshihiro Tsujimoto , Alexei A. Belik

We carried out a comprehensive study of the structural, electrical transport, thermal and thermodynamic properties in ferrimagnetic Mn$_3$Si$_2$Te$_6$ single crystals. Mn and Te $K$-edge X-ray absorption spectroscopy and synchrotron powder…

Strongly Correlated Electrons · Physics 2021-10-22 Yu Liu , Zhixiang Hu , Milinda Abeykoon , Eli Stavitski , Klaus Attenkofer , Eric D. Bauer , C. Petrovic

We investigate the electronic structure and the ferroelectric properties of the recently discovered multiferroic ScFeO$_3$ by means of ab-initio calculations. The $3d$ manifold of Fe in the half-filled configuration naturally favors an…

High energy x-ray diffraction measurements on Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$ (PZN) single crystals show that the system does not have a rhombohedral symmetry at room temperature as previously believed. The new phase (X) in the bulk of the…

Strongly Correlated Electrons · Physics 2009-11-07 Guangyong Xu , Z. Zhong , Y. Bing , Z. -G. Ye , C. Stock , G. Shirane

We report neutron diffraction and magnetization studies of the magnetic order in multiferroic BiFeO3. In ferroelectric monodomain single crystals, there are three magnetic cycloidal domains with propagation vectors equivalent by…

Strongly Correlated Electrons · Physics 2015-05-27 M. Ramazanoglu , W. Ratcliff , Y. J. Choi , Seongsu Lee , S-W. Cheong , V. Kiryukhin

Electric polarization loops are measured at room temperature on highly pure BiFeO3 single crystals synthesized by a flux growth method. Because the crystals have a high electrical resistivity, the resulting low leakage currents allow us to…

Materials Science · Physics 2009-11-13 D. Lebeugle , D. Colson , A. Forget , M. Viret

In this work, we report the effects of calcination temperature on structural, dielectric, semiconducting and optical properties of YFeO3 nanoparticles prepared by a high energy ball milling process. The structural analysis of the X-ray…

Materials Science · Physics 2019-10-08 Chandra Bhal Singh , Dinesh Kumar , Narendra Kumar Verma , Akhilesh Kumar Singh