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HfO2, a simple binary oxide, holds ultra-scalable ferroelectricity integrable into silicon technology. Polar orthorhombic (Pbc21) form in ultra-thin-films ascribes as the plausible root-cause of the astonishing ferroelectricity, which has…

The structural phase transition in hexagonal BaMnO$_3$ occurring at $T_c$=130 K was studied in ceramic samples using electron and X-ray diffraction, second harmonic generation as well as by dielectric and lattice dynamic spectroscopies. The…

The direction of ferroelectric polarization is prescribed by the symmetry of the crystal structure. Therefore, rotation of the polarization direction is largely limited, despite the opportunity it offers in understanding important…

We present a unique example of giant magnetoelectric effect in a conventional multiferroic HoMnO3, where polarization is very large (~56 mC/m2) and the ferroelectric transition temperature is higher than the magnetic ordering temperature by…

Strongly Correlated Electrons · Physics 2015-05-13 N. Hur , I. K. Jeong , M. F. Hundley , S. B. Kim , S. -W. Cheong

The magnetic order, spin dynamics, and crystal structure of the multiferroic Sr0.56Ba0.44MnO3 have been investigated using neutron and x-ray scattering. Ferroelectricity develops at TC=305 K with a polarization of 4.2 microC/cm2 associated…

Controlling the ferroelectricity and magnetism in multiferroic materials has been an important research topic. We report the formation of a highly polarized state in multiferroic DyMnO3 single crystals which develops well above the magnetic…

Materials Science · Physics 2014-09-05 Tao Zou , Zhiling Dun , Huibo Cao , Mengze Zhu , Daniel Coulter , Haidong Zhou , Xianglin Ke

We present a study of the magnetic properties of Gd2/3Ca1/3MnO3 single crystals at low temperatures. We show that this material behave as an inhomogeneous ferrimagnet. In addition to small saturation magnetization at 5 K, we have found…

Materials Science · Physics 2009-11-13 N. Haberkorn , S. Larrégola , D. Franco , G. Nieva

Hexagonal YMnO_3 with space group P63cm is one of the rare examples of multiferroic materials that exhibit co-dependence of a robust ferroelectric phase along with antiferromagnetic ordering. This is primarily ascribed to tilting of the…

Strongly Correlated Electrons · Physics 2010-05-25 A. K. Singh , S. D. Kaushik , V. Siruguri , S. Patnaik

We report an electric-field poling study of the geometric-driven improper ferroelectric h-ErMnO$_3$. From a detailed dielectric analysis we deduce the temperature and frequency dependent range for which single-crystalline h-ErMnO$_3$…

Hexagonal manganites are multiferroic materials with two highly-dissimilar phase transitions: a ferroelectric transition (from P63/mmc to P63cm) at a temperature higher than 1000 K and an antiferromagnetic transition at TN=65 - 130 K.…

Strongly Correlated Electrons · Physics 2018-02-20 Hasung Sim , Jaehong Jeong , Haeri Kim , S-W Cheong , Je-Geun Park

Combining our comprehensive investigations of polarization evolution, soft-mode by Raman scattering and microstructure by TEM, and the results reported in the literatures, we show that prototypical relaxor Pb(Mg1/3Nb2/3)O3 (PMN) is…

Materials Science · Physics 2013-01-17 Desheng Fu , Hiroki Taniguchi , Mitsuru Itoh , Shigeo Mori

We discuss the particle size driven tunability of the coexistence of ferromagnetism and ferroelectricity in Pr0.67Ca0.33MnO3(PCMO) with the help of x ray diffraction, magnetization, impedance spectroscopy, and remanent polarization…

Strongly Correlated Electrons · Physics 2014-12-25 Vinay Kumar Shukla , Soumik Mukhopadhyay , Kalipada Das , A. Sarma , I. Das

SrTiO$_{3}$ is known to be an incipient ferroelectric. It is thought that ferroelectric stability in SrTiO$_{3}$ is suppressed by a delicate competition with quantum fluctuation and antiferrodistortion. The ferroelectric phase can, however,…

Materials Science · Physics 2014-04-22 Ashima Arora , Goutam Sheet

<001> oriented 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals were poled under different electric fields, i.e. Epoling=4 kV/cm and Epoling=13 kV/cm. In addition to the temperature-dependent dielectric constant measurement, X-ray diffraction…

Materials Science · Physics 2009-11-07 Ke-Pi Chen , Xiao-Wen Zhang , Hao-Su Luo

SmFeO3 has attracted considerable attention very recently due to the reported multiferroic properties above room-temperature. We have performed powder and single crystal neutron diffraction as well as complementary polarization dependent…

We report ferroelectricity with fairly large spontaneous polarization (P ~ 0.2 - 0.8 \muC/cm2) below the N\'eel temperature of chromium (TNCr) in weakly ferromagnetic rare-earth orthochromites, RCrO3 (R=rare-earth) only when the rare-earth…

Materials Science · Physics 2012-12-19 B. Rajeswaran , D. I. Khomskii , A. K. Zvezdin , C. N. R. Rao , A. Sundaresan

From magnetic susceptibility, dielectric permittivity, electric polarization and specific heat measurements, we discover spin-induced ferroelectricity and magnetoelectric coupling in Mn3TeO6 and observe two successive magnetic transitions…

Materials Science · Physics 2015-12-01 L. Zhao , Z. Hu , C. Y. Kuo , T. -W. Pi , M. -K. Wu , L. H. Tjeng , A. C. Komarek

Low-dimensional ferroelectricity and polar materials have attracted considerable attentions for their fascinating physics and potential applications. Based on first-principles calculations, here we investigate the stacking modes and polar…

Materials Science · Physics 2022-10-12 Wencong Sun , Ning Ding , Jun Chen , Hai-Peng You , Jin Peng , Shan-Shan Wang , Shuai Dong

Piezoelectricity is inherent only in noncentrosymmetric materials, but a piezoelectric response can also be obtained in centrosymmetric crystals if subjected to inhomogeneous deformation. This phenomenon, known as flexoelectricity, affects…

Materials Science · Physics 2007-10-22 P. Zubko , G. Catalan , A. Buckley , P. R. L. Welche , J. F. Scott

A comparative theoretical study is presented for the rhombohedral R3 and R3m phase HfO2, of two possible forms in its heavily Zr-doped ferroelectric thin films found recently in experiments. Their structural stability and polarization under…

Materials Science · Physics 2023-07-03 Wenbin Ouyang , Fanghao Jia , Wei Ren