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We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…

Soft Condensed Matter · Physics 2018-05-23 Derek Frydel , Rudolf Podgornik

We report Brownian dynamics (BD) simulation and theoretical results for a system of spherical colloidal particles with permanent dipole moments in a rotating magnetic field. Performing simulations at a fixed packing fraction and dipole…

Soft Condensed Matter · Physics 2011-03-07 Sebastian Jaeger , Sabine H. L. Klapp

Correlated anion and cation motion can significantly reduce the overall ion conductivity in electrolytes versus the ideal conductivity calculated based on the diffusion constants alone. Using coarse-grained molecular dynamics simulations,…

Soft Condensed Matter · Physics 2020-06-01 Kuan-Hsuan Shen , Lisa M. Hall

The ionization of two-active-electron systems by intense laser fields is investigated theoretically. In comparison with time-dependent Hartree-Fock and exact two electron simulation, we show that the ionization rate is overestimated in SAE…

Atomic Physics · Physics 2015-06-18 Zengxiu Zhao , Jianmin Yuan

We apply relativistic many-body methods to compute static differential polarizabilities for transitions inside the ground-state hyperfine manifolds of monovalent atoms and ions. Knowing this transition polarizability is required in a number…

Atomic Physics · Physics 2011-07-13 V. A. Dzuba , V. V. Flambaum , K. Beloy , A. Derevianko

The response of a suspension under a variety of static or alternating external fields strongly depends on the equilibrium electric double layer that surrounds the colloidal particles in the suspension. The theoretical models for salt-free…

Soft Condensed Matter · Physics 2022-02-11 Jun-Sik Sin , Kwang-Il Kim , Kuk-Chol Ri , Dok-Yong Ju , Nam-Hyok Kim , Chung-Sik Sin

Nonlinear electrokinetic phenomena, where electrically driven fluid flows depend nonlinearly on the applied voltage, are commonly encountered in aqueous suspensions of colloidal particles. A prime example is the induced-charge…

Soft Condensed Matter · Physics 2024-11-27 Zhanwen Wang , Michael J. Miksis , Petia M. Vlahovska

I show that the theory developed for quantum delocalization of an excited Hydrogen atom in a two-frequency linearly polarized microwave field can be used with a few adaptions to explain the quantum delocalization of Alkali atoms in a…

Atomic Physics · Physics 2016-09-08 Luca Perotti

In order to study chromospheric magnetosonic wave propagation including, for the first time, the effects of ion-neutral interactions in the partially ionized solar chromosphere, we have developed a new multi-fluid computational model,…

Solar and Stellar Astrophysics · Physics 2017-03-08 Yana G. Maneva , Alejandro A. Laguna , Andrea Lani , Stefaan Poedts

The study of the electrical double layer lies at the heart of colloidal and interfacial science. The standard mean-field Poisson-Boltzmann (PB) theory is incapable of modeling many phenomena originated from ion correlation. An important…

Soft Condensed Matter · Physics 2022-09-26 Nikhil R. Agrawal , Rui Wang

Tasker type III polar terminations of ionic crystals carry a net surface charge as well as a dipole moment and are fundamentally unstable. In contact with electrolytes, such polar surfaces can be stabilized by adsorption of counter ions…

Chemical Physics · Physics 2019-03-22 Thomas Sayer , Michiel Sprik , Chao Zhang

Monolayers of colloidal particles at oil-water interfaces readily crystalize owing to electrostatic repulsion, which is often mediated through the oil. However, little attempts exist to control it using oil-soluble electrolytes. We probe…

Soft Condensed Matter · Physics 2023-05-04 Carolina van Baalen , Jacopo Vialetto , Lucio Isa

Charged colloidal monolayers at the interface between water and air (or oil) are used in a large number of chemical, physical and biological applications. Although a considerable experimental and theoretical effort has been devoted in the…

Soft Condensed Matter · Physics 2018-12-03 Aviv Karnieli , Tomer Markovich , David Andelman

We consider the millimeter-wave electrodynamics specific to quasi-two-dimensional conductors and superconductors based on the organic donor molecule BEDT-TTF. Using realistic physical parameters, we examine the current polarizations that…

Strongly Correlated Electrons · Physics 2009-10-31 Stephen Hill

Trajectories of a polarizable species (atoms or molecules) in the vicinity of a negatively charged nanoparticle (at a floating potential) are considered. The atoms are pulled into regions of strong electric field by polarization forces. The…

Plasma Physics · Physics 2019-05-30 Valerian Nemchinsky , Alexander Khrabry

Mean-field theory is used to model polyelectrolyte adsorption and the possibility of overcompensation of charged surfaces. For charged surfaces that are also chemically attractive, the overcharging is large in high salt conditions,…

Soft Condensed Matter · Physics 2009-11-10 Adi Shafir , David Andelman

We present a theory that enables us to calculate the effective surface charge of colloidal particles and to efficiently obtain titration curves for different salt concentrations. The theory accounts for the shift of pH of solution due to…

Soft Condensed Matter · Physics 2022-11-01 Amin Bakhshandeh , Derek Frydel , Yan Levin

Alkali vapor cells with antirelaxation coating (especially paraffin-coated cells) have been a central tool in optical pumping and atomic spectroscopy experiments for 50 years. We have discovered a dramatic change of the alkali vapor density…

Nonlinear field dependence of electrophoresis in high fields has been investigated theoretically, yet experimental studies have failed to reach consensus on the effect. In this work, we present a systematic study on the nonlinear…

Soft Condensed Matter · Physics 2019-07-10 Soichiro Tottori , Karolis Misiunas , Ulrich F. Keyser , Douwe Jan Bonthuis

The influence of the chain degree of ionization on the adsorption of weak polyelectrolytes on neutral and on oppositely and likely charged surfaces is investigated for the first time, by means of Monte Carlo simulations with the mesoscopic…

Biological Physics · Physics 2012-10-02 F. Alarcón , E. Pérez , A. Gama Goicochea
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