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In photovoltaic diodes recombination of photogenerated electrons and holes is a major loss process. Biological light harvesting complexes (LHCs) prevent recombination via the use of cascade structures, which lead to spatial separation of…

We studied the recombination dynamics of charge carriers in organic bulk heterojunction solar cells made of the blend system poly(2,5-bis(3-dodecyl thiophen-2-yl) thieno[2,3-b]thiophene) (pBTCT-C12):[6,6]-phenyl-C61-butyric acid methyl…

The power conversion efficiency of organic solar cells based on donor--acceptor blends is governed by an interplay of polaron pair dissociation and bimolecular polaron recombination. Both processes are strongly dependent on the charge…

Materials Science · Physics 2010-05-26 C. Deibel , A. Wagenpfahl , V. Dyakonov

Conventional models of planar and bulk heterojunction organic solar cells have been extended by introducing doping in the active layer. We have studied the performance of organic solar cells as a function of dopant concentration. For bulk…

Materials Science · Physics 2015-06-03 V. A. Trukhanov , V. V. Bruevich , D. Yu. Paraschuk

The unique properties of organic semiconductors make them versatile base materials for many applications ranging from light emitting diodes to transistors. The low spin-orbit coupling typical for carbon-based materials and the resulting…

A design tool was formulated for optimizing the efficiency of inorganic, thin-film, photovoltaic solar cells. The solar cell can have multiple semiconductor layers in addition to antireflection coatings, passivation layers, and buffer…

Numerical Analysis · Mathematics 2024-09-23 Tom H. Anderson , Benjamin J. Civiletti , Peter Monk , Akhlesh Lakhtakia

We propose a model to explain the reduced bimolecular recombination rate found in state-of-the-art bulk heterojunction solar cells. When compared to the Langevin recombination, the experimentally observed rate is one to four orders of…

Materials Science · Physics 2009-08-09 C. Deibel , A. Wagenpfahl , V. Dyakonov

The theoretical analysis of photovoltaic conversion efficiency of highly effective silicon solar cells (SC) is performed for n-type and p-type bases. The case is considered when the Shockley-Read-Hall recombination in the silicon bulk is…

The major loss mechanism of photogenerated polarons was investigated in P3HT:PCBM solar cells by the photo-CELIV technique. For pristine and annealed devices, we find that the experimental data can be explained by a bimolecular…

Materials Science · Physics 2010-02-08 C. Deibel , A. Baumann , A. Wagenpfahl , V. Dyakonov

The charge carrier mobility is a key parameter for the organic bulk heterojunction solar cell efficiency. It was recently shown that the interplay charge carrier transport and recombination, both depending on electron and hole mobilities,…

Materials Science · Physics 2011-01-17 A. Wagenpfahl , C. Deibel , V. Dyakonov

We report on the effect of the strong spin orbit coupling and the Lorentz force on the efficiency of TiO2 based dye sensitized solar cells. Upon inclusion of Ho2O3, due to the strong spin orbit coupling of the rare earth Ho3+ ion, we do see…

The power conversion efficiency of organic solar cells has recently improved beyond 20%. The active layers of these devices comprise of at least two organic semiconductors, forming a type II heterojunction. Hereby, the device performance is…

Materials Science · Physics 2026-01-22 Jonathan L. Langentepe-Kong , Manasi Pranav , Safa Shoaee , Dieter Neher

Singlet fission, in which the optical spin-singlet exciton dissociates into two low energy triplet excitons, has been proposed as a viable approach to enhance the quantum efficiency of organic solar cells. We show that even when singlet…

Strongly Correlated Electrons · Physics 2013-03-15 K. Aryanpour , J. A. Muñoz , S. Mazumdar

Fundamental electronic processes such as charge-carrier transport and recombination play a critical role in determining the efficiency of hybrid perovskite solar cells. The presence of mobile ions complicates the development of a clear…

Materials Science · Physics 2020-12-17 Sebastian Reichert , Katelyn Goetz , Christopher Wöpke , Yana Vaynzof , Carsten Deibel

Metastable defects can decisively influence the diode factor and thus the efficiency of a solar cell. The diode factor is also influenced by the doping level and the recombination mechanisms in the solar cell. Here we quantify how the…

Applied Physics · Physics 2025-12-01 T. Wang , F. Ehre , T. P. Weiss , B. Veith-Wolf , V. Titova , N. Valle , M. Melchiorre , J. Schmidt , S. Siebentritt

The great progress in organic photovoltaics (OPV) over the past few years has been largely achieved by the development of non-fullerene acceptors (NFAs), with power conversion efficiencies now approaching 20%. To further improve device…

Charge separation is a critical process for achieving high efficiencies in organic photovoltaic cells. The initial tightly bound excitonic electron-hole pair has to dissociate fast enough in order to avoid photocurrent generation and thus…

Mesoscale and Nanoscale Physics · Physics 2017-12-05 S. Oviedo-Casado , A. Urbina , J. Prior

Suppressing charge recombination is key for organic solar cells to become commercial reality. However, there is still no conclusive picture of how recombination losses are influenced by the complex nanoscale morphology. Here, new insight is…

Recombination losses contribute to reduce $J_{SC}$, $V_{OC}$ and the fill factor of organic solar cells. Recent advances in non-fullerene organic photovoltaics have shown, nonetheless, that efficient charge generation can occur under small…

Materials Science · Physics 2022-11-24 Artur M. Andermann , Luis G. C. Rego

We propose an efficient plasmonic structure consisting of metal strips and thin-film silicon for solar energy absorption. We numerically demonstrate the absorption enhancement in symmetrical structure based on the mode coupling between the…

Optics · Physics 2010-11-22 Tong Li , Lei Dai , Chun Jiang
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