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We investigate the phase behaviour of mixtures of two populations of colloidal particles dispersed in a binary solvent system near its critical composition. The surfaces of particles are chemically modified to elicit a specific solvent…

Soft Condensed Matter · Physics 2026-02-16 T. E. Kodger , N. Farahmand Bafi , M. Labbé-Laurent , E. Steijlen , A. Maciolek , P. Schall

If colloidal solute particles are suspended in a solvent close to its critical point, they act as cavities in a fluctuating medium and thereby restrict and modify the fluctuation spectrum in a way which depends on their relative…

Soft Condensed Matter · Physics 2018-11-14 Anna Maciolek , Siegfried Dietrich

Critical Casimir forces can play an important role for applications in nano-science and nanotechnology, owing to their piconewton strength, nanometric action range, fine tunability as a function of temperature, and exquisite dependence on…

We present a numerical study of the effective potential $V_\mathrm{eff}$ between two hard-sphere colloids dispersed in a solvent of interacting particles, for several values of temperature and solvent density, approaching the solvent…

Soft Condensed Matter · Physics 2013-04-08 Nicoletta Gnan , Emanuela Zaccarelli , Piero Tartaglia , Francesco Sciortino

From experimental studies it is well-known that colloidal particles suspended in a near-critical binary solvent exhibit interesting aggregation phenomena, often associated with colloidal phase transitions, and assumed to be driven by…

Soft Condensed Matter · Physics 2015-06-19 John R. Edison , Nikos Tasios , Simone Belli , Robert Evans , Rene van Roij , Marjolein Dijkstra

We present an experimental and theoretical study of the phase behavior of a binary mixture of colloids with opposite adsorption preferences in a critical solvent. As a result of the attractive and repulsive critical Casimir forces, the…

Soft Condensed Matter · Physics 2011-10-03 O. Zvyagolskaya , A. J. Archer , C. Bechinger

Spatial confinement of a near-critical medium changes its fluctuation spectrum and modifies the corresponding order parameter distribution. These effects result in effective, so-called critical Casimir forces (CCFs) acting on the confining…

Soft Condensed Matter · Physics 2014-03-24 T. F. Mohry , S. Kondrat , A. Maciolek , S. Dietrich

We study the phase behavior of colloidal suspensions the solvents of which are considered to be binary liquid mixtures undergoing phase segregation. We focus on the thermodynamic region close to the critical point of the accompanying…

Soft Condensed Matter · Physics 2015-06-03 T. F. Mohry , A. Maciołek , S. Dietrich

Critical Casimir interactions represent a perfect example of bath-induced forces at mesoscales. These forces may have a relevant role in the living systems as well as a role in the design of nanomachines fueled by environmental…

Mesoscale and Nanoscale Physics · Physics 2023-12-20 Ignacio A. Martinez , Artyom Petrosyan , Sergio Ciliberto

We review recent advances in the theoretical, numerical, and experimental studies of critical Casimir forces in soft matter, with particular emphasis on their relevance for the structures of colloidal suspensions and on their dynamics.…

Soft Condensed Matter · Physics 2023-12-27 Andrea Gambassi , S. Dietrich

Colloids immersed in a critical binary liquid mixture are subject to critical Casimir forces (CCFs) because they confine its concentration fluctuations and influence the latter via effective surface fields. To date, CCFs have only been…

Soft Condensed Matter · Physics 2013-09-04 Akira Furukawa , Andrea Gambassi , Siegfried Dietrich , Hajime Tanaka

In soft and condensed matter physics, effective interactions often emerge as a result of the spatial confinement of a fluctuating field. For instance, microscopic particles in a binary liquid mixture are subject to critical Casimir forces…

We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of…

Soft Condensed Matter · Physics 2015-06-03 T. F. Mohry , A. Maciołek , S. Dietrich

If a fluctuating medium is confined, the ensuing perturbation of its fluctuation spectrum generates Casimir-like effective forces acting on its confining surfaces. Near a continuous phase transition of such a medium the corresponding order…

Soft Condensed Matter · Physics 2011-02-15 A. Gambassi , A. Maciolek , C. Hertlein , U. Nellen , L. Helden , C. Bechinger , S. Dietrich

Among the various kinds of effective forces in soft matter, the spatial range and the direction of the so-called critical Casimir force - which is generated by the enhanced thermal fluctuations close to a continuous phase transition - can…

Soft Condensed Matter · Physics 2011-02-14 Andrea Gambassi , S. Dietrich

The Casimir effect in quantum electrodynamics (QED) is perhaps the best-known example of fluctuation-induced long-ranged force acting on objects (conducting plates) immersed in a fluctuating medium (quantum electromagnetic field in vacuum).…

Statistical Mechanics · Physics 2009-07-13 Andrea Gambassi

Percolation and critical phenomena show common features such as scaling and universality. Colloidal particles, immersed in a solvent close to criticality, experience long-range effective forces, named critical Casimir forces. %These…

Soft Condensed Matter · Physics 2014-07-16 Nicoletta Gnan , Emanuela Zaccarelli , Francesco Sciortino

We investigate the behavior of colloidal particles immersed in a binary liquid mixture of water and 2,6-lutidine in the presence of a chemically patterned substrate. Close to the critical point of the mixture, the particles are subjected to…

Soft Condensed Matter · Physics 2009-11-13 F. Soyka , O. Zvyagolskaya , C. Hertlein , L. Helden , C. Bechinger

We study theoretically and experimentally the solvent-mediated critical Casimir force acting on colloidal particles immersed in a binary liquid mixture of water and 2,6-lutidine and close to substrates which are chemically patterned with…

We study the behavior of the critical Casimir force and its interplay with the van der Waals force acting between two parallel slabs separated at a distance $L$ from each other confining a non-polar simple fluid or a binary liquid mixture.…

Statistical Mechanics · Physics 2015-07-20 Galin Valchev , Daniel Dantchev
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