Related papers: A note on Gibbs paradox
In Physica A vol 387(24) (2008) pp6079-6094 [1], a kinetic equation for gas flows was proposed that leads to a set of four macroscopic conservation equations, rather than the traditional set of three equations. The additional equation…
I discuss how five reasonably sounding assumptions lead to a dilemma -- the Page-time paradox -- , which appears to challenge a conventional statistical mechanical underpinning of black hole thermodynamics. By inspecting the conceptual…
Nonadditive Tsallis $q$-statistics has successfully been applied for a plethora of systems in natural sciences and other branches of knowledge. Nevertheless, its foundations have been severely criticised by some authors based on the…
In recent papers, several authors have claimed that a definition of the thermodynamic entropy in terms of the logarithm of a volume in phase space, originally suggested by Gibbs, is the only valid definition. Arguing from the Gibbs entropy,…
We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…
Colloidal particles are distinguishable. Moreover, their thermodynamic properties are extensive. Statistical Mechanics predicts such behaviour if one accepts that the configurational integral of a system of N colloids must be divided by N!.…
We compare two approaches to the generalization of the ordinary Fermi-statistics based on the nonadditive Tsallis $q$-exponential used in the Gibbs factor instead of the conventional exponential function. Both numerical and analytical…
The concept of quantum superposition is reconsidered and discussed from the viewpoint of Bohmian mechanics, the hydrodynamic formulation of quantum mechanics, in order to elucidate some physical consequences that go beyond the simple…
Zeno's paradoxes are explained as being the result of inappropriate combination of discrete and continuous mathematical systems. It is proposed that the source of this confusion lies in the course of development of the number system, which…
Consistent statistical physical description is given for systems where the elementary excitations are composite objects. Explicit calculational scheme is constructed for the energy density and the total number of thermodynamical degrees of…
In this chapter we address the topic of quantum thermodynamics in the presence of additional observables beyond the energy of the system. In particular we discuss the special role that the generalized Gibbs ensemble plays in this theory,…
Arguments are presented that the assumption, implicit to traditional statistical thermodynamics, that at zero temperature all erratic motions cease, should be dispensed with. Assuming instead a random ultrarelativistic unobservable motion,…
In this paper we find a connection between the macroscopic classical laws of gases and the quantum mechanical description of molecules, composing an ideal gas. In such a gas, the motion of each individual molecule can be considered…
Although its practical efficiency is unquestionable, it is well known that thermodynamics presents conceptual difficulties from the theoretical point of view. It is shown that the problem comes from an imperfect compatibility between the…
The long standing contrast between Boltzmann's and Gibbs' approach to statistical thermodynamics has been recently rekindled by Dunkel and Hilbert [1], who criticize the notion of negative absolute temperature (NAT), as a misleading…
There are reasons to believe that implications of a certain paradox introduced by Ginzburg and related problems have not been fully recognized. Pertinent issues remain open and unresolved. There are instances when the current widely used…
The statistical mechanics of Gibbs is a juxtaposition of subjective, probabilistic ideas on the one hand and objective, mechanical ideas on the other. In this paper, we follow the path set out by Jaynes, including elements added…
The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…
For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…
Understanding the transition to turbulence has been impeded by a modeling oversight