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Related papers: A Computed Room Temperature Line List for Phosphin…

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{\it Ab initio} potential energy and dipole moment surfaces are computed for sulfur trioxide (SO$_3$) at the CCSD(T)-F12b level of theory and appropriate triple-zeta basis sets. These surfaces are fitted and used, with a slight correction…

Earth and Planetary Astrophysics · Physics 2017-09-13 Daniel S. Underwood , Jonathan Tennyson , Sergei N. Yurchenko

A comprehensive hot line list is calculated for $^{31}$PH$_3$ in its ground electronic state. This line list, called SAlTY, contains almost 16.8 billion transitions between 7.5 million energy levels and it is suitable for simulating spectra…

Earth and Planetary Astrophysics · Physics 2015-04-13 Clara Sousa-Silva , Ahmed F. Al-Refaie , Jonathan Tennyson , Sergei N. Yurchenko

We present 'BYTe', a comprehensive 'hot' line list for the ro-vibrational transitions of ammonia, 14NH3, in its ground electronic state. This line list has been computed variationally using the program suite TROVE, a new…

Earth and Planetary Astrophysics · Physics 2017-07-03 S. N. Yurchenko , R. J. Barber , J. Tennyson

A computed line list for formaldehyde, H$_2{}^{12}$C$^{16}$O, applicable to temperatures up to $T=1500$~K is presented. An empirical potential energy and {\it ab initio} dipole moment surfaces are used as the input to nuclear motion program…

Astrophysics of Galaxies · Physics 2015-06-02 Ahmed F. Al-Refaie , Andrey Yachmenev , Jonathan Tennyson , Sergei N. Yurchenko

We present the first variational calculation of a hot temperature ab initio line list for the CH$_3$ radical. It is based on a high level ab initio potential energy surface and dipole moment surface of CH$_3$ in the ground electronic state.…

Chemical Physics · Physics 2019-05-15 Ahmad Y. Adam , Andrey Yachmenev , Sergei N. Yurchenko , Per Jensen

A computed line list for hydrogen peroxide, H$_2{}^{16}$O$_2$, applicable to temperatures up to $T=1250$~K is presented. A semi-empirical high accuracy potential energy surface is constructed and used with an {\it ab initio} dipole moment…

Earth and Planetary Astrophysics · Physics 2016-07-05 Ahmed F. Al-Refaie , Oleg L. Polyansky , Roman I. Ovsyannikov , Jonathan Tennyson , Sergei N. Yurchenko

Calculations are reported on the rotation-vibration energy levels of the arsine molecule with associated transition intensities. A potential energy surface (PES) obtained from \textit{ab initio} electronic structure calculations is refined…

Earth and Planetary Astrophysics · Physics 2019-02-07 Phillip A. Coles , Sergei N. Yurchenko , Richard P. Kovacich , James Hobby , Jonathan Tennyson

Atmospheric carbon dioxide concentrations are being closely monitored by remote sensing experiments which rely on knowing line intensities with an uncertainty of 0.5% or better. We report a theoretical study providing rotation-vibration…

Accurate rotational-vibrational line lists for $^{31}$P$^{14}$N and $^{31}$P$^{15}$N in their ground electronic states are computed. The line lists are produced using an empirical potential energy curve obtained by fitting to the…

Astrophysics of Galaxies · Physics 2015-04-14 Leo Yorke , Sergei N. Yurchenko , Lorenzo Lodi , Jonathan Tennyson

Remote sensing experiments require high-accuracy, preferably sub-percent, line intensities and in response to this need we present computed room temperature line lists for six symmetric isotopologues of carbon dioxide: $^{13}$C$^{16}$O$_2$,…

Earth and Planetary Astrophysics · Physics 2017-11-01 Emil J. Zak , Jonathan Tennyson , Oleg L. Polyansky , Lorenzo Lodi , Nikolay F. Zobov , Sergei A. Tashkun , Valery I. Perevalov

A comprehensive, calculated line list of frequencies and transition probabilities for the singly deuterated isotopologue of H3+, H2D+, is presented. The line list, called ST1, contains over 22 million rotational-vibrational transitions…

Computational Physics · Physics 2010-05-11 Taha Sochi , Jonathan Tennyson

A rovibronic line list for the ground ($X$ $^3\Sigma^-$) and first excited ($a$ $^1\Delta$) states of phosphinidene, $^{31}$PH, is computed. The line list is designed for studies of exoplanetary and cool stellar atmospheres with…

Earth and Planetary Astrophysics · Physics 2019-07-17 Jonathan Langleben , Jonathan Tennyson , Sergei N. Yurchenko , Peter Bernath

A new hot line list is calculated for $^{12}$CH$_4$ in its ground electronic state. This line list, called 10to10, contains 9.8 billion transitions and should be complete for temperatures up to 1500 K. It covers the wavelengths longer than…

Earth and Planetary Astrophysics · Physics 2014-06-27 Sergei N. Yurchenko , Jonathan Tennyson

A rotation-vibration line list for the electronic ground state ($\tilde{X}^{1}A_{1}$) of SiH$_2$ is presented. The line list, named CATS, is suitable for temperatures up to 2000 K and covers the wavenumber range 0 - 10,000…

Chemical Physics · Physics 2020-04-03 Victoria H. J. Clark , Alec Owens , Jonathan Tennyson , Sergei N. Yurchenko

A new room temperature line list for $^{15}$NH$_3$ is presented. This line list comprised of transition frequencies and Einstein coefficients has been generated using the `spectroscopic' potential energy surface NH3-Y2010 and an ab initio…

Earth and Planetary Astrophysics · Physics 2015-03-02 Sergei N. Yurchenko

A new hot line list for the main isotopologue of CO$_2$ is presented. The line list consists of almost 2.5 billion transitions between 3.5 million rotation-vibration states of CO$_2$ in its ground electronic state, covering the wavenumber…

Earth and Planetary Astrophysics · Physics 2020-07-10 S. N. Yurchenko , Thomas M. Mellor , Richard S. Freedman , J. Tennyson

A variationally computed $^{28}$SiH$_4$ rotation-vibration line list applicable for temperatures up to $T=1200\,$K is presented. The line list, called OY2T, considers transitions with rotational excitation up to $J=42$ in the wavenumber…

Chemical Physics · Physics 2017-12-29 A. Owens , A. Yachmenev , W. Thiel , J. Tennyson , S. N. Yurchenko

Rotation-vibration spectra of the nitric acid molecule, HNO\3, are calculated for wavenumbers up to 7000~\cm. Calculations are performed using a Hamiltonian expressed in internal curvilinear vibrational coordinates solved using a hybrid…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

This work presents the AYT2 line list: a comprehensive list of 114 million $^{1}$H$_2$$^{32}$S vibration-rotation transitions computed using an empirically-adjusted potential energy surface and an {\it ab initio} dipole moment surface. The…

Earth and Planetary Astrophysics · Physics 2016-07-05 Ala'a A. A. Azzam , Jonathan Tennyson , Sergei N. Yurchenko , Olga V. Naumenko

Accurate line lists for three molecules, BeH, MgH and CaH, in their ground electronic states are presented. These line lists are suitable for temperatures relevant to exoplanetary atmospheres and cool stars (up to 2000K). A combination of…

Solar and Stellar Astrophysics · Physics 2012-08-22 Benjamin Yadin , Thomas Veness , Pierandrea Conti , Christian Hill , Sergei N. Yurchenko , Jonathan Tennyson
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